Intermediates derived from p-terphenyl in the methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid saturated with carbon dioxide: Pulse radiolysis study

Rafał Kocia

doi:10.2478/nuka-2022-0007

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Intermediates derived from p-terphenyl in the methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid saturated with carbon dioxide: Pulse radiolysis study

Nukleonika

Volume 67 (2022): Issue 4 (December 2022)

By: Rafał Kocia

Open Access

|Jan 2023

Abstract

Radiation-induced processes in ionic liquid (IL) methyltributylammonium bis[(trifluoromethyl)sulfonyl] imide ([MeBu₃N][NTf₂]) solutions containing p-terphenyl (TP) and saturated with carbon dioxide (CO₂) were studied using nanosecond pulse radiolysis technique with UV-vis detection. The transient absorption spectra generated in these solutions were assigned to TP radical anions (TP^•−) and triplet excited states (³TP*). Saturation of [MeBu₃N][NTf₂] solutions with carbon dioxide efficiently takes out presolvated electrons $(e_{presolv}^{-})$ ( {{\rm{e}}_{{\rm{presolv}}}^ - } ) and solvated electrons $(e_{solv}^{-})$ ( {{\rm{e}}_{{\rm{solv}}}^ - } ) . On the other hand CO₂ is not a scavenger of excited states of TP (¹TP*, ³TP*), which in the reaction with triethylamine (TEA) leads to the formation of TP^•−.

References

Welton, T. (1999). Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem. Rev., 99(8), 2071–2084. DOI: 10.1021/cr980032t.
Open DOI Search in Google Scholar Back to article
Wasserscheid, P., & Keim, W. (2000). Ionic liquids – new “solutions” for transition metal catalysis. Angew. Chem. Int. Ed., 39(21), 3772–3789. DOI: 1433-7851/00/3921-3773.
Open DOI Search in Google Scholar Back to article
Earle, M. J., & Seddon, K. R. (2000). Ionic liquids. Green solvents for the future. Pure Appl. Chem., 72(7), 1391–1398. DOI: 10.1351/pac200072071391.
Open DOI Search in Google Scholar Back to article
Rogers, R. D., & Seddon, K. R. (2002). Ionic liquids: Industrial applications to green chemistry. Washington, USA: The American Chemical Society.
Search in Google Scholar Back to article
Chiappe, C., & Pieraccini, D. (2005). Ionic liquids: Solvent properties and organic reactivity. J. Phys. Org. Chem., 18(4), 275–297. DOI: 10.1002/poc.863.
Open DOI Search in Google Scholar Back to article
Jain, N., Kumar, A., Chauhan, S., & Chauhan, S. M. S. (2005). Chemical and biochemical transformations in ionic liquids. Tetrahedron, 61, 1015–1060. DOI: 10.1016/j.tet.2004.10.070.
Open DOI Search in Google Scholar Back to article
Zhao, H., Xia, S., & Ma, P. (2005). Use of ionic liquids as ‘green’ solvents for extractions. J. Chem. Technol. Biotechnol., 80(10), 1089–1096. DOI: 10.1002/jctb.1333.
Open DOI Search in Google Scholar Back to article
Weyershausen, B., & Lehmann, K. (2005). Industrial application of ionic liquids as performance additives. Green Chem., 7(1), 15–19. DOI: 10.1039/b411357h.
Open DOI Search in Google Scholar Back to article
Endres, F., & El Abedin, S. Z. (2006). Air and water stable ionic liquids in physical chemistry. Phys. Chem. Chem. Phys., 8(18), 2101–2116. DOI: 10.1039/b600519p.
Open DOI Search in Google Scholar Back to article
Hough, W. L., Smiglak, M., Rodríguez, H., Swatloski, R. P., Spear, S. K., Daly, D. T., Pernak, J., Grisel, J. E., Carliss, R. D., Soutullo, M. D., Davis, Jr. J. H., & Rogers, R. D. (2007). The third evolution of ionic liquids: active pharmaceutical ingredients. New J. Chem., 31(8), 1429–1436. DOI: 10.1039/b706677p.
Open DOI Search in Google Scholar Back to article
Plechkova, N. V., & Seddon, K. R. (2008). Applications of ionic liquids in the chemical industry. Chem. Soc. Rev., 37(1), 123–150. DOI: 10.1039/b006677j.
Open DOI Search in Google Scholar Back to article
Armand, M., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009). Ionic-liquid materials for the electrochemical challenges of the future. Nat. Mater., 8(8), 621–629. DOI: 10.1038/nmat2448.
Open DOI Search in Google Scholar Back to article
U.S. Department of Energy National Energy Technology Laboratory. (2013). Program Plan Carbon Capture. Albany: U.S. Department of Energy, Office of Fossil Energy, National Energy Technology Laboratory, Strategic Center for Coal. www.netl.doe.gov/technologies/carbon_seq/core_rd/co2capture.html.2009.
Search in Google Scholar Back to article
Houghton, J. T., Ding, Y., Griggs, D. J., Noguer, M., van der Linden, P. J., Dai, X., Maskell, K., & Johnson, C. A. (2001). Climate change 2001: The scientific basis. Contribution of working group I to the third assessment report of the intergovernmental panel on climate change. Cambridge, UK: Cambridge University Press.
Search in Google Scholar Back to article
Bates, E. D., Mayton, R. D., Ntai, I., & Davis, Jr. J. H. (2002) CO₂ capture by a task-specific ionic liquid. J. Am. Chem. Soc., 124(6), 926–927. DOI: 10.1021/ja017593d.
Open DOI Search in Google Scholar Back to article
Bara, J. E., Camper, D. E., Gin, D. L., & Noble, R. D. (2010). Room-temperature ionic liquids and composite materials: platform technologies for CO₂ capture. Acc. Chem. Res., 43(1), 152–159. DOI: 10.1021/ar9001747.
Open DOI Search in Google Scholar Back to article
Zhang, Z., Hu, S., Song, J., Li, W., Yang, G., & Han, B. (2009). Hydrogenation of CO₂ to formic acid promoted by a diamine-functionalized ionic liquid. ChemSus-Chem., 2(3), 234–238. DOI: 10.1002/cssc.200800252.
Open DOI Search in Google Scholar Back to article
Ghavre, M., Morrissey, S., & Gathergood, N. (2011). Hydrogenation in ionic liquid. In A. Kokorin (Ed.), Ionic liquids: Applications and perspectives (pp. 331–392). Rijeka, Croatia, HR: InTech Open Access Publisher.
Search in Google Scholar Back to article
Blanchard, L. A., Gu, Z. Y., & Brennecke, J. F. (2001). High-pressure phase behavior of ionic liquid/CO₂ systems. J. Phys. Chem. B, 105(12), 2437–2444. DOI: 10.1021/jp003309d.
Open DOI Search in Google Scholar Back to article
Buzzeo, M. C., Klymenko, O. V., Wadhawan, J. D., Hardacre, C., Seddon, K. R., & Compton, R. G. (2004). Kinetic analysis of the reaction between electrogenerated superoxide and carbon dioxide in the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and hexyltriethylammonium bis(trifluoromethyl-sulfonyl) imide. J. Phys. Chem. B, 108(12), 3947–3954. DOI: 10.1021/jp031121z.
Open DOI Search in Google Scholar Back to article
Aki, S. N. V. K., Mellein, B. R., Saurer, E. M., & Brennecke, J. F. (2004). High-pressure phase behavior of carbon dioxide with imidazolium-based ionic liquids. J. Phys. Chem. B, 108(52), 20355–20365. DOI: 10.1021/jp046895+.
Open DOI Search in Google Scholar Back to article
Anthony, J. L., Anderson, J. L., Maginn, E. J., & Brennecke, J. F. (2005). Anion effects on gas solubility in ionic liquids. J. Phys. Chem. B, 109(13), 6366–6374. DOI: 10.1021/jp046404l.
Open DOI Search in Google Scholar Back to article
Cadena, C., Anthony, J. L., Shah, J. K., Morrow, T. I., Brennecke, J. F., & Maginn, E. J. (2004). Why is CO₂ so soluble in imidazolium-based ionic liquids? J. Am. Chem. Soc., 126(16), 5300–5308. DOI: 10.1021/ja039615x.
Open DOI Search in Google Scholar Back to article
Ohlin, C. A., Dyson, P. J., & Laurenczy, G. (2004). Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation. Chem. Commun., 35(9), 1070–1071. DOI: 10.1039/b401537a.
Open DOI Search in Google Scholar Back to article
Husson-Borg, P., Majer, V., & Costa Gomes, M. F. (2003). Solubilities of oxygen and carbon dioxide in butylmethylimidazolium tetrafluoroborate as a function of temperature and at pressures close to atmospheric pressure. J. Chem. Eng. Data, 48(3), 480–485. DOI: 10.1021/je0256277.
Open DOI Search in Google Scholar Back to article
Pérez-Salado Kamps, Á., Tuma, D., Xia, J., & Maurer, G. (2003). Solubility of CO₂ in the ionic liquid [bmim][PF₆]. J. Chem. Eng. Data, 48(3), 746–749. DOI: 10.1021/je034023f.
Open DOI Search in Google Scholar Back to article
Evans, R. G., Klymenko, O. V., Saddoughi, S. A., Hardacre, C., & Compton, R. G. (2004). Electroreduction of oxygen in a series of room temperature ionic liquids composed of group 15-centered cations and anions. J. Phys. Chem. B, 108(23), 7878–7886. DOI: 10.1021/jp031309i.
Open DOI Search in Google Scholar Back to article
Dyson, P. J., Laurenczy, G., Ohlin, C. A., Vallance, J., & Welton, T. (2003). Determination of hydrogen concentration in ionic liquids and the effect (or lack of) on rates of hydrogenation. Chem. Commun., 9(19), 2418–2419. DOI: 10.1039/B308309H.
Open DOI Search in Google Scholar Back to article
Neftel, A., Moor, E., Oeschger, H., & Stauffer, B. (1985). Evidence from polar ice cores for the increase in atmospheric CO₂ in the past two centuries. Nature, 315(6014), 45–47. DOI: 10.1038/315045a0.
Open DOI Search in Google Scholar Back to article
Harvey, F. (2009, May). The Guardian. Retrieved November 23, 2020, from http://www.guardian.co.uk/environment/2011/may/29/carbon-emissions-nuclearpower.
Search in Google Scholar Back to article
Peng, J., & Deng, Y. (2001). Cycloaddition of carbon dioxide to propylene oxide catalyzed by ionic liquids. New J. Chem., 25(4), 639–641. DOI: 10.1039/B008923K.
Open DOI Search in Google Scholar Back to article
Yang, H., Gu, Y., Deng, Y., & Shi, F. (2002). Electrochemical activation of carbon dioxide in ionic liquids: synthesis of cyclic carbonates at mild reaction conditions. Chem. Commun., 33(3), 274–275. DOI: 10.1039/B108451H.
Open DOI Search in Google Scholar Back to article
Harmon, C. D., Smith, W. H., & Costa, D. A. (2001). Criticality calculations for plutonium metal at room temperature in ionic liquid solutions. Radiat. Phys. Chem., 60(3), 157–159. DOI: 10.1016/S0969-806X(00)00336-4.
Open DOI Search in Google Scholar Back to article
Behar, D., Gonzales, C., & Neta, P. (2001). Reaction kinetics in ionic liquids: Pulse radiolysis studies of 1-butyl-3-methylimidazolium salts. J. Phys. Chem. A, 105(32), 7607–7614. DOI: 10.1021/jp011405o.
Open DOI Search in Google Scholar Back to article
Marcinek, A., Zielonka, J., Gębicki, J., Gordon, C. M., & Dunkin, I. R. (2001). Ionic liquids: Novel media for characterization of radical ions. J. Phys. Chem. A, 105(40), 9305–9309. DOI: 10.1021/jp0117718.
Open DOI Search in Google Scholar Back to article
Behar, D., Neta, P., & Schultheisz, C. (2002). Reaction kinetics in ionic liquids as studied by pulse radiolysis: Redox reactions in the solvents methyltributylammonium bis(trifluoromethylsulphonyl)imide and n-butylpyridinium tetrafluoroborate. J. Phys. Chem. A, 106(13), 3139–3147. DOI: 10.1021/jp013808u.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., & Neta. P. (2002). Reaction kinetics in the ionic liquid methyltributylammonium bis(trifluoromethylsulfonyl)imide. Pulse radiolysis study of ^·CF₃ radical reactions. J. Phys. Chem. A, 106(22), 5468–5473. DOI: 10.1021/jp020165p.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., & Neta, P. (2002). Reaction kinetics in the ionic liquid methyltributylammonium bis(trifluoromethylsulfonyl)imide. Pulse radiolysis study of 4-mercaptobenzoic acid. J. Phys. Chem. A, 106(39), 9030–9035. DOI: 10.1021/jp020806g.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., & Neta, P. (2002). Formation and reaction of Br₂^·− radicals in the ionic liquid methyltributylammonium bis(trifluoromethylsulfonyl)imide and in other solvents. J. Phys. Chem. A, 106(46), 11130–11134. DOI: 10.1021/jp021498p.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., Neta, P., & Wishart, J. F. (2003). Pulse radiolysis study of the reactions of hydrogen atoms in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide. J. Phys. Chem. A, 107(46), 9794–9799. DOI: 10.1021/jp035265p.
Open DOI Search in Google Scholar Back to article
Wishart, J. F., & Neta, P. (2003). Spectrum and reactivity of the solvated electron in the ionic liquid methyltributylammonium bis(trifluoromethylsulfonyl) imide. J. Phys. Chem. B, 107(30), 7261–7267. DOI: 10.1021/jp027792z.
Open DOI Search in Google Scholar Back to article
Skrzypczak, A., & Neta, P. (2003). Diffusion-controlled electron-transfer reactions in ionic liquids. J. Phys. Chem. A, 107(39), 7800–7803. DOI: 10.1021/jp030416+.
Open DOI Search in Google Scholar Back to article
Skrzypczak, A., & Neta, P. (2004). Rate constants for reaction of 1,2-dimethylimidazole with benzyl bromide in ionic liquids and organic solvents. Int. J. Chem. Kinet., 36(4), 253–258. DOI: 10.1002/kin.10162.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., Nyga, M., & Mirkowski, J. (2005). Formation of Br₂^·−, BrSCN^·− and (SCN)₂^·− intermediates in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide. Pulse radiolysis study. Nukleonika, 50(Suppl. 2), S35–S38.
Search in Google Scholar Back to article
Wishart, J. F., Lall-Ramnarine, S. I., Rajub, R., Scumpia, A., Bellevue, S., Ragbir, R., & Engel, R. (2005). Effects of functional group substitution on electron spectra and solvation dynamics in a family of ionic liquids. Radiat. Phys. Chem., 72(2/3), 99–104. DOI: 10.1016/j.radphyschem.2004.09.005.
Open DOI Search in Google Scholar Back to article
Yang, J., Kondoh, T., Norizawa, K., Nagaishi, R., Taguchi, M., Takahashi, K., Katoh, R., Anishchik, S. V. R., Yoshida, Y., & Tagawa, S. (2008). Picosecond pulse radiolysis: dynamics of solvated electrons in ionic liquid and geminate ion recombination in liquid alkanes. Radiat. Phys. Chem., 77(10/12), 1233–1238. DOI: 10.1016/j.radphyschem.2008.05.031.
Open DOI Search in Google Scholar Back to article
Takahashi, K., Sato, T., Katsumura, Y., Yang, J., Kondoh, T., Yoshida, Y., & Katoh, R. (2008). Reactions of solvated electrons with imidazolium cations in ionic liquids. Radiat. Phys. Chem., 77(10/12), 1239–1243. DOI: 10.1016/j.radphyschem.2008.05.042.
Open DOI Search in Google Scholar Back to article
Asano, A., Yang, J., Kondoh, T., Norizawa, K., Nagaishi, R., Takahashi, K., & Yoshida, Y. (2008). Molar absorption coefficient and radiolytic yield of solvated electrons in diethylmethyl(2-methoxy)ammonium bis(trifluoromethanesulfonyl)imide ionic liquid. Radiat. Phys. Chem., 77(10/12), 1244–1247. DOI: 10.1016/j.radphyschem.2008.05.032.
Open DOI Search in Google Scholar Back to article
Kimura, A., Taguchi, M., Kondoh, T., Yang, J., Yoshida, Y., & Hirota, K. (2008). Study on the reaction of chlorophenols in room temperature ionic liquids with ionizing radiation. Radiat. Phys. Chem., 77(10/12), 1253–1257. DOI: 10.1016/j.radphyschem.2008.05.020.
Open DOI Search in Google Scholar Back to article
Wishart, F., Funston, A. M., & Szreder, T. (2006). Radiation chemistry of ionic liquids. In Molten Salts XIV – Proceedings of the International Symposium, 206th ECS Meeting, 3–8 October 2004 (pp. 802–813). Pennington, New Jersey, USA: The Electrochemical Society.
Search in Google Scholar Back to article
Allen, D., Baston, G., Bradley, A. E., Gorman, T., Haile, A., Hamblett, I., Hatter, J. E., Healey, M. J. F., Hodgson, B., Lewin, R., Lovell, K. V., Newton, B., Pitner, W. R., Rooney, D. W., Sanders, D., Seddon, K. R., Sims, H. E., & Thied, R. C. (2002). An investigation of the radiochemical stability of ionic liquids. Green Chem., 4(2), 152–158. DOI: 10.1039/b111042j.
Open DOI Search in Google Scholar Back to article
Shkrob, I. A., Chemerisov, S. D., & Wishart, J. F. (2007). The initial stages of radiation damage in ionic liquids and ionic liquid-based extraction systems. J. Phys. Chem. B, 111(40), 11786–1793. DOI: 10.1021/jp073619x.
Open DOI Search in Google Scholar Back to article
Qi, M., Wu, G., Li, Q., & Lu, Y. (2008). γ-Radiation effect on ionic liquid [bmim][BF₄]. Radiat. Phys. Chem., 77(7), 877–883. DOI: 10.1016/j.radphyschem.2007.12.007.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., Kocia, R., & Mirkowski, J. (2009). Formations of p-terphenyl excited states in the ionic liquid methyltributylammonium bis[(trifluoromethyl) sulfonyl]imide. Pulse radiolysis study. Res. Chem. Intermed., 35, 411–419. DOI: 10.1007/s11164-009-0056-2.
Open DOI Search in Google Scholar Back to article
Kocia, R., Grodkowski, J., & Mirkowski, J. (2015). Pulse radiolysis studies of p-terphenyl in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide, [MeBu₃N][NTf₂]. Res. Chem. Intermed., 41, 5079–5093. DOI: 10.1007/s11164-014-1590-0.
Open DOI Search in Google Scholar Back to article
Kocia, R. (2019). Pulse radiolysis studies of intermediates derived from p-terphenyl in the oxygenated methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid. Int. J. Chem. Kinet., 51(12), 958–964. DOI: 10.1002/kin.21323.
Open DOI Search in Google Scholar Back to article
Carmichael, I., & Hug, G. (1986). Triplet-triplet absorption spectra of organic molecules in condensed phases. J. Phys. Chem. Ref. Data, 15, 1–250. DOI: 10.1063/1.555770.
Open DOI Search in Google Scholar Back to article
Shida, T. (1988). Electronic absorption spectra of radical ions. Amsterdam: Elsevier.
Search in Google Scholar Back to article
Liu, A., Loffredo, D. M., & Trifunac, A. D. (1993). Photoionization and ensuing ion-molecule reactions of polycyclic aromatic hydrocarbons in alkane and alcohol solutions. J. Phys. Chem., 97(15), 3791–3799. DOI: 10.1021/j100117a027.
Open DOI Search in Google Scholar Back to article
Fujiwara, H., Kitamura, T., Wada, Y., Yanagida, S., & Kamat, P. V. (1999). Onium salt effects on p-terphenyl-sensitized photoreduction of water to hydrogen. J. Phys. Chem. A, 103(25), 4874–4878. DOI: 10.1021/jp984740u.
Open DOI Search in Google Scholar Back to article
Matsuoka, S., Kohzuki, T., Pac, C., Ishida, A., Takamuku, S., Kusaba, M., Nobuaki, N., & Yanagida, S. (1992). Photocatalysis of oligo(p-phenylenes). Photochemical reduction of carbon dioxide with triethylamine. J. Phys. Chem., 96(11), 4437–4445. DOI: 10.1021/j100190a057.
Open DOI Search in Google Scholar Back to article
Schuler, R. H., Patterson, L. K., & Janata, E. (1980). Yield for the scavenging of hydroxyl radicals in the radiolysis of nitrous oxide-saturated aqueous solutions. J. Phys. Chem., 84(16), 2088–2089. DOI: 10.1021/j100453a020.
Open DOI Search in Google Scholar Back to article
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988). Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (^•OH/^•O⁻ in aqueous solution. J. Phys. Chem. Ref. Data, 17, 513–886. DOI: 10.1063/1.555805.
Open DOI Search in Google Scholar Back to article
Gordon, S., Hart, E. J., Matheson, M. S., Rabani, J., & Thomas, J. K. (1963). Reactions of the hydrated electron. Discuss. Faraday Soc., 36, 193–205. DOI: 10.1039/DF9633600193.
Open DOI Search in Google Scholar Back to article
Sullivan, B. P., Krist, K., & Guard, H. E. (1993). Electrochemical and electrocatalytic reactions of carbon dioxide. Amsterdam, NL: Elsevier Science Publishers B.V.
Search in Google Scholar Back to article
Lamy, E., Nadjo, L., & Saveant, J. M. (1977). Standard potential and kinetic parameters of the electrochemical reduciton of carbon dioxide in dimethyformamide. J. Electroanal. Chem., 78(2), 403–407. DOI: 10.1016/S0022-0728(77)80143-5.
Open DOI Search in Google Scholar Back to article
Dhanasekaran, T., Grodkowski, J., Neta, P., Hambright, P., & Fujita, E. (1999). p-Terphenyl-sensitized photoreduction of CO₂ with cobalt and iron porphyrins. Interaction between CO and reduced metalloporphyrins. J. Phys. Chem. A, 103(38), 7742–7748. DOI: 10.1021/jp991423u.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., Dhanasekaran, T., Neta, P., Hambright, P., Brunschwig, B. S., Shinozaki, K., & Fujita, E. (2000). Reduction of cobalt and iron phthalocyanines and the role of the reduced species in catalyzed photoreduction of CO₂. J. Phys. Chem. A, 104(48), 11332–11339. DOI: 10.1021/jp002709y.
Open DOI Search in Google Scholar Back to article
Grodkowski, J. (2004). Radiolytic and photochemical reduction of carbon dioxide in solution catalyzed by transition metal complexes with some selected macrocycles. Warszawa: Institute of Nuclear Chemistry and Technology. (Raporty IChTJ. Seria A nr 1/2004).
Search in Google Scholar Back to article
Grodkowski, J., & Neta, P. (2000). Cobalt corrin catalyzed photoreduction of CO₂. J. Phys. Chem. A, 104(9), 1848–1853. DOI: 10.1021/jp9939569.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., Neta, P., Fujita, E., Mahammed, A., Simkhovich, L., & Gross, Z. (2002). Reduction of cobalt and iron corroles and catalyzed reduction of CO₂. J. Phys. Chem. A, 106(18), 4772–4778. DOI: 10.1021/jp013668o.
Open DOI Search in Google Scholar Back to article
Grodkowski, J., & Neta, P. (2000). Ferrous ions as catalysts for photochemical reduction of CO₂ in homogeneous solutions. J. Phys. Chem. A, 104(19), 4475–4479. DOI: 10.1021/jp993456f.
Open DOI Search in Google Scholar Back to article

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DOI: https://doi.org/10.2478/nuka-2022-0007 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922

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Language: English

Page range: 73 - 80

Submitted on: Oct 26, 2022

Accepted on: Dec 2, 2022

Published on: Jan 20, 2023

Published by: Institute of Nuclear Chemistry and Technology

In partnership with: Paradigm Publishing Services

Publication frequency: 4 issues per year

Keywords:

Carbon dioxide,

Ionic liquid,

Methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide,

Related subjects:

Physics,

Astronomy and astrophysics,

Physics, other

© 2023 Rafał Kocia, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Volume 67 (2022): Issue 4 (December 2022)