Preparation and spectral properties of products of the reaction of N,N-dimethylhydrazine with selected enolethers/alkoxymethylene systems

Denisa Tarabová; Viktor Milata

doi:10.2478/v10188-012-0035-x

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Preparation and spectral properties of products of the reaction of N,N-dimethylhydrazine with selected enolethers/alkoxymethylene systems

Acta Chimica Slovaca

Volume 5 (2012): Issue 2 (October 2012)

By: Denisa Tarabová and Viktor Milata

Open Access

|Dec 2012

Abstract

There were studied series of activated enolethers (alkoxymethylene derivatives of malonic or 3-oxobutanoic acids derivatives of general formula R-O-CH=C(R¹, R²) where R¹ = R²/ R¹ ≠ R² (R¹, R² = CO₂CH₃, CO₂CH₂CH₃, COCH₃, CN) with N,N-dimethylhydrazine. They smoothly provided products of nucleophilic vinylic substitution reaction - dimethyl hydrazinyl methylene derivatives of malonic or 3-oxobutanoic acids (enhydrazines), respectively from 20 minutes to 2 hours at room temperature.

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Articles in this issue

DOI: https://doi.org/10.2478/v10188-012-0035-x | Journal eISSN: 1339-3065 | Journal ISSN: 1337-978X

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Language: English

Page range: 232 - 235

Published on: Dec 14, 2012

Published by: Slovak University of Technology in Bratislava

In partnership with: Paradigm Publishing Services

Publication frequency: 1 issue per year

Keywords:

N,N-dimethylhydrazine,

enolethers,

nucleophilic vinylic substitution reaction,

enhydrazines

Related subjects:

Chemistry,

Chemistry, other

© 2012 Denisa Tarabová, Viktor Milata, published by Slovak University of Technology in Bratislava
This work is licensed under the Creative Commons License.

Volume 5 (2012): Issue 2 (October 2012)