Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

Grzegorz Lewandowski; E. Rytwińska; Eugeniusz Milchert

doi:10.2478/v10026-007-0066-z

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Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

Green Sciences

Volume 9 (2007): Issue 3 (September 2007)

By: Grzegorz Lewandowski, E. Rytwińska and Eugeniusz Milchert

Open Access

|Nov 2007

Abstract

The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)₆ were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)₆). According to the design 20 experiments were performed at the constant temperature of 70°C.

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DOI: https://doi.org/10.2478/v10026-007-0066-z | Journal eISSN: 3072-0389

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Language: English

Page range: 105 - 107

Published on: Nov 6, 2007

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: 4 issues per year

Keywords:

epoxidation,

tert-butyl hydroperoxide,

(1Z,5E,9E)-1,5,9-cyclododecatriene,

1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene,

design of experiments,

optimization

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2007 Grzegorz Lewandowski, E. Rytwińska, Eugeniusz Milchert, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 9 (2007): Issue 3 (September 2007)