The Arctic: a sink for mercury

Parisa A. Ariya; Ashu P. Dastoor; Marc Amyot; William H. Schroeder; Leonard Barrie; Kurt Anlauf; Farhad Raofie; Andrew Ryzhkov; Didier Davignon; Janick Lalonde; Alexandra Steffen

doi:10.3402/tellusb.v56i5.16458

The Arctic: a sink for mercury

Tellus B: Chemical and Physical Meteorology

Volume 56 (2004): Issue 5

By: Parisa A. Ariya, Ashu P. Dastoor, Marc Amyot, William H. Schroeder, Leonard Barrie, Kurt Anlauf, Farhad Raofie, Andrew Ryzhkov, Didier Davignon, Janick Lalonde and Alexandra Steffen

Open Access

|Jan 2004

Abstract

Mercury is a persistent, toxic and bio-accumulative pollutant of global interest. Its main mass in the troposphere is in the form of elemental gas-phase mercury. Rapid, near-complete depletion of mercury has been observed during spring in the atmospheric boundary layer of frozen marine areas in Arctic, sub-Arctic and Antarctic locations. It is strongly correlated with ozone depletion. To date, evidence has indicated strongly that chemistry involving halogen gases from surface sea-salt is the mechanism of this destruction. Precisely which halogen gases are the main players has remained unresolved. Our novel kinetic data and multiscale modelling show that Br atoms and BrO radicals are the most effective halogens driving mercury oxidation. The reduction of oxidized mercury deposited in the snow pack back to Hg⁰ and subsequent diffusion to the atmosphere is observed. However, it cannot compensate for the total deposition, and a net accumulation occurs. We use a unique global atmospheric mercury model to estimate that halogen-driven mercury depletion events result in a 44% increase in the net deposition of mercury to the Arctic. Over a 1-yr cycle, we estimate an accumulation of 325 tons of mercury in the Arctic.

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Articles in this issue

DOI: https://doi.org/10.3402/tellusb.v56i5.16458 | Journal eISSN: 1600-0889

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Language: English

Page range: 397 - 403

Submitted on: Oct 30, 2003

Accepted on: Apr 13, 2004

Published on: Jan 1, 2004

Published by: Stockholm University Press

In partnership with: Paradigm Publishing Services

© 2004 Parisa A. Ariya, Ashu P. Dastoor, Marc Amyot, William H. Schroeder, Leonard Barrie, Kurt Anlauf, Farhad Raofie, Andrew Ryzhkov, Didier Davignon, Janick Lalonde, Alexandra Steffen, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.

Volume 56 (2004): Issue 5