Sodium Metasilicate-MgO Blend Catalyst for Producing Mono and Diacylglycerol from Palm Kernel Oil Using High Shear Compartment Reactor

Arief Rakhman Affandi; Ria Millati; Chusnul Hidayat

doi:10.2478/pjct-2024-0035

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Sodium Metasilicate-MgO Blend Catalyst for Producing Mono and Diacylglycerol from Palm Kernel Oil Using High Shear Compartment Reactor

Green Sciences

Volume 26 (2024): Issue 4 (December 2024)

By: Arief Rakhman Affandi, Ria Millati and Chusnul Hidayat

Open Access

|Dec 2024

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Abstract

Sodium metasilicate (SMS) tended to agglomerate during glycerolysis reactions in high shear compartment reactors (HSCR), hindering triacylglycerol (TAG) conversion. Therefore, the aim was to evaluate the SMS-magnesium oxide (MgO) blend as a heterogeneous catalyst for glycerolysis reactions. Various SMS-MgO ratios (ranging from 2.5:1 to 10.0:1) were evaluated. The results demonstrated that increasing MgO in the blend reduced catalyst basicity and minimized O-Si-O groups and catalyst crystallinity, preventing clumping and increasing catalyst surface area. The SMS-MgO 5.0:1 blend exhibited the smallest pore size (<2 nm) with a surface area of 4.22 m² ._g^–1 and basicity of 11.59 ± 0.115 mmol . g^–1. This blend achieved the highest TAG conversion of 53.98%, with a MAG content of 16.86 ± 0.528% when it was performed at 120 °C with an agitator speed of 2,000 rpm for 6 h. Thus, the SMS-MgO 5.0:1 blend shows promise as a heterogeneous catalyst in glycerolysis reaction in HSCR, hindering agglomeration and enhancing surface area.

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Articles in this issue

DOI: https://doi.org/10.2478/pjct-2024-0035 | Journal eISSN: 3072-0389 (formerly 1899-4741) | Journal ISSN: 1509-8117

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Language: English

Page range: 17 - 24

Published online: Dec 31, 2024

Published in print: Dec 1, 2024

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

Basicity,

Catalyst Agglomeration,

Glycerolysis,

High Shear Compartment Reactor,

MgO-Sodium metasilicate blend.

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2024 Arief Rakhman Affandi, Ria Millati, Chusnul Hidayat, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons Attribution 4.0 License.

Volume 26 (2024): Issue 4 (December 2024)