Comparison of Minimum Detectable Concentration with the IUPAC Detection Limit

I. Janiga; J. Mocak; I. Garaj

doi:10.2478/v10048-008-0028-5

.blurhash-client-img { display: none !important; }

Comparison of Minimum Detectable Concentration with the IUPAC Detection Limit

Measurement Science Review

Volume 8 (2008): Issue 5 (October 2008)

By: I. Janiga, J. Mocak and I. Garaj

Open Access

|Oct 2008

Abstract

Detection capability is an important performance characteristic of a measurement process. It is characterized by ISO as minimum detectable value. Another characteristic, used in chemical measurements, was defined by IUPAC as the limit of detection. These and further closely related characteristics are compared and theoretically analysed. Directions for their use are given and exemplified using chemical trace analysis of lead.

References

Janiga, I., Garaj, I., Cisko, P. (2004). Estimation of minimum detectable value by using linear calibration with constant standard deviation. Forum Metricum Slov. 8, 68-73.
Search in Google Scholar
Janiga, I., Mocak, J., Cisko, P., Garaj, I., Szarková, D. (2006). Detection of the mercury content in food and medicines by means of linear calibration function. Forum Statist. Slov. 2, 67-72.
Search in Google Scholar
International Organization for Standardization. (1996). ISO 11843-2. Capability of detection. Part 2: Methodology in the linear calibration case. ISO/TC69/SC6, P. Wilrich, Chairman.
Search in Google Scholar
Slovak Institute for Standardization. (2002). Slovak Technical Standard. STN ISO 11843-2. Detekčná schopnost'. Čast' 2: Metodika lineárnej kalibrácie (in Slovak). Bratislava.
Search in Google Scholar
IUPAC, Analytical Chemistry Division (1978). Nomenclature, symbol, units and their usage in spectrochemical analysis. II. Data interpretation. Spectrochim. Acta B 33(6), 241-246.
Search in Google Scholar
Currie, L. A. (1995). Nomenclature in evaluation of analytical methods including detection and quantification capabilities. IUPAC Recommendations 1995. Pure & Appl. Chem. 67, 1699-1723.10.1351/pac199567101699
Search in Google Scholar
Mocak, J., Bond, A. M., Mitchell, S., Schollary, G. (1997). A statistical overview of standard (IUPAC and ACS) and new procedures for determining the limits of detection and quantification: Application to voltammetric and stripping techniques. IUPAC Technical Report 1997. Pure & Appl. Chem. 69, 297-328.10.1351/pac199769020297
Search in Google Scholar
Mocak, J., Bobrowski, A. (2001). Determination of cadmium and lead in water - new recommended way of evaluating the limits of detection and quantification. Water Sci. & Technol. Water Supply 1, 19-26.10.2166/ws.2001.0017
Search in Google Scholar

Articles in this issue

DOI: https://doi.org/10.2478/v10048-008-0028-5 | Journal eISSN: 1335-8871

Journal RSS Feed

Language: English

Page range: 108 - 110

Published on: Oct 24, 2008

Published by: Slovak Academy of Sciences, Institute of Measurement Science

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

minimum detectable value,

minimum detectable concentration,

limit of detection,

critical value,

decision limit,

limit of identification,

limit of quantification

Related subjects:

Engineering,

Electrical engineering,

Control engineering, metrology and testing

© 2008 I. Janiga, J. Mocak, I. Garaj, published by Slovak Academy of Sciences, Institute of Measurement Science
This work is licensed under the Creative Commons License.

Volume 8 (2008): Issue 5 (October 2008)