Carbon nanotubes functionalized by salts containing stereogenic heteroatoms as electrodes in their battery cells

Sandra Zdanowska; Magdalena Pyzalska; Józef Drabowicz; Damian Kulawik; Volodymyr Pavlyuk; Tomasz Girek; Wojciech Ciesielski

doi:10.1515/pjct-2016-0066

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Carbon nanotubes functionalized by salts containing stereogenic heteroatoms as electrodes in their battery cells

Green Sciences

Volume 18 (2016): Issue 4 (December 2016)

By: Sandra Zdanowska, Magdalena Pyzalska, Józef Drabowicz, Damian Kulawik, Volodymyr Pavlyuk, Tomasz Girek and Wojciech Ciesielski

Open Access

|Dec 2016

Abstract

This paper concentrates on electrochemical properties of groups of multi-walled carbon nanotubes (MWCNT) functionalized with substituents containing a stereogenic heteroatom bonded covalently to the surface of the carbon nanotube. This system was tested in Swagelok-type cells. The cells comprised a system (functionalized CNT with salts containing S and P atoms) with a working electrode, microfiber separators soaked with electrolyte solution, and a lithium foil counter/reference (commercial LiCoO₂) electrode. The electrolyte solution was 1 M LiPF₆ in propylene carbonate. Using standard techniques (cyclic voltammetry/chronopotentiometry), galvanostatic cycling was performed on the cells at room temperature with a CH Instruments Model 600E potentiostat/galvanostat electrochemical measurements. Methods of functionalization CNT were compared in terms of the electrochemical properties of the studied systems. In all systems, the process of charge/discharge was observed.

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Articles in this issue

DOI: https://doi.org/10.1515/pjct-2016-0066 | Journal eISSN: 3072-0389

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Language: English

Page range: 22 - 26

Published on: Dec 30, 2016

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

multi-walled carbon nanotubes (MWCNT),

battery,

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2016 Sandra Zdanowska, Magdalena Pyzalska, Józef Drabowicz, Damian Kulawik, Volodymyr Pavlyuk, Tomasz Girek, Wojciech Ciesielski, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Volume 18 (2016): Issue 4 (December 2016)