The Ti-MWW catalyst - its characteristic and catalytic properties in the epoxidation of allyl alcohol by hydrogen peroxide

Agnieszka Wróblewska; Anna Fajdek; Eugeniusz Milchert; Barbara Grzmil

doi:10.2478/v10026-010-0006-1

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The Ti-MWW catalyst - its characteristic and catalytic properties in the epoxidation of allyl alcohol by hydrogen peroxide

Green Sciences

Volume 12 (2010): Issue 1 (March 2010)

By: Agnieszka Wróblewska, Anna Fajdek, Eugeniusz Milchert and Barbara Grzmil

Open Access

|Apr 2010

Abstract

Ti-MWW, one of the latest titanium-silicalite catalysts, has been prepared by direct hydrothermal synthesis using hexamethyleneimine as a structure-directing agent. The characteristic of the catalyst was performed by means of the following methods: XRD, SEM, IR, UV-vis and X'Ray microanalysis. The catalytic properties of Ti-MWW have been compared with those of the conventional titanium-silicalites TS-1 and TS-2 in the epoxidation of allyl alcohol with hydrogen peroxide. The process has been described by the following main functions: the selectivity of the transformation to glycidol in relation to allyl alcohol consumed, the conversions of the substrates (allyl alcohol and hydrogen peroxide) and the selectivity of the transformation to organic compounds in relation to hydrogen peroxide consumed.

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Articles in this issue

DOI: https://doi.org/10.2478/v10026-010-0006-1 | Journal eISSN: 3072-0389

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Language: English

Page range: 29 - 34

Published on: Apr 8, 2010

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

Ti-MWW,

titanium-silicalites,

glycidol,

liquid phase epoxidation,

hydrogen peroxide

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2010 Agnieszka Wróblewska, Anna Fajdek, Eugeniusz Milchert, Barbara Grzmil, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 12 (2010): Issue 1 (March 2010)