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Strong similarities between night-time deposition velocities of carbonyl sulphide and molecular hydrogen inferred from semi-continuous atmospheric observations in Gif-sur-Yvette, Paris region Cover

Strong similarities between night-time deposition velocities of carbonyl sulphide and molecular hydrogen inferred from semi-continuous atmospheric observations in Gif-sur-Yvette, Paris region

Open Access
|Jan 2013

Figures & Tables

Table 1

Estimates of COS and H2 fluxes (F) and deposition velocities (ν) during nocturnal stable conditions (Gif-sur-Yvette, in 2011).

Carbonyl sulphideHydrogenDate year 2011COS vs. 222Rn (pmol Bq−1)*r2, nFCOS (nmol m−2 h−1)[COS] (ppt)νCOS (mm s−1)H2 vs. 222Rn (nmol Bq−1)*r2, nFH (µmol m−2 h−1)[H2] (ppb)vH(mm s−1)Feb 1–2217.8±19.30.91, 148.155050.10423.5±42.30.90, 1315.865850.17Mar 23–24263.6±29.30.92, 913.655400.15ndndndndndMar 25–26111.5±15.30.84, 125.565330.07138.7±20.80.83, 116.925350.09Apr 5–6385.7±100.40.40, 1119.255150.24355.5±34.70.90, 1317.745370.21May 24–25153.7±69.50.41, 97.675350.09ndndndndndMay 27–28245.5±80.10.54, 1012.255450.15ndndndndndJun 10–11124.5±44.10.61, 76.215150.08189.6±43.00.79, 79.465450.11Sep 15–16387.9±49.70.79, 1824.204450.36ndndndndndNov 28–29160.4±15.90.93, 98.015200.1047.7±4.70.92, 112.384800.03Nov 30–Dec 1126.8±15.40.92, 86.335250.08157.3±26.30.83, 97.855100.10Dec 5–6569.9±96.70.72, 1528.455050.36ndndndndndDec 7–8241.2±49.40.66, 1412.035050.15ndndndndndDec 9–10621.2±93.10.71, 2031.015100.39377.3±65.10.61, 2318.835150.24Dec 10–11220.1±31.50.73, 2011.034950.14ndndndndnd

[i] Data collected during turbulent nights were not considered. nd=no data.

[ii] *The uncertainty in the best-fit slope is given as ±one standard error.

Fig. 1

COS, CO and H2 mole fractions, and 222Rn activity during November–December 2011 at Gif-sur-Yvette. The vertical red dashed lines indicate stable atmospheric conditions (radon highs) associated with H2 highs and COS lows. The vertical blue dashed lines indicate stable atmospheric conditions associated with H2 and COS lows. Major COS lows are numbered 1–7. The yellow vertical bands correspond to the sunlit hours from sunrise to sunset. From late November to mid December, the sun rises between 7:17 and 7:35 am and sets between 3:57 and 4:01 pm UTC.

Fig. 2

COS, CO and H2 mole fractions, and 222Rn activity during early February (left column), late March (middle column) and early August 2011 (right column) at Gif-sur-Yvette. The vertical red dashed lines indicate stable atmospheric conditions (radon highs) associated with H2 highs and COS lows. The vertical blue dashed lines indicate stable atmospheric conditions associated with H2 and COS lows. The vertical black dashed lines indicate stable atmospheric conditions associated with H2 lows and COS highs. The yellow vertical bands correspond to the sunlit hours from sunrise to sunset. In early February, the sun rises between 7:14 and 7:19 am and sets between 4:51 and 4:55 pm UTC. In late March, the sun rises between 5:39 and 5:45 am and sets between 6:09 and 6:14 pm. In early August, the sun rises between 4:23 and 4:27 am and sets between 7:27 and 7:31 pm.

Fig. 3

Correlation of the COS and H2 mole fractions to 222Rn activity during nocturnal stable atmospheric conditions (February 1–2/2011). H2 levels recorded during rush hours (5:30–8:30 UTC) are plotted with open squares.

Fig. 4

A comparison of the observed COS and H2 deposition velocities. Error bars represent the overall uncertainty of each deposition event.

Language: English
Page range: 20719 - 20719
Submitted on: Feb 26, 2013
Accepted on: Jun 24, 2013
Published on: Jan 1, 2013
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services

© 2013 Sauveur Belviso, Martina Schmidt, Camille Yver, Michel Ramonet, Valerie Gros, Thomas Launois, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.