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Intermediates derived from p-terphenyl in the methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid saturated with carbon dioxide: Pulse radiolysis study Cover

Intermediates derived from p-terphenyl in the methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid saturated with carbon dioxide: Pulse radiolysis study

Nukleonika
Volume 67 (2022): Issue 4 (December 2022)
By: Rafał Kocia  
Open Access
|Jan 2023

Figures & Tables

Fig. 1

Transient absorption spectra registered after pulse irradiation of carbon dioxide (A), argon (B), and oxygen (C) saturated solutions of [MeBu3N][NTf2] IL containing 14 mM TP after the following time delays on the spectra shown, respectively. The dose applied was 18 Gy.

Fig. 2

The absorbance measured at λ = 470 nm as a function of the logarithm of time after pulse irradiation of carbon dioxide-saturated [MeBu3N][NTf2] IL solutions containing 14 mM TP.

Fig. 3

Transient absorption spectra registered after pulse irradiation of carbon dioxide-saturated solutions of [MeBu3N][NTf2] IL containing 14 mM TP and 0.22 mM TEA after the following time delays: 40 ns (circles), 100 ns (up triangles), 2 μs (squares), 10 μs (down triangles), 25 μs (stars), and 100 μs (diamonds). The dose applied was 18 Gy.

Fig. 4

The absorbance measured at λ = 450 nm (black circles), λ = 470 nm (red squares), and λ = 475 nm (blue up triangles) as a function of the logarithm of time after pulse irradiation of carbon dioxide-saturated [MeBu3N] [NTf2] IL solutions containing 14 mM TP and 0.22 mM TEA.
DOI: https://doi.org/10.2478/nuka-2022-0007 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922
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Language: English
Page range: 73 - 80
Submitted on: Oct 26, 2022
|
Accepted on: Dec 2, 2022
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Published on: Jan 20, 2023
Published by: Institute of Nuclear Chemistry and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year
Keywords:
Carbon dioxide,
Ionic liquid,
Methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide,
p-Terphenyl,
Pulse radiolysis,
Radical ions
Related subjects:
Chemistry,
Nuclear chemistry,
Physics,
Astronomy and astrophysics,
Physics, other

© 2023 Rafał Kocia, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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