Simple method of copper analysis using monosodium glutamate and its application in ore analysis

Prasetyo, Erik

doi:10.2478/v10002-012-0002-6

Abstract

A simple photometric method for copper (II) analysis using monosodium glutamate (MSG) is presented. The method is technically simple, inexpensive, quantitative, and makes use of readily available reagents. The rapid reaction of copper (II) with glutamate in aqueous solution at pH 10 to form a blue complex serves as a basis for the determination of copper (II) in the range of 10-500 μg/ml. Copper recovery is > 82%. The method could be used to determine copper (II) concentrations in iron ore samples.

References

Al-Sibaai, A. A., & Fogg, A. G. (1973). Stability of dilute standard solutions of antimony, arsenic, iron and rhenium used in colorimetry. Analyst, 98, 732-738 DOI: 10.1039/AN9739800732.10.1039/an9739800732
Search in Google Scholar
Bastug, A. S., Goz, S. E., Talman, Y., Gokturk, S., Asil, E., & Caliskan, E. (2011). Formation constants and coordination thermodynamics for binary complexes of Cu(II) and some α-amino acids in aqueous solution. Journal of Coordination Chemistry, 64(2), 281-292. DOI: 10.1080/00958972.2010.541454.10.1080/00958972.2010.541454
Search in Google Scholar
Butler, E. J., & Forbes, D. H. S. (1965). A comparison of three absorptiometric methods for the determination of copper in biological materials. Analytica Chimica Acta, 33, 59-66. DOI: 10.1016/S0003-2670(01)84854-6.10.1016/S0003-2670(01)84854-6
Search in Google Scholar
Castro, B., Lima, J. L. F. C., & Reis, S. (1995). Potentiometric determination of formation constants of copper(II)/bile acid/peptide in aqueous solute. Journal of Pharmaceutical and Biomedical Analysis, 13(4/5) 465-470.
Search in Google Scholar
Ghasemi, J., Ahmadi, Sh., & Torkestani, K. (2003). Simultaneous determination of copper, nickel, cobalt and zinc using zincon as a metallochromic indicator with partial least squares. Analytica Chimica Acta, 487(2), 181-188. DOI: 10.1016/S0003-2670(03)00556-7.10.1016/S0003-2670(03)00556-7
Search in Google Scholar
Hamada, Y. Z., Holyfield, H., Rosli, K., & Burkey, T. (2009). Equilibrium models of Cr3+ and Cu2+ with glutamate. Journal of Coordination Chemistry, 62(5), 721-733. DOI: 10.1080/00958970802353660.10.1080/00958970802353660
Search in Google Scholar
Hoste, J., Eeckhout, J., & Gillis, J. (1953). Spectrophotometric determination of copper with cuproine. AnalyticaChimica Acta, 9, 263-274.10.1016/S0003-2670(01)80768-6
Search in Google Scholar
Irving, H. M., & Tomlinson, W. R. (1968). Effect of chromium(III) and of other ions on the absorptiometric determination of copper with 2, 2'-biquinolyl. Talanta, 15(11), 1267-1279. DOI: org/10.1016/0039-9140(68)80049-9.10.1016/0039-9140(68)80049-9
Search in Google Scholar
Jacobsen, E., Langmyhr, F. J., & Selmer-Olsen, A. R. (1961). On the use of bis-cyclohexanone-oxalyldihydrazone and bis-acetaldehyde-oxalyldihydrazone in the analysis of copper. Analytica Chimica Acta, 24, 579-588. DOI: 10.1016/0003-2670(61)80120-7.10.1016/0003-2670(61)80120-7
Search in Google Scholar
Kállay, C., Várnagy, K., Micera, G., Sanna, D., & Sóvágó, I. (2005). Copper (II) complexes of oligopeptides containing aspartyl and glutamyl residues. Potentiometric and spectroscopic studies. Journal of Inorganic Biochemistry, 99(7), 1514-1525. DOI: 10.1016/j.jinorgbio.2005.04.009.10.1016/j.jinorgbio.2005.04.00915927267
Search in Google Scholar
Kumar, B., Singh, H. B., Katyal, M., & Sharma, R. L. (1991). Spectrophotometric and derivative spectrophotometric determination of copper (II) with dithizone in aqueous phase. Microchimica Acta, 105(1-3), 79-87.10.1007/BF01245203
Search in Google Scholar
Larsen, E. R., (1974). Spectrophotometric determination of copper in fertilizer with neocuproine. AnalyticalChemistry, 46(8), 1131-1132. DOI: 10.1021/ac60344a047.10.1021/ac60344a047
Search in Google Scholar
Laznicka, P. (2006). Giant metallic deposit: Future Sources of Industrial Metals. Berlin: Springer Verlag.
Search in Google Scholar
Marczenko, Z., & Balcerzak, M. (2000). Separation, Preconcentration and Spectrophotometry in InorganicAnalysis. Amsterdam: Elsevier.
Search in Google Scholar
Moon, C. J., Whateley, M. K. G., & Evans, A. M. (2006). Introduction to Mineral Exploration (2 ed.). Blackwell Publishing.
Search in Google Scholar
Ninomiya, K., (1998). Natural occurrence. Food Reviews International, 14(2-3), 177-211.10.1080/87559129809541157
Search in Google Scholar
Peterson, R. E., & Bollier, M. E. (1955). Spectrophotometric determination of serum copper with biscyclohexanone oxalydishydrasone. Analytical Chemistry, 27, 1195-1197.10.1021/ac60103a054
Search in Google Scholar
Ravnik, V., Dermelj, M., & Kosta, L. (1974). A highly selective diethyldithiocarbamate extraction system in activation analysis of copper, indium, manganese and zinc, Application to the analysis of standard reference materials. Journal of Radioanalytical and Nuclear Chemistry, 20(2), 443-453. 146 Sabel, C. E., Neureuther, J. M., & Siemann, S. (2010). A spectrophotometric method for the determination of zinc, copper, and cobalt ions in metalloproteins using Zincon. Analytical Biochemistry, 397, 218-226. DOI: 10.1016/j.ab.2009.10.037.10.1016/j.ab.2009.10.037
Search in Google Scholar
San Andres, M. P., Marina, M. L., & Vera, S. (1994). Spectrophotometric determination of copper(II), nickel(II) and cobalt(II) as complexes with sodium diethyldithiocarbamate in cationic micellar medium of exadecyltrimethylammonium salts. Talanta, 41(2), 179-185. DOI: 10.1016/0039-9140(94)80105-3.10.1016/0039-9140(94)80105-3
Search in Google Scholar
Shah, S. M., & Paul, J. (1972). Simultaneous determination of copper and manganese with sodium diethyl dithiocarbamate. Microchemical Journal, 17(1), 119-124. DOI: 10.1016/0026-265X(72)90046-X.10.1016/0026-265X(72)90046-X
Search in Google Scholar
Stoner, R. E., & Dasler, W. (1964). Spectrophotometric Determination of Microgram Quantities of Copper in Biologic Materials; Clinical Chemistry, 10, 845-852.10.1093/clinchem/10.9.845
Search in Google Scholar
Thakur, M., & Deb, M. K. (1999). The use of 1-[pyridyl-(2)-azo]-naphthol-(2) in the presence of TX-100 and N,N%-diphenylbenzamidine for the spectrophotometric determination of copper in real samples. Talanta,49(3), 561-569.10.1016/S0039-9140(99)00054-5
Search in Google Scholar

Simple method of copper analysis using monosodium glutamate and its application in ore analysis

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