Stable bromine isotopic composition of atmospheric CH3Br

Axel Horst; Brett F. Thornton; Henry Holmstrand; Per Andersson; Patrick M. Crill; Örjan Gustafsson

doi:10.3402/tellusb.v65i0.21040

Stable bromine isotopic composition of atmospheric CH3Br

Tellus B: Chemical and Physical Meteorology

Volume 65 (2013): Issue 1

By: Axel Horst, Brett F. Thornton, Henry Holmstrand, Per Andersson, Patrick M. Crill and Örjan Gustafsson

Open Access

|Jan 2013

Bill M , Conrad M. E , Goldstein A. H . Stable carbon isotope composition of atmospheric methyl bromide . Geophys. Res. Lett . 2004 ; 31 ( 4 ): 1 – 4 . DOI: 10.1029/2003GL018639 .
Search in Google Scholar Back to article
Bill M , Rhew R. C , Weiss R. F , Goldstein A. H . Carbon isotope ratios of methyl bromide and methyl chloride emitted from a coastal salt marsh . Geophys. Res. Lett . 2002 ; 29 : 1 – 4 . DOI: 10.1029/2001GL012946 .
Search in Google Scholar Back to article
Bohlke J. K , Sturchio N. C , Gu B. H , Horita J , Brown G. M , co-authors . Perchlorate isotope forensics . Anal. Chem . 2005 ; 77 ( 23 ): 7838 – 7842 . DOI: 10.1021/ac051360d .
Search in Google Scholar Back to article
Callaghan T. V , Bergholm F , Christensen T. R , Jonasson C , Kokfelt U , co-authors . A new climate era in the sub-Arctic: accelerating climate changes and multiple impacts . Geophys. Res. Lett . 2010 ; 37 DOI: 10.1029/2009GL042064 .
Search in Google Scholar Back to article
Christensen T. R , Johansson T. R , Akerman H. J , Mastepanov M , Malmer N , co-authors . Thawing sub-Arctic permafrost: effects on vegetation and methane emissions . Geophys. Res. Lett . 2004 ; 31 ( 4 ): DOI: 10.1029/2003GL018680 .
Search in Google Scholar Back to article
Draxler R. R . HYSPLIT4 user's guide . 1999 . NOAA Tech. Memo ERL ARL-230, NOAA, Ed., 24 .
Search in Google Scholar Back to article
Draxler R. R , Hess G. D . Description of the HYSPLIT_4 modeling system . 1997 . NOAA Tech. Memo, ERL ARL-224, NOAA, Ed., 24 .
Search in Google Scholar Back to article
Gao Y. Q , Marcus R. A . Strange and unconventional isotope effects in ozone formation . Science . 2001 ; 293 ( 5528 ): 259 – 263 . DOI: 10.1126/science.1058528 .
Search in Google Scholar Back to article
Gola A. A , D'Anna B , Feilberg K. L , Sellevåg S. R , Bache-Andreassen L , co-authors . Kinetic isotope effects in the gas phase reactions of OH and Cl with CH₃Cl, CD₃Cl, and 13CH₃Cl . Atmos. Chem. Phys . 2005 ; 5 ( 9 ): 2395 – 2402 . DOI: 10.5194/acp-5-2395-2005 .
Search in Google Scholar Back to article
Hardacre C. J , Blei E , Heal M. R . Growing season methyl bromide and methyl chloride fluxes at a sub-Arctic wetland in Sweden . Geophys. Res. Lett . 2009 ; 36 : 1 – 5 . DOI: 10.1029/2009GL038277 .
Search in Google Scholar Back to article
Harper D. B , Kalin R. M , Larkin M. J , Hamilton J. T. G , Coulter C . Microbial transhalogenation: a complicating factor in determination of atmospheric chloro- and bromomethane budgets . Environ. Sci. Technol . 2000 ; 34 : 2525 – 2527 .
Search in Google Scholar Back to article
Horst A , Holmstrand H , Andersson P , Andersson A , Carrizo D , co-authors . Compound-specific bromine isotope analysis of methyl bromide using gas chromatography hyphenated with inductively coupled plasma multiple-collector mass spectrometry . Rapid Commun. Mass Spectrom . 2011 ; 25 ( 17 ): 2425 – 2432 . DOI: 10.1002/rcm.5144 .
Search in Google Scholar Back to article
Huang L , Sturchio N. C , Abrajano T , Heraty L. J , Holt B. D . Carbon and chlorine isotope fractionation of chlorinated aliphatic hydrocarbons by evaporation . Org. Geochem . 1999 ; 30 ( 8A ): 777 – 785 . DOI: 10.1016/S0146-6380(99)00060- .
Search in Google Scholar Back to article
Laturnus F . Marine macroalgae in polar regions as natural sources for volatile organohalogens . Environ. Sci. Pollut. Res . 2001 ; 8 ( 2 ): 103 – 108 .
Search in Google Scholar Back to article
Laube J. C , Kaiser J , Sturges W. T , Boenisch H , Engel A . Chlorine isotope fractionation in the stratosphere . Science . 2010 ; 329 ( 5996 ): 1167 – 1167 . DOI: 10.1126/science.1191809 .
Search in Google Scholar Back to article
Letts M. G , Roulet N. T , Comer N. T , Skarupa M. R , Verseghy D. L . Parametrization of peatland hydraulic properties for the Canadian land surface scheme . Atmos.Ocean . 2000 ; 38 : 141 – 160 .
Search in Google Scholar Back to article
McCauley S , Goldstein A , DePaolo D . An isotopic approach for understanding the CH₃Br budget of the atmosphere . Proc. Natl. Acad. Sci. USA . 1999 ; 96 ( 18 ): 10006 – 10009 . DOI: 10.1007/BF02987302 .
Search in Google Scholar Back to article
Montzka S. A , Butler J. H , Hall B. D , Mondeel D. J , Elkins J. W . A decline in tropospheric organic bromine . Geophys. Res. Lett . 2003 ; 30 ( 15 ): 1 – 4 . DOI: 10.1029/2003GL017745 .
Search in Google Scholar Back to article
Montzka S. A , Reimann S , Engel A , Krüger K , O'Doherty S , co-authors . Ozone-depleting substances (ODSs) and related chemicals. In: Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project, Report No. 52, Chapt. 1 . 2011
Search in Google Scholar Back to article
Redeker K. R , Wang N. Y , Low J. C , McMillan A , Tyler S. C , co-authors . Emissions of methyl halides and methane from rice paddies . Science . 2000 ; 290 ( 5493 ): 966 – 969 . DOI: 10.1126/science.290.5493.966 .
Search in Google Scholar Back to article
Rhew R. C , Miller B. R , Weiss R. F . Natural methyl bromide and methyl chloride emissions from coastal salt marshes . Nature . 2000 ; 403 ( 6767 ): 292 – 295 . DOI: 10.1038/35002043 .
Search in Google Scholar Back to article
Shouakar-Stash O , Drimmie R , Frape S . Determination of inorganic chlorine stable isotopes by continuous flow isotope ratio mass spectrometry . Rapid Commun. Mass. Spectrom . 2005 ; 19 ( 2 ): 121 – 127 . DOI: 10.1002/rcm.1762 .
Search in Google Scholar Back to article
Thornton B. F , Horst A , Carrizo D , Holmstrand H , Andersson P , co-authors . A high-volume cryosampler and sample purification system for halogen isotope studies of methyl halides . J. Atmos. Oceanic. Technol . DOI: 10.1175/JTECH-D-12-00228.1 (Published online 27 May 2013: http://journals.ametsoc.org/doi/abs/10.1175/JTECH-D-12-00228.1) In press .
Search in Google Scholar Back to article
White M , Varner R , Crill P. M , Mosedale C . Controls on the seasonal exchange of CH₃Br in temperate peatlands . Global Biogeochem. Cycles . 2005 ; 19 ( 4 ): 1 – 14 . DOI: 10.1029/2004GB002343 .
Search in Google Scholar Back to article
Wolfsberg M . Note on secondary isotope effects in reaction rates . J. Chem. Phys . 1960 ; 33 ( 1 ): 2 – 6 . DOI: 10.1063/1.1731078 .
Search in Google Scholar Back to article
Yvon-Lewis S. A , Saltzman E. S , Montzka S. A . Recent trends in atmospheric methyl bromide: analysis of post-Montreal Protocol variability . Atmos. Chem. Phys . 2009 ; 9 ( 16 ): 5963 – 5974 . DOI: 10.5194/acp-9-5963-2009 .
Search in Google Scholar Back to article

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DOI: https://doi.org/10.3402/tellusb.v65i0.21040 | Journal eISSN: 1600-0889

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Language: English

Page range: 21040 - 21040

Submitted on: Apr 4, 2013

Accepted on: Aug 20, 2013

Published on: Jan 1, 2013

Published by: Stockholm University Press

In partnership with: Paradigm Publishing Services

Keywords:

tropospheric methyl bromide,

Arctic,

© 2013 Axel Horst, Brett F. Thornton, Henry Holmstrand, Per Andersson, Patrick M. Crill, Örjan Gustafsson, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.

Volume 65 (2013): Issue 1