Figure 1

Figure 2

Figure 3

Figure 4

Concentrations of metals found in certified reference material HISS-1 from the National Research Council, Canada_
| Metals | HISS 1 certified | HISS 1 observed | Recovery (%) |
|---|---|---|---|
| Cd | 0.024 ± 0.009 | 0.021 ± 0.03 | 87 |
| Cr | 30.0 ± 6.8 | 32.10 ± 2.35 | 107 |
| Cu | 2.29 ± 0.37 | 2.40 ± 0.21 | 104 |
| Fe | - | - | - |
| Mn | 66.1 ± 4.2 | 62.85 ± 1.36 | 95 |
| Mo | - | - | - |
| Ni | 2.16 ± 0.29 | 2.25 ± 1.10 | 104 |
| Pb | 3.13 ± 0.40 | 3.02 ± 0.02 | 96 |
| Se | 0.050 ± 0.007 | 0.046 ± 0.1 | 92 |
| Zn | 4.94 ± 0.79 | 4.70 ± 0.25 | 95 |
SQG criteria values and current study results_
| LEL | TEL | MET | TET | SEL | PEL | Annual average results | |
|---|---|---|---|---|---|---|---|
| Cd | 0.6 | 0.596 | 0.9 | 3 | 10 | 3.53 | 0.35 |
| Cr | 26 | 37.3 | 55 | 100 | 110 | 90 | 78.71 |
| Cu | 16 | 35.7 | 28 | 86 | 110 | 197 | 18.63 |
| Ni | 16 | 18 | 35 | 61 | 75 | 36 | 257.42 |
| Pb | 31 | 35 | 42 | 170 | 250 | 91,3 | 2.28 |
| Zn | 120 | 123 | 150 | 540 | 820 | 315 | 98.20 |
Classification of used indices for lake sediment_
| Indices | Pollution class | |
|---|---|---|
| EF | EF < 2 | No or minimal enrichment |
| Yongming et al. (2006) | EF = 2–5 | Moderate enrichment |
| EF = 5–20 | Significant enrichment | |
| EF = 20–40 | Very high enrichment | |
| EF > 40 | Extremely high enrichment | |
| Igeo | 1geo < 0 | Unpolluted |
| (Muller, 1969, 1981) | 0 < Igeo < 1 | Unpolluted-moderately polluted |
| 1 < Igeo < 2 | Moderately polluted | |
| 2 < Igeo < 3 | Moderately strongly polluted | |
| 3 < Igeo < 4 | Strongly polluted | |
| 4 < Igeo < 5 | Strongly very strongly polluted | |
| Igeo > 5 | Very strongly polluted | |
| CF | CF < 1 | Low pollution |
| Hakanson, 1980 | 1 ≤ CF ≤ 3 | Moderate pollution |
| 3 ≤ CF ≤ 6 | Considerable pollution | |
| CF ≥ 6 | High pollution | |
| CD | Cd < 6 | Low contamination degree |
| Hakanson (1980) | 6 ≤ CD ≤ 12 | Moderate contamination degree |
| 12 ≤ Cd < 24 | Considerable contamination degree | |
| CD ≥ 24 | Very high contamination degree | |
| mCD | mCD < 1.5 | Very low pollution |
| Abrahim & Parker (2008) | 1.5 < mCD < 2 | Low pollution |
| 2 < mCD < 4 | Moderate pollution | |
| 4 < mCD < 8 | High pollution | |
| 8 < mCD < 16 | Very high pollution | |
| 16 < mCD < 32 | Extremely high pollution | |
| mCD > 32 | Ultra-high pollution | |
| PLI | PLI = 0 | Perfect |
| Tomlinson et al. (1980) | PLI = 1 | Presence of pollutant at base level |
| PLI > 1 | Progressive pollution | |
| mER index | mER < 40 | Low potential ecological risk |
| Brady et al. (2015), Hakanson (1980) | 40 ≤ mER ≤ 80 | Moderate potential ecological risk |
| 80 ≤ mER ≤ 160 | Significant potential ecological risk | |
| 160 ≤ mER ≤ 320 | High potential ecological risk | |
| mER ≥ 320 | Very high potential ecological risk | |
| mPER index | mPER < 150 | Low ecological risk |
| 160 ≤ mPER < 300 | Moderate ecological risk | |
| Hakanson (1980) | 300 ≤ mPER < 600 | Significant ecological risk |
| mPER ≥ 600 | Very high ecological risk | |
EF, Igeo and CF of Karataş Lake’s sediment by seasons_
| EF | (Igeo) | CF | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Autumn | Winter | Spring | Summer | Autumn | Winter | Spring | Summer | Autumn | Winter | Spring | Summer | |
| Cd | 8.960 | 18 133 | 14.085 | 15.024 | –1.23 | –0.15 | –0.27 | 0.009 | 0.639 | 1.343 | 1.242 | 1.509 |
| Cr | 10 519 | 10 539 | 13 543 | 8592 | –0.98 | –0.87 | –0.47 | –0.83 | 0.758 | 0.816 | 1.083 | 0.842 |
| Cu | 3824 | 3421 | 5556 | 5610 | –2.40 | –2.54 | –1.46 | –1.38 | 0.284 | 0.257 | 0.543 | 0.574 |
| Fe | 5208 | 4763 | 6400 | 4722 | –1.96 | –2.06 | –1.39 | –1.66 | 0.383 | 0.358 | 0.572 | 0.472 |
| Mn | 5799 | 5652 | 6483 | 5401 | –1.79 | –1.81 | –1.30 | –1.45 | 0.432 | 0.426 | 0.607 | 0.546 |
| Mo | 3335 | 2171 | 3714 | 1972 | –2.68 | –3.21 | –2.28 | –2.92 | 0.234 | 0.162 | 0.308 | 0.198 |
| Ni | 42 941 | 46 793 | 59 200 | 38 371 | 1.05 | 1.27 | 1.61 | 1.34 | 3.114 | 3.624 | 4.603 | 3.308 |
| Pb | 1563 | 0.443 | 1559 | 1600 | –3.67 | –5.47 | –3.43 | –3.15 | 0.118 | 0.034 | 0.139 | 0.168 |
| Se | 29 563 | 33 887 | 27 187 | 45 657 | 0.41 | 0.63 | 0.63 | 1.61 | 2.006 | 2.337 | 2.317 | 4.603 |
| Zn | 10 533 | 10 913 | 11 863 | 14 532 | –1.05 | –0.92 | –0.45 | 0.01 | 0.722 | 0.791 | 1.096 | 1.517 |
The concentrations (mg ⋅ kg−1) of some heavy metals and Se in Karataş Lake’s sediment_
| Season I | Cd | Cr | Cu | Fe | Mn | Mo | Ni | Pb | Se | Zn |
|---|---|---|---|---|---|---|---|---|---|---|
| Autumn | 0.08–0.33 | 16.90–103.74 | 5.91–18.03 | 6629.49–23 327.41 | 143.96–540.26 | 0.36–0.97 | 49.04–324.30 | 0.54–3.57 | 1.11–1.39 | 54.53–75.06 |
| Winter | 0.23–0.62 | 20.37–136.33 | 5.71–15.28 | 7906.09–23 633.99 | 167.82–575.60 | 0.13–0.83 | 68.57–422.22 | 0.28–1.18 | BDL** | 53.80–106.30 |
| Spring | 0.13–0.57 | 53.86–161.25 | 12.40–38.37 | 23 334.75–33 640.99 | 378.83–607.52 | 0.52–1.14 | 118.53–575.79 | 2.43–3.00 | 1.11–1.68 | 70.40–130.90 |
| Summer | 0.17–0.65 | 39.95–104.41 | 15.30–43.54 | 15 301.18–25 791.46 | 391.32–563.52 | 0.19–0.98 | 136.94–316.23 | 1.76–5.84 | 1.48–4.05 | 72.94–308.56 |
| Annual Mean | 0.35 | 78.71 | 18.63 | 21068.77 | 427.37 | 0.58 | 257.42 | 2.28 | 1.38 | 98.00 |
Comparison of annual mean concentrations (mg · kg−1) of heavy metals and Se in Karataş Lake sediment (this study) with values reported for Karataş, Beyşehir, and Eğirdir Lakes in previous studies_
| Metal | This study | Başyiğit and Tekin-Özan (2013) (Karataş Lake) | Kaya (2021) (Karataş Lake) | Şener et al. (2023a) (Beyşehir Lake) | Özçelik and Tekin-Özan (2024) (Eğirdir Lake) |
|---|---|---|---|---|---|
| Cd | 0.35 | 0.20 | 0 | 0.61 | |
| Cr | 78.71 | 37.06 | 164.89 | 78.58 | 14.43 |
| Cu | 18.63 | 21.95 | 25.86 | 42.87 | 14.20 |
| Fe | 21 068.77 | 6968.60 | - | 19 765.22 | 10 357.88 |
| Mn | 427.36 | 306.40 | - | 1510.30 | 330.09 |
| Mo | 0.58 | 0.21 | - | - | 1.09 |
| Ni | 257.43 | 131.81 | - | 56.27 | 25.49 |
| Pb | 2.28 | 0.88 | 0 | 12.01 | 41.38 |
| Se | 1.38 | 2.83 | - | - | 2.38 |
| Zn | 98.00 | 28.17 | 41.61 | 48.20 | 35.37 |
mER index and mPER index of Karataş Lake’s sediment by seasons
| Autumn | Winter | Spring | Summer | |
|---|---|---|---|---|
| Cd | 268.8 | 543.99 | 422.55 | 450,72 |
| Cr | 21.03 | 21.07 | 27.08 | 17.18 |
| Cu | 11.47 | 17.10 | 27.78 | 28.05 |
| Mn | 5799 | 5652 | 6483 | 5401 |
| Ni | 214.70 | 233.96 | 296 | 191.85 |
| Pb | 7.81 | 2.21 | 7.79 | 8 |
| Zn | 10.53 | 10.91 | 11.86 | 14.53 |
| mPER | 540.13 | 834.89 | 799.54 | 715.73 |