Size-dependent growth kinetics of vitamin C crystals in water solutions of L(+)-ascorbic acid with the addition of methanol and ethanol

Bogusława Wierzbowska; Krzysztof Piotrowski; Joanna Koralewska; Andrzej Matynia

doi:10.2478/v10026-008-0015-5

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Size-dependent growth kinetics of vitamin C crystals in water solutions of L(+)-ascorbic acid with the addition of methanol and ethanol

Green Sciences

Volume 10 (2008): Issue 1 (March 2008)

By: Bogusława Wierzbowska, Krzysztof Piotrowski, Joanna Koralewska and Andrzej Matynia

Open Access

|Apr 2008

Abstract

Growth kinetics of vitamin C crystals during the batch mass crystallization process in L(+)-ascorbic acid - methanol - ethanol - water system was determined. The linear growth rate values were estimated on the basis of the product crystal size distributions. The kinetic model of the continuous process in a MSMPR crystallizer was adopted for the batch mode description according to Nyvlt's conception, taking the sizedependent growth (SDG) rate effects into consideration. The kinetic parameter values were determined with a Rojkowski hyperbolic SDG model. A good compatibility between the experimental product crystal population density distributions and the SDG model predictions was observed. The interpretation of the kinetic data was presented and discussed.

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Articles in this issue

DOI: https://doi.org/10.2478/v10026-008-0015-5 | Journal eISSN: 3072-0389 (formerly 1899-4741) | Journal ISSN: 1509-8117

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Language: English

Page range: 60 - 65

Published on: Apr 3, 2008

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

vitamin C,

methanol,

ethanol,

batch cooling crystallizer,

crystals growth rate,

size-dependent growth (SDG) kinetics

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2008 Bogusława Wierzbowska, Krzysztof Piotrowski, Joanna Koralewska, Andrzej Matynia, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 10 (2008): Issue 1 (March 2008)