Synthesis and characteristics of titanium silicalite TS-1, Ti-Beta and Ti-MWW catalysts

Agnieszka Wróblewska; Anna Fajdek; Eugeniusz Milchert

doi:10.2478/v10026-009-0015-0

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Synthesis and characteristics of titanium silicalite TS-1, Ti-Beta and Ti-MWW catalysts

Green Sciences

Volume 11 (2009): Issue 1 (March 2009)

By: Agnieszka Wróblewska, Anna Fajdek and Eugeniusz Milchert

Open Access

|Apr 2009

Abstract

The synthesis methods of the following titanium-silicalite catalysts: TS-1, Ti-Beta and Ti-MWW were presented. The results of the analyses of the catalysts by XRD, SEM and IR, UV-vis methods were also shown. A brief description of the catalytic performances of these catalysts in the oxidation process of olefins, alkenes, alcohols and aromatic compounds was presented.

References

Sheldon, R. (1996). Selective catalytic synthesis of fine chemicals: opportunities and trends.107(1 - 3), 75 - 83. DOI: 10.1016/1381-1169(95)00229-4.
Open DOI Search in Google Scholar
Sheldon, R., Arends, I. & Dijksman, A. (2000). New developments in catalytic alcohol oxidations for fine chemicals synthesis.57(1 - 3), 157 - 166. DOI: 10,1016/S0920-5861(99)00317-X.
Open DOI Search in Google Scholar
Blaser, H. & Studer, M. (1999). The role of catalysis for the clean production of fine chemicals.189, 191 - 204. PII: S0926-860X(99)00276-8.
Open DOI Search in Google Scholar
Mills, P. & Chaudhari, R. (1997). Multiphase catalytic reactor engineering and design for pharmaceuticals.37(4), 367 - 404. DOI: 10,1016/ S0920-5861(97)00028-X.
Open DOI Search in Google Scholar
Blaser, H. (2000). Heterogeneous catalysis for fine chemicals production.60(1 - 3), 161 - 165. DOI: 10,1016/S0920-5861(00)00332-1.
Open DOI Search in Google Scholar
Millini, R., Massaro, E., Perego, G. & Bellussi, G. (1992). Framework composition of titanium silicalite 1.137(2), 497 - 503.
Open DOI Search in Google Scholar
Wróblewska, A. & Milchert, E. (2002). Synthesis of titanium-silicalite catalysts.46(3 - 4), 151 - 175.
Search in Google Scholar
Khouw, C., Dartt, C., Labinger, J. & Davis, M. (1994). Studies on the catalytic oxidation of alkanes and alkenes by titanium silicalites.149, 195 - 205.
Open DOI Search in Google Scholar
Notari, B. (1987). Innovation in Zeolite Material Scienece.37, 413.
Open DOI Search in Google Scholar
Hauptman, S. (1985).Leibziger: VEB deutscher Verlag für Grundstoffindustrie.
Search in Google Scholar
Koch, M., Wark, M. & Schulz-Ekloff, G. (1999).Germany: University of Bremen.
Search in Google Scholar
Kooyman, P. (1993).Delft: Technische Universiteit.
Search in Google Scholar
Notari, B. (1988). Innovation In Zeolite Materials Science. 37, 413.
Search in Google Scholar
Clerici, M. (1991). Oxidation of saturated hydrocarbons with hydrogen peroxide, catalyzed by titanium silicalite.68(1 - 2), 249 - 261.
Open DOI Search in Google Scholar
Tatsumi, T., Nakamura, M., Negeshi, S. & Tominaga, H (1990). Shape-selective oxidation of alkenes with hydrogen peroxide catalyzed by titanosilicalite.476 - 477.
Search in Google Scholar
Huybrechts, D., Bruyker, L. & Jacobs, P. (1990). Oxyfunctionalization of alkenes with hydrogen peroxide on titanium silicalite.345, 240.
Open DOI Search in Google Scholar
Romano, U., Esposito, A., Maspero, F., Neri, F. & Clerici, M. (1990). New Developments In Selective Oxidation.55, 33.
Open DOI Search in Google Scholar
Clerici, M. & Ingllina, P. (1993). Epoxidation of lower olefins with hydrogen peroxide and titanium silicalite.140, 71.
Open DOI Search in Google Scholar
Goutier, S. & Tuel, A. (1994). Oxidation of aniline over TS-1, the titanium substituted silicalite -1.118(2), 173 - 186.
Open DOI Search in Google Scholar
Van der Waal J. (1998). Prof. Thesis Univ. Delft, The Niderlandy.
Search in Google Scholar
Van der Waal, J., Rigutto, M. & Van Bekkum, H. (1997). Zeolite titanium beta as a selective catalyst in the epoxidation of bulky alkenes.167(2), 331 - 342. DOI: 10.1016/S0926-860X(97)00323-2.
Open DOI Search in Google Scholar
Corey, E. & Schmidt, G. (1979). Useful procedures for the oxidation of alcohols involving pyridinium dichromate in aprotic media.5, 399 - 402.
Open DOI Search in Google Scholar
Wu, P., Tatsumi, T., Komatsu, T. & Yashima, T. (2001). A novel titano-silicalite with MWW structure: I. Hydrothermal synthesis, elimination of extraframework titanium, and characterizations.105(15), 2897 - 2905. DOI: 10.1021/jp002816S.
Open DOI Search in Google Scholar
Degnan, T. (2003). The implications of the fundamentals of shape selectivity for the development of catalysts for the petroleum and petrochemical industries.216(1-2), 32 - 46. DOI: 10.1016/S0021-9517(02)00105-7.
Open DOI Search in Google Scholar
Fan, W., Wu, P., Namba, S. & Tatsumi, T. (2006). Synthesis and catalytic properties of a new titanosilicate molecular sieve with the structure analogous to MWW-type lamellar precursor.243(1), 183 - 191. DOI: 10.1016/jat.2006.07.003.
Search in Google Scholar
Wu, P., Tatsumi, T., Komatu, T. & Yashima, T. (2002). A novel titanosilicate with MWW structure: II. Catalytic properties In The selective oxidation of alkenes.202(2), 245 - 255. DOI: 10.1006/jat.2001.3278.
Search in Google Scholar
Wu, P. & Tatsumi, T. (2002). Preparation of B-free Ti-MWW through reversible structural conversion.1026 - 1027. DOI: 10.1039/b201170k.
Open DOI Search in Google Scholar
Wu, P., Liu, Y., He, M. & Tatsumi, T. (2004). A novel titanosilicalite with MWW structure. Catalytic properties In selective epoxidation of diallyl ether with hydrogen peroxide.228(1), 183 - 191. DOI: 10.1016/jat.2004.09.001.
Search in Google Scholar
Song, F., Liu, Y., Wu, H. & He, M. (2006). A novel titanosilicate with MWW structure: Highly effective liquidphase ammoximation of cycloheksanone.237(2), 359 - 367. DOI: 10.1016/j.jcat.2005.11.018.
Open DOI Search in Google Scholar
Vayssilov, G. (1997). Structural and physicochemical features of titanium siliclites.39, 209.
Open DOI Search in Google Scholar
Saxton, R. (1999). Crystalline microporous titanium silicalites.9(1 - 2), 43 - 57. DOI: 10.1023/A:1019102320274.
Open DOI Search in Google Scholar
Camblor, M., Corma, A., Martinez, A. & Perez-Pariente, J. (1992). Synthesis of titaniumsilicoaluminate isomorphous to zeolite beta and its application as a catalyst for the selective oxidation of large organic molecules.8, 589 - 590.
Search in Google Scholar
Wu, P., Tatsumi, T., Komatsu, T. & Yashima, T. (2001). A novel titanosilicate with MWW structure. I. Hydrothermal synthesis, elimination of extraframework titanium, and characterizations.105(15), 2897 - 2905. DOI: 10.1021/jp002816s.
Open DOI Search in Google Scholar

Articles in this issue

DOI: https://doi.org/10.2478/v10026-009-0015-0 | Journal eISSN: 3072-0389 (formerly 1899-4741) | Journal ISSN: 1509-8117

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Language: English

Page range: 64 - 71

Published on: Apr 6, 2009

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

TS-1,

Ti-Beta,

Ti-MWW,

titanium-silicalite catalysts

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2009 Agnieszka Wróblewska, Anna Fajdek, Eugeniusz Milchert, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 11 (2009): Issue 1 (March 2009)