Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

Wróblewska, Agnieszka; Wójtowicz, Grzegorz

doi:10.2478/v10026-010-0037-7

Abstract

The influence of technological parameters on the transformation of 1-butene-3-ol (1B3O) to bis(3-methyl-1-propene) ether (2×1B3O ether) and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether (1B3Ox1,2EB3O ether) over the TS-2 catalyst was presented. The reaction was performed in a glass reactor at atmospheric pressure and in methanol medium (protic solvent). The optimum conditions of 2×1B3O ether and 1B3Ox1,2EB3O ether obtaining were established by the mathematical method of experiments design (rotatable-uniform design) and after the analyses of the layer drawings.

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Bis(3-methyl-1-propene) ether and 3-(3-methyl-1-propene)-3-methyl-1,2-epoxypropane ether synthesis during the epoxidation of 1-butene-3-ol with hydrogen peroxide over the TS-2 catalyst

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