Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water

Chen, Shuai; Qiao, Lemeng; Feng, Xuejiao; Huang, Yufu; Gao, Guilan; Guan, Jie; Lin, Donghai

doi:10.2478/pjct-2023-0003

Abstract

Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C and used as an adsorbent to remove methylene blue (MB) from water. The synthesized nZVI/CZIF-8 has a specific surface area of 806.9 m2/g, a pore volume of 0.86 cm³/g and an nZVI content of 1.35%, respectively. Both the nZVI/CZIF-8 and CZIF-8 have identical functional groups of O-H, C-H and C=C. With the increase of CZIF-8 size, MB removal rate increased. The doping of nZVI increased the MB removal percentage from 74.5% for ZIF-8 to 96.2% within 80 min for nZVI/CZIF-8. The MB removal percentage increased with the dosage of nZVI/CZIF-8. The MB adsorption with the adsorbents conforms to the Freundlich adsorption isothermal model and the removal rate fitted well to a pseudo-first-order model. The results demonstrate the feasibility of synthesizing high active and stable nZVI/CZIF-8 particles.

References

Rafatullah, M., Sulaiman, O., Hashim, R. & Ahmad, A. (2010). Adsorption of methylene blue on low-cost adsorbents: A review. J. Hazard. Mater., 177, 70–80. DOI: 10.1016/j.jhazmat.2009.12.047.20044207
Open DOI Search in Google Scholar Back to article
Fadillah, G., Saleh, T.A., Wahyuningsih, S., Ninda Karlina Putri, E. & Febrianastuti, S. (2019). Electrochemical removal of methylene blue using alginate-modified graphene adsorbents. Chem. Eng. J., 378, 122140. DOI: 10.1016/j.cej.2019.122140.
Open DOI Search in Google Scholar Back to article
Zhang, P., O’Connor, D., Wang, Y., Jiang, L., Xia, T., Wang, L., Tsang, D.C.W., Ok, Y.S. & Hou, D. (2020). A green biochar/iron oxide composite for methylene blue removal. J. Hazard. Mater., 384, 121286. DOI: 10.1016/j.jhazmat.2019.121286.31586920
Open DOI Search in Google Scholar Back to article
Salama, R.S., El-Sayed, E.-S.M., El-Bahy, S.M. & Awad, F.S. (2021). Silver nanoparticles supported on UIO-66 (Zr): As an efficient and recyclable heterogeneous catalyst and efficient adsorbent for removal of indigo carmine. Colloid. Surface. A, 626, 127089. DOI: 10.1016/j.colsurfa.2021.127089.
Open DOI Search in Google Scholar Back to article
Alshorifi, F.T., Ali, S.L. & Salama, R.S. (2022). Promotional synergistic effect of Cs–Au NPs on the performance of Cs–Au/MgFe₂O₄ catalysts in catalysis 3,4-dihydropyrimidin-2(1h)-ones and degradation of RhB dye. J. Inorg. Organomet. P., 32, 3765–3776. DOI: 10.1007/s10904-022-02389-8.
Open DOI Search in Google Scholar Back to article
Alshorifi, F.T., Alswat, A.A. & Salama, R.S. (2022). Gold-selenide quantum dots supported onto cesium ferrite nanocomposites for the efficient degradation of rhodamine B. Heliyon, 8, 6. DOI: 10.1016/j.heliyon.2022.e09652.918988935706958
Open DOI Search in Google Scholar Back to article
Ghosh, D. & Bhattacharyya, K.G. (2002). Adsorption of methylene blue on kaolinite. Appl. Clay Sci., 20, 295–300. DOI: 10.1016/S0169-1317(01)00081-3.
Open DOI Search in Google Scholar Back to article
El-Hakam, S.A., Alshorifi, F.T., Salama, R.S., Gamal, S., El-Yazeed, W.S.A., Ibrahim, A.A. & Ahmed, A.I. (2022). Application of nanostructured mesoporous silica/bismuth vanadate composite catalysts for the degradation of methylene blue and brilliant green. J. Mater. Res. Technol., 18, 1963–1976. DOI: 10.1016/j.jmrt.2022.03.067.
Open DOI Search in Google Scholar Back to article
Zhang, Y., Zheng, Y., Yang, Y., Huang, J., Zimmerman, A.R., Chen, H., Hu, X. & Gao, B. (2021). Mechanisms and adsorption capacities of hydrogen peroxide modified ball milled biochar for the removal of methylene blue from aqueous solutions. Bioresour. Technol., 337, 125432. DOI: 10.1016/j. biortech.2021.125432.
Open DOI Search in Google Scholar Back to article
Santoso, E., Ediati, R., Kusumawati, Y., Bahruji, H., Sulistiono, D.O. & Prasetyoko, D. (2020). Review on recent advances of carbon based adsorbent for methylene blue removal from waste water. Mate. Today Chem., 16, 100233. DOI: 10.1016/j.mtchem.2019.100233.
Open DOI Search in Google Scholar Back to article
Güleç, F., Williams, O., Kostas, E.T., Samson, A., Stevens, L.A. & Lester, E. (2022). A comprehensive comparative study on methylene blue removal from aqueous solution using biochars produced from rapeseed, whitewood, and seaweed via different thermal conversion technologies. Fuel, 330, 125428. DOI: 10.1016/j.fuel.2022.125428.
Open DOI Search in Google Scholar Back to article
Reyes-Miranda, J., Garcia-Murillo, A., Garrido-Hernández, A.& Carrillo-Romo, F.d.J. (2021). Fast and mild alkaline solvothermal synthesis of nanostructured flower-like Na2Ti₃O₇ and its methylene blue adsorption capacity. Mater. Lett., 292, 129589. DOI: 10.1016/j.matlet.2021.129589.
Open DOI Search in Google Scholar Back to article
Zhang, Z., Xu, L., Liu, Y., Feng, R., Zou, T., Zhang, Y., Kang, Y.& Zhou, P. (2021). Efficient removal of methylene blue using the mesoporous activated carbon obtained from mangosteen peel wastes: Kinetic, equilibrium, and thermodynamic studies. Micropor. Mesopor. Mat., 315, 110904. DOI: 10.1016/j.micromeso.2021.110904.
Open DOI Search in Google Scholar Back to article
Dai, K., Zhao, G., Kou, J., Wang, Z., Zhang, J., Wu, J., Yang, P., Li, M., Tang, C., Zhuang, W.& Ying, H. (2021). Magnetic mesoporous sodium citrate modified lignin for improved adsorption of calcium ions and methylene blue from aqueous solution. J. Environ. Chem. Eng., 9, 105180. DOI: 10.1016/j.jece.2021.105180.
Open DOI Search in Google Scholar Back to article
Ajeel, S.J., Beddai, A.A. & Almohaisen, A.M.N. (2021). Preparation of alginate/graphene oxide composite for methylene blue removal. Mater. Today: Proc., DOI: 10.1016/j. matpr.2021.05.331.
Open DOI Search in Google Scholar Back to article
Sharma, P., Olufemi, A.F. & Qanungo, K. (2021). Development of green geo-adsorbent pellets from low fire clay for possible use in methylene blue removal in aquaculture. Mater. Today: Proc., DOI: 10.1016/j.matpr.2021.07.343.
Open DOI Search in Google Scholar Back to article
Chandarana, H., Senthil Kumar, P., Seenuvasan, M. & Anil Kumar, M. (2021). Kinetics, equilibrium and thermodynamic investigations of methylene blue dye removal using casuarina equisetifolia pines. Chemosphere, 285, 131480. DOI: 10.1016/j. chemosphere.2021.131480.
Open DOI Search in Google Scholar Back to article
Ibrahim, A.A., Salama, R.S., El-Hakam, S.A., Khder, A.S. & Ahmed, A.I. (2021). Synthesis of sulfated zirconium supported MCM-41 composite with high-rate adsorption of methylene blue and excellent heterogeneous catalyst. Colloid. Surface. A, 616, 126361. DOI: 10.1016/j.colsurfa.2021.126361.
Open DOI Search in Google Scholar Back to article
Pasinszki, T., Krebsz, M., Chand, D., Kótai, L., Homonnay, Z., Sajó, I.E. & Váczi, T. (2020). Carbon microspheres decorated with iron sulfide nanoparticles for mercury(II) removal from water. J. Mater. Sci., 55, 1425–1435. DOI: 10.1007/s10853-019-04032-3.
Open DOI Search in Google Scholar Back to article
Wang, G., Gao, G., Yang, S., Wang, Z., Jin, P. & Wei, J. (2021). Magnetic mesoporous carbon nanospheres from renewable plant phenol for efficient hexavalent chromium removal. Micropor. Mesopor. Mat., 310, 110623. DOI: 10.1016/j.micromeso.2020.110623.
Open DOI Search in Google Scholar Back to article
Krebsz, M., Pasinszki, T., Tung, T.T., Nine, M.J. & Losic, D. (2021). Multiple applications of bio-graphene foam for efficient chromate ion removal and oil-water separation. Chemosphere, 263, 127790. DOI: 10.1016/j.chemosphere.2020.127790.32854003
Open DOI Search in Google Scholar Back to article
Pasinszki, T., Krebsz, M., Kótai, L., Sajó, I.E., Homonnay, Z., Kuzmann, E., Kiss, L.F., Váczi, T. & Kovács, I. (2015). Nanofurry magnetic carbon microspheres for separation processes and catalysis: Synthesis, phase composition, and properties. J. Mater. Sci., 50, 7353–7363. DOI: 10.1007/s10853-015-9292-6.
Open DOI Search in Google Scholar Back to article
Chen, S., Belver, C., Li, H., Ren, L.Y., Liu, Y.D., Bedia, J., Gao, G.L. & Guan, J. (2018). Effects of pH value and calcium hardness on the removal of 1,1,1-trichloroethane by immobilized nanoscale zero-valent iron on silica based supports. Chemosphere, 211, 102–111. DOI: 10.1016/j.chemo-sphere.2018.07.127.
Open DOI Search in Google Scholar Back to article
Sawafta, R. & Shahwan, T. (2019). A comparative study of the removal of methylene blue by iron nanoparticles from water and water-ethanol solutions. J. Mol. Liq., 273, 274–281. DOI: 10.1016/j.molliq.2018.10.010.
Open DOI Search in Google Scholar Back to article
Yang, B., Tian, Z., Zhang, L., Guo, Y.& Yan, S. (2015). Enhanced heterogeneous fenton degradation of methylene blue by nanoscale zero valent iron (nZVI) assembled on magnetic Fe₃O₄/reduced graphene oxide. J. Water Proc. Eng., 5, 101–111. DOI: 10.1016/j.jwpe.2015.01.006.
Open DOI Search in Google Scholar Back to article
Zhang, J., Zhang, T., Liang, X., Wang, Y., Shi, Y., Guan, W., Liu, D., Ma, X., Pang, J., Xie, X., Hong, K. & Wu, Z. (2020). Efficient photocatalysis of Cr(VI) and methylene blue by dispersive palygorskite-loaded zero-valent iron/carbon nitride. Appl. Clay Sci., 198, 105817. DOI: 10.1016/j.clay.2020.105817.
Open DOI Search in Google Scholar Back to article
Zhang, N., Eric, M., Zhang, C., Zhang, J., Feng, K., Li, Y. & Wang, S. (2021). ZVI impregnation altered arsenic sorption by ordered mesoporous carbon in presence of Cr(VI): A mechanistic investigation. J. Hazard. Mater., 414, 125507. DOI: 10.1016/j.jhazmat.2021.125507.34030402
Open DOI Search in Google Scholar Back to article
Xu, J., Wang, X., Pan, F., Qin, Y., Xia, J., Li, J. & Wu, F. (2018). Synthesis of the mesoporous carbon-nano-zero-valent iron composite and activation of sulfite for removal of organic pollutants. Chem. Eng. J., 353, 542–549. DOI: 10.1016/j. cej.2018.07.030.
Open DOI Search in Google Scholar Back to article
Chen, S., Li, Z., Belver, C., Gao, G., Guan, J., Guo, Y., Li, H., Ma, J., Bedia, J. & Wójtowicz, P. (2020). Comparison of the behavior of ZVI/carbon composites from both commercial origin and from spent Li-ion batteries and mill scale for the removal of ibuprofen in water. J. Environ. Manage., 264, 110480. DOI: 10.1016/j.jenvman.2020.110480.32250905
Open DOI Search in Google Scholar Back to article
Shi, J., Wang, J., Wang, W., Teng, W. & Zhang, W.-x. (2019). Stabilization of nanoscale zero-valent iron in water with mesoporous carbon (nZVI@MC). J. Environ. Sci., 81, 28–33. DOI: 10.1016/j.jes.2019.02.010.30975326
Open DOI Search in Google Scholar Back to article
Baikousi, M., Georgiou, Y., Daikopoulos, C., Bourlinos, A.B., Filip, J., Zbořil, R., Deligiannakis, Y. & Karakassides, M.A. (2015). Synthesis and characterization of robust zero valent iron/mesoporous carbon composites and their applications in arsenic removal. Carbon, 93, 636–647. DOI: 10.1016/j. carbon.2015.05.081.
Open DOI Search in Google Scholar Back to article
Gadipelli, S. & Guo, Z.X. (2015). Tuning of ZIF-derived carbon with high activity, nitrogen functionality, and yield – A case for superior CO₂ capture. Chem. Sus. Chem., 8, 2123–2132. DOI: 10.1002/cssc.201403402.451509725917928
Open DOI Search in Google Scholar Back to article
Aijaz, A., Fujiwara, N. & Xu, Q. (2014). From metal– organic framework to nitrogen-decorated nanoporous carbons: High CO₂ uptake and efficient catalytic oxygen reduction. J. Am. Chem. Soc., 136, 6790–6793. DOI: 10.1021/ja5003907.24786634
Open DOI Search in Google Scholar Back to article
Sann, E.E., Pan, Y., Gao, Z., Zhan, S. & Xia, F. (2018). Highly hydrophobic ZIF-8 particles and application for oil-water separation. Sep. Purif. Technol., 206, 186–191. DOI: 10.1016/j. seppur.2018.04.027.
Open DOI Search in Google Scholar Back to article
Pérez-Miana, M., Reséndiz-Ordóñez, J.U. & Coronas, J. (2021). Solventless synthesis of ZIF-l and ZIF-8 with hydraulic press and high temperature. Micropor. Mesopor. Mater., 328, 111487. DOI: 10.1016/j.micromeso.2021.111487.
Open DOI Search in Google Scholar Back to article
Qu, Y., Qin, L. & Liu, X. (2023). Carbonized ZIF-8/chitosan biomass imprinted hybrid carbon aerogel for phenol selective removal from wastewater. Carbohyd. Polym., 300, 120268. DOI: 10.1016/j.carbpol.2022.120268.36372491
Open DOI Search in Google Scholar Back to article
Jiang, X.-F., Wang, X.-B., Dai, P., Li, X., Weng, Q., Wang, X., Tang, D.-M., Tang, J., Bando, Y. & Golberg, D. (2015). High-throughput fabrication of strutted graphene by ammonium-assisted chemical blowing for high-performance supercapacitors. Nano Energy, 16, 81–90. DOI: 10.1016/j. nanoen.2015.06.008.
Open DOI Search in Google Scholar Back to article
Stobinski, L., Lesiak, B., Malolepszy, A., Mazurkiewicz, M., Mierzwa, B., Zemek, J., Jiricek, P. & Bieloshapka, I. (2014). Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. J. Electron Spectrosc., 195, 145–154. DOI: 10.1016/j.elspec.2014.07.003.
Open DOI Search in Google Scholar Back to article
Chen, S., Bedia, J., Li, H., Ren, L.Y., Naluswata, F. & Belver, C. (2018). Nanoscale zero-valent iron@mesoporous hydrated silica core-shell particles with enhanced dispersibility, transportability and degradation of chlorinated aliphatic hydrocarbons. Chem. Eng. J., 343, 619–628. DOI: 10.1016/j. cej.2018.03.011.
Open DOI Search in Google Scholar Back to article
Zhang, X., Lin, D. & Chen, W. (2015). Nitrogen-doped porous carbon prepared from a liquid carbon precursor for CO₂ adsorption. RSC Adv., 5, 45136–45143. DOI: 10.1039/c5ra08014b.
Open DOI Search in Google Scholar Back to article
Chen, X., Lu, K., Lin, D., Li, Y., Yin, S., Zhang, Z., Tang, M. & Chen, G. (2021). Hierarchical porous tubular biochar based sensor for detection of trace lead (II). Electroanalysis, 33, 473–482. DOI: 10.1002/elan.202060148.
Open DOI Search in Google Scholar Back to article
Lu, K.C., Wang, J.K., Lin, D.H., Chen, X., Yin, S.Y. & Chen, G.S. (2020). Construction of a novel electrochemical biosensor based on a mesoporous silica/oriented graphene oxide planar electrode for detecting hydrogen peroxide. Anal. Methods, 12, 2661–2667. DOI: 10.1039/d0ay00430h.32930296
Open DOI Search in Google Scholar Back to article
Yin, S., Wang, J., Li, Y., Wu, T., Song, L., Zhu, Y., Chen, Y., Cheng, K., Zhang, J., Ma, X., Lin,D. & Chen, G. (2021). Macroscopically oriented magnetic core-regularized nanomaterials for glucose biosensors assisted by self-sacrificial label. Electroanalysis, 33, 2216–2225. DOI: 10.1002/elan.202100231.
Open DOI Search in Google Scholar Back to article
Lin, D., Zhang, X., Cui, X. & Chen, W. (2014). Highly porous carbons with superior performance for CO₂ capture through hydrogen-bonding interactions. RSC Adv., 4, 27414–27421. DOI: 10.1039/c4ra04545a.
Open DOI Search in Google Scholar Back to article
Luan, Tran, B., Chin, H.-Y., Chang, B.K. & Chiang, A.S.T. (2019). Dye adsorption in ZIF-8: The importance of external surface area. Micropor. Mesopor. Mater., 277, 149–153. DOI: 10.1016/j.micromeso.2018.10.027.
Open DOI Search in Google Scholar Back to article
Yao, J., He, M., Wang, K., Chen, R., Zhong, Z. & Wang, H. (2013). High-yield synthesis of zeolitic imidazolate frameworks from stoichiometric metal and ligand precursor aqueous solutions at room temperature. Cryst. Eng. Comm., 15, 3601–3606. DOI: 10.1039/C3CE27093A.
Open DOI Search in Google Scholar Back to article
Guan, X., Sun, Y., Qin, H., Li, J., Lo, I.M.C., He, D. & Dong, H. (2015). The limitations of applying zero-valent iron technology in contaminants sequestration and the corresponding countermeasures: The development in zero-valent iron technology in the last two decades (1994–2014). Water Res., 75, 224–248. DOI: 10.1016/j.watres.2015.02.034.25770444
Open DOI Search in Google Scholar Back to article
Albadarin, A.B., Collins, M.N., Naushad, M., Shirazian, S., Walker, G. & Mangwandi, C. (2017). Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue. Chem. Eng. J., 307, 264–272. DOI: 10.1016/j.cej.2016.08.089.
Open DOI Search in Google Scholar Back to article

Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water

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