Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst — the new and friendly method of 2,3-epoxybutane-1-ol synthesis

Agnieszka Wróblewska; Anna Fajdek; Eugeniusz Milchert

doi:10.2478/v10026-010-0019-9

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Epoxidation of crotyl alcohol in the presence of titanium silicalite Ti-MWW catalyst — the new and friendly method of 2,3-epoxybutane-1-ol synthesis

Green Sciences

Volume 12 (2010): Issue 2 (June 2010)

By: Agnieszka Wróblewska, Anna Fajdek and Eugeniusz Milchert

Open Access

|Jul 2010

Abstract

Epoxidation of crotyl alcohol (CA) with 30 wt% hydrogen peroxide over Ti-MWW catalyst has been studied with methanol as a solvent and at autogenic pressure. The influence of temperature in the range of 20-120°C, the molar ratio of CA/H₂O₂ 1:1-5:1, methanol concentration 5-90 wt%, Ti-MWW catalyst concentration 0.0-5.0 wt% and the reaction time 5-300 min have been studied. The main product of CA epoxidation is 2,3-epoxybutane-1-ol (2,3EB1O), a compound with many applications.

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Articles in this issue

DOI: https://doi.org/10.2478/v10026-010-0019-9 | Journal eISSN: 3072-0389

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Language: English

Page range: 57 - 61

Published on: Jul 9, 2010

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

Ti-MWW,

crotyl alcohol epoxidation,

2,3-epoxybutane-1-ol

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2010 Agnieszka Wróblewska, Anna Fajdek, Eugeniusz Milchert, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 12 (2010): Issue 2 (June 2010)