Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods

Doroudi, Zohreh; Niazi, Ali

doi:10.2478/pjct-2018-0004

Abstract

A fast, simple, and economical method for extraction, preconcentration and determination of cobalt, nickel and copper as their 1-(2-pyridilazo) 2-naphthol (PAN) complexes based on ultrasound-assisted emulsification–microextraction (USAEME) and multivariate calibration of spectrophotometric data is presented. Various parameters affecting the extraction efficiency were optimized both with univariate and Box–Behnken design. The resolution of ternary mixtures of these metallic ions was accomplished by using partial least-squares regression (PLS), orthogonal signal correction-partial least-squares regression (OSC-PLS), and orthogonal signal correction-genetic algorithmspartial least-squares regression (OSC-GA-PLS). Under the optimum conditions, the calibration graphs were linear in the range of 2.0–150.0, 2.0–120.0 and 2.0–150.0 ng mL⁻¹ for Co²⁺, Ni²⁺, and Cu²⁺, respectively, with a limit of detection of 0.14 (Co²⁺), 0.13 (Ni²⁺) and 0.14 ng mL⁻¹ (Cu²⁺) and the relative standard deviation was <2.5%. The method was successfully applied to the simultaneous determination of these cations in different samples.

References

1. Hedberg, Y., Herting, G. & Wallinder, I.O. (2011). Risks of using membrane filtration for trace metal analysis and assessing the dissolved metal fraction of aqueous media – A study on zinc, copper and nickel. Environ. Pollut. 159(5), 1144–1150. DOI: 10.1016/j.envpol.2011.02.014.10.1016/j.envpol.2011.02.01421367497
Open DOI Search in Google Scholar Back to article
2. Şengil, I.A. & Özacar, M. (2008). Biosorption of Cu(II) from aqueous solutions by mimosa tannin gel. J. Hazard. Mater. 157(2–3), 277–285. DOI: 10.1016/j.jhazmat.2007.12.115.10.1016/j.jhazmat.2007.12.11518289780
Open DOI Search in Google Scholar Back to article
3. Regueiroa, J., Lomparta, M., Garcia-Jaresa, C., Garcia-Monteagudob, J.C. & Celaa, R. (2008). Ultrasound-assisted emulsification–microextraction of emergent contaminants and pesticides in environmental waters. J. Chromatogr. A 1190(1–2), 27–38. DOI: 10.1016/j.chroma.2008.02.091.10.1016/j.chroma.2008.02.09118359033
Open DOI Search in Google Scholar Back to article
4. Feng, J., Qiu, H., Liu, X. & Jiang, Sh. (2013). The development of solid-phase microextraction fibers with metal wires as supporting substrates. TrAC, Trends Anal. Chem. 46, 44–58. DOI: 10.1016/j.trac.2013.01.015.10.1016/j.trac.2013.01.015
Open DOI Search in Google Scholar Back to article
5. Su, Sh., Chen, B., He, M. & Hu, B. (2014). Graphene oxide–silica composite coating hollow fiber solid phase microextraction online coupled with inductively coupled plasma mass spectrometry for the determination of trace heavy metals in environmental water samples. Talanta 123, 1–9. DOI: 10.1016/j.talanta.2014.01.061.10.1016/j.talanta.2014.01.06124725857
Open DOI Search in Google Scholar Back to article
6. Miró, M. & Hansen, E.H. (2013). On-line sample processing involving microextraction techniques as a front-end to atomic spectrometric detection for trace metal assays: A review. Anal. Chim. Acta 782, 1–11. DOI: 10.1016/j.aca.2013.03.019.10.1016/j.aca.2013.03.01923708278
Open DOI Search in Google Scholar Back to article
7. Sereshti, H., Khojeh, V. & Samadi, S. (2011). Optimization of dispersive liquid–liquid microextraction coupled with inductively coupled plasma-optical emission spectrometry with the aid of experimental design for simultaneous determination of heavy metals in natural waters. Talanta 83(3), 885–890. DOI: 10.1016/j.talanta.2010.10.052.10.1016/j.talanta.2010.10.05221147333
Open DOI Search in Google Scholar Back to article
8. Mirzaei, M., Behzadi, M., Mahmoud Abadi, N. & Beizaei, A. (2011). Simultaneous separation/preconcentration of ultra-trace heavy metals in industrial wastewaters by dispersive liquid–liquid microextraction based on solidification of floating organic drop prior to determination by graphite furnace atomic absorption spectrometry. J. Hazard. Mater. 186(2–3), 1739–1743. DOI: 10.1016/j.jhazmat.2010.12.080,10.1016/j.jhazmat.2010.12.08021232852
Search in Google Scholar Back to article
9. Stanisz, E., Werner, J. & Zgoła-Grześkowia, A. (2014). Liquid-phase microextraction techniques based on ionic liquids for preconcentration and determination of metals. TrAC, Trends Anal. Chem. 61, 54–66. DOI: 10.1016/j.trac.2014.06.008.10.1016/j.trac.2014.06.008
Open DOI Search in Google Scholar Back to article
10. Deng, Q., Chen, M., Kong, L., Zhao, X., Guo, J. & Wen, X. (2013). Novel coupling of surfactant assisted emulsification dispersive liquid–liquid microextraction with spectrophotometric determination for ultra-trace nickel. Spectrochim. Acta, Part A 104, 64–69. DOI: 10.1016/j.saa.2012.10.080.10.1016/j.saa.2012.10.08023266677
Search in Google Scholar Back to article
11. Rezaee, M., Assadi, Y., Milani Hosseini, M.R., Aghaee, E., Ahmadi, F. & Berijani, S., (2006). Determination of organic compounds in water using dispersive liquid-liquid microextraction. J. Chromatogr. A 1116(1–2), 1–9. DOI: 10.1016/j.chroma.2006.03.007.10.1016/j.chroma.2006.03.007
Open DOI Search in Google Scholar Back to article
12. Takagai, Y., Akiyama R. & Igarashi, S. (2006). Powerful preconcentration method for capillary electrophoresis and its application to ultra-trace amounts of polycyclic aromatic hydrocarbons analyses. Anal. Bioanal. Chem. 385(5), 888–894. DOI: 10.1007/s00216-006-0447-9.10.1007/s00216-006-0447-9
Open DOI Search in Google Scholar Back to article
13. Andruch, V., Balogh, I.S., Burdel, M., Kocúrová, L. & Šandrejová, J. (2013). Application of ultrasonic irradiation and vortex agitation in solvent microextraction. TrAC, Trends Anal. Chem. 49, 1–19. DOI: org/10.1016/j.trac.2013.02.006.10.1016/j.trac.2013.02.006
Open DOI Search in Google Scholar Back to article
14. Jiang, H., Qin, Y. & Hu, B. (2008). Dispersive liquid phase microextraction (DLPME) combined with graphite furnace atomic absorption spectrometry (GFAAS) for determination of trace Co and Ni in environmental water and rice samples. Talanta 74(5), 1160–1165. DOI: 10.1016/j.talanta.2007.08.022.10.1016/j.talanta.2007.08.022
Open DOI Search in Google Scholar Back to article
15. Anthemidis, A.N. & Ioannou, K.I.G. (2011). Sequential injection dispersive liquid–liquid microextraction based on fatty alcohols and poly(etheretherketone)-turnings for metal determination by flame atomic absorption spectrometry. Talanta 84, 1215–1220. DOI: 10.1016/j.talanta.2010.12.017.10.1016/j.talanta.2010.12.017
Open DOI Search in Google Scholar Back to article
16. Sereshti, H., Entezari Heravi, Y. & Samadi, S. (2012). Optimized Ultrasound-Assisted Emulsification Microextraction for Simultaneous Trace Multielement Determination of Heavy Metals in Real Water Samples by ICP-OES. Talanta 97, 235–241. DOI: org/10.1016/j.talanta.2012.04.024.10.1016/j.talanta.2012.04.024
Open DOI Search in Google Scholar Back to article
17. Oliveira, E.P., Yang, L., Sturgeon, R.E., Santelli, R.E., Bezerra, M.A., Willie, S.N. & Capilla, R. (2011). Determination of trace metals in high-salinity petroleum produced formation water by inductively coupled plasma mass spectrometry following on-line analyte separation/preconcentration. J. Anal. At. Spectrom. 26(3), 578–585. DOI: 10.1039/c0ja00108b.10.1039/c0ja00108b
Open DOI Search in Google Scholar Back to article
18. Karim-Nezhad, G., Saghatforoush L. & Ershad, S. (2009). Simultaneous Determination of Copper and Iron in Biological Samples with 1-(2-Pyridylazo)-2-naphthol in Anionic AOT Micellar Solution Using Derivative Spectrophotometry. Asian J. Chem. 21(2), 2565–2572.
Search in Google Scholar Back to article
19. Niazi, A. & Yazdanipour, A. (2008). Simultaneous spectrophotometric determination of cobalt, copper and nickel using 1-(2-thiazolylazo)-2-naphthol by chemometrics methods. Chin. Chem. Lett. 19(7), 860–864. DOI: 10.1016/j.cclet.2008.04.047.10.1016/j.cclet.2008.04.047
Open DOI Search in Google Scholar Back to article
20. Saavedra, R., Soto, C., Gómez, R. & Muñoz, A. (2013). Determination of lead(II) by thermal lens spectroscopy (TLS) using 2-(2′-thiazolylazo)-p-cresol (TAC) as chromophore reagent. Microchem. J. 110, 308–313. DOI: 10.1016/j.microc.2013.04.019.10.1016/j.microc.2013.04.019
Open DOI Search in Google Scholar Back to article
21. Niazi, A. & Azizi, A. (2008). Orthogonal Signal Correction – Partial Least Squares Method for Simultaneous Spectrophotometric Determination of Nickel, Cobalt, and Zinc. Turk. J. Chem. 32, 217–228.
Search in Google Scholar Back to article
22. Hejazi, L., Mohammadi, D.E., Yamini, Y. & Brereton, R.G. (2004). Solid-phase extraction and simultaneous spectrophotometric determination of trace amounts of Co, Ni and Cu using partial least squares regression. Talanta 62(1), 185–191 DOI: 10.1016/S0039-9140(03)00412-0.10.1016/S0039-9140(03)00412-0
Open DOI Search in Google Scholar Back to article
23. Niazi, A., Azizi A. & Ramezani, M. (2008). Simultaneous spectrophotometric determination of mercury and palladium with Thio-Michler’s Ketone using partial least squares regression and orthogonal signal correction. Spectrochim. Acta, Part A 71 (3), 1172–1177. DOI: 10.1016/j.saa.2008.03.017.10.1016/j.saa.2008.03.017
Open DOI Search in Google Scholar Back to article
24. Niazi, A. (2006). Simultaneous Determination of Uranium and Thorium Using Partial Least Squares Regression and Orthogonal Signal Correction. J. Braz. Chem. Soc. 17, 1020–1026. DOI: org/10.1590/S0103-50532006000500029.10.1590/S0103-50532006000500029
Open DOI Search in Google Scholar Back to article
25. Tarighat, M.A. & Afkhami, A. (2012). Spectrophotometric Determination of Cu(II), Co(II) and Ni(II) using Ratio Spectra Continuous Wavelet Transformation in some Food and Environmental Samples. J. Braz. Chem. Soc. 23, 1312–1319. DOI: org/10.1590/S0103-50532012000700016.10.1590/S0103-50532012000700016
Open DOI Search in Google Scholar Back to article
26. Leardi, R. (2001). Genetic algorithms in chemometrics and chemistry: a review. J. Chemom. 15, 559–569. DOI: 10.1002/cem.651.10.1002/cem.651
Open DOI Search in Google Scholar Back to article
27. Ghasemi, J., Niazi A. & Leardi, R. (2003). Genetic-algorithm-based wavelength selection in multicomponent spectrophotometric determination by PLS: application on copper and zinc mixture. Talanta 59(2), 311–317. DOI:10.1016/S0039-9140(02)00505-2.10.1016/S0039-9140(02)00505-2
Open DOI Search in Google Scholar Back to article
28. Niazi, A., Soufi, A. & Mobarakabadi, M. (2006). Genetic Algorithm Applied to Selection of Wavelength in Partial Least Squares for Simultaneous Spectrophotometric Determination of Nitrophenol Isomers. Anal. Lett. 39(11), 2359–2372. DOI: 10.1080/00032710600751016.10.1080/00032710600751016
Open DOI Search in Google Scholar Back to article
29. Ghasemi, J., Ebrahimi, D.M., Hejazi, L., Leardi R. & Niazi, A. (2007). Simultaneous kinetic-spectrophotometric determination of sulfide and sulfite by partial least squares and genetic algorithm variable selection. J. Anal. Chem. 62 (4), 348–354. DOI: 10.1134/S1061934807040090.10.1134/S1061934807040090
Open DOI Search in Google Scholar Back to article
30. Niazi, A. & Leardi, R. (2012). Genetic algorithms in chemometrics. J. Chemom. 26(6), 345–351. DOI: 10.1002/cem.2426.10.1002/cem.2426
Open DOI Search in Google Scholar Back to article
31. Karbakhsh, R. & Sabet, R. (2011). Application of different chemometric tools in QSAR study of azoloadamantanes against influenza A virus. Res. Pharm. Sci. 6(1), 23–33.
Search in Google Scholar Back to article
32. Lurie, J.J. (1978). Handbook of Analytical Chemistry. Moscow: Mir Publishers.
Search in Google Scholar Back to article
33. Niazi, A., Khorshidi N. & Ghaemmaghami, P. (2015). Microwave-assisted of dispersive liquid–liquid microextraction and spectrophotometric determination of uranium after optimization based on Box–Behnken design and chemometrics methods. Spectrochim. Acta, Part A 135, 69–75. DOI: 0.1016/j.saa.2014.06.148.10.1016/j.saa.2014.06.14825062051
Search in Google Scholar Back to article
34. Box, E.P. & Behnken, D. W. (1960). Some new three-level designs for the study of quantitative variables. Technometrics 2, 455–475.10.1080/00401706.1960.10489912
Search in Google Scholar Back to article
35. Chopra, S., Patil, G.V. & Motwani, S.K. (2007). Release modulating hydrophilic matrix systems of losartan potassium: optimization of formulation using statistical experimental design. Eur. J. Pharm. Biopharm. 66(1), 73–82. DOI: 10.1016/j.ejpb.2006.09.001.10.1016/j.ejpb.2006.09.001
Open DOI Search in Google Scholar Back to article
36. Yetilmezsoy, K., Demirel, S. & Vanderbei, R.J. (2009). Response surface modeling of Pb (II) removal from aqueous solution by Pistacia vera L.: Box–Behnken experimental design. J. Hazard. Mater. 171(1–3), 551–562. DOI: 10.1016/j.jhazmat.2009.06.035.10.1016/j.jhazmat.2009.06.035
Open DOI Search in Google Scholar Back to article
37. Shokoufi, N., Shemirani, F. & Assadi, Y. (2007). Fiber optic-linear array detection spectrophotometry in combination with dispersive liquid-liquid microextraction for simultaneous preconcentration and determination of palladium and cobalt. Anal. Chim. Acta 597(2), 349–356. DOI: 10.1016/j.aca.2007.07.009.10.1016/j.aca.2007.07.009
Open DOI Search in Google Scholar Back to article
38. Jaggi, S. & Gupta, U. (2013). Solid phase extraction and preconcentration of Ni(II) using 1-(2-pyridylazo)-2-naphthol) (PAN) modified β-cyclodextrin butanediol diglycidyl ether polymer as a solid phase extractant. Maced. J. Chem. Chem. En. 32(1), 57–67.10.20450/mjcce.2013.86
Search in Google Scholar Back to article
39. Gharehbaghi, M., Shemirani, F. & Baghdadi, M. (2008). Dispersive liquid–liquid microextraction and spectrophotometric determination of cobalt in water samples. Int. J. Environ. Anal. Chem. 88, 513–523. DOI: 10.1080/03067310701809128.10.1080/03067310701809128
Open DOI Search in Google Scholar Back to article
40. Shokoufi, N., Shemirani, F. & Memarzadeh, F. (2007). Fiber optic-linear array detection spectrophotometry in combination with cloud point extraction for simultaneous preconcentration and determination of cobalt and nickel. Anal. Chim. Acta 601(2), 204–211. DOI: 10.1016/j.aca.2007.08.042.10.1016/j.aca.2007.08.042
Open DOI Search in Google Scholar Back to article
41. Wold, S., Antii, H., Lindgren, F. & Ohman, J. (1998). Orthogonal signal correction of near-infrared spectra. Chemom. Intell. Lab. Syst. 44, 175–185.10.1016/S0169-7439(98)00109-9
Open DOI Search in Google Scholar Back to article

Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods

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