Time dependence of the luminescence intensity in CdBr2: AgCl,PbBr2 crystals under N2-laser excitation at room temperature

I. Bolesta; B. Kalivoshka; I. Karbovnyk; V. Lesivtsiv; I. Novosad; S. Novosad; I. Rovetskyy; S. Velgosh

doi:10.2478/s13536-014-0232-y

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Time dependence of the luminescence intensity in CdBr2: AgCl,PbBr2 crystals under N2-laser excitation at room temperature

Materials Science-Poland

Volume 32 (2014): Issue 4 (December 2014)

By: I. Bolesta, B. Kalivoshka, I. Karbovnyk, V. Lesivtsiv, I. Novosad, S. Novosad, I. Rovetskyy and S. Velgosh

Open Access

|Dec 2014

Abstract

Results of optical-luminescence studies of polydoped photochromic CdBr2: AgCl,PbBr2 crystals are presented. It is shown that the luminescence decrease vs. time under N2-laser excitation in the range of A-band of Pb2+ absorption is due to photochemical reactions. The empirical model describing the decrease of the luminescence related to silver impurities due to photochemical processes is suggested. Model parameters (trapping cross-section — σ — and the amount of centres destroyed by irradiation — β) were determined using the comparative analysis of experimental and calculated luminescence decay curves.

References

[1] Dürr H., Bouas-laurent H., Photochromism: Molecules and Systems, Elsevier, 2003.
Search in Google Scholar
[2] Delaire J.A., Nakatani K., Chem. Rev., 100(5) (2000), 1817. http://dx.doi.org/10.1021/cr980078m10.1021/cr980078m
Search in Google Scholar
[3] Megla G.K., Appl. Optics, 5(6) (1966), 945. http://dx.doi.org/10.1364/AO.5.00094510.1364/AO.5.000945
Search in Google Scholar
[4] Araujo R.J., Appl. Optics, 7(5) (1968), 781. http://dx.doi.org/10.1364/AO.7.00078110.1364/AO.7.000781
Search in Google Scholar
[5] Scott J.L., Tanaka K., Cryst. Growth Des., 5(3) (2005), 1209. http://dx.doi.org/10.1021/cg049591l10.1021/cg049591l
Search in Google Scholar
[6] Bensouici A., Plaza J.L., Dieguez E. et al., J. Lumin., 130(4) (2010), 688. http://dx.doi.org/10.1016/j.jlumin.2009.11.02010.1016/j.jlumin.2009.11.020
[7] Lyskovich A.B. (Ed.), Wide-gap Layered Crystals and Their Physics Properties, Vyscha Shkola, Lvov, 1982 (in rus.).
Search in Google Scholar
[8] Brodin M.S., Blonsky I.V., Excitonic Processes in Layered Crystals, Kiev, Naukova Dumka, 1986 (in rus.).
Search in Google Scholar
[9] Lyskovich O.B., Novosad S.S., Kravchuk O.Y., Ukr. J. Phys., 40(9) (1995), 1001 (in ukr.).
Search in Google Scholar
[10] Novosad S.S., Gal’chynskyy O.V., Kovalyuk R.O., Nucl. Instrum. Meth., 116,1916 (1996), 265. http://dx.doi.org/10.1016/0168-583X(96)00058-410.1016/0168-583X(96)00058-4
Search in Google Scholar
[11] Novosad S.S., Novosad I.S., PCSS, 8(4) (2007), 759 (in ukr.).
Search in Google Scholar
[12] Novosad S.S., Novosad I.S., Funct. Mater., 11,2 (2004), 258.
Search in Google Scholar
[13] Novosad S.S., Novosad I.S., Borodchuk A.V., Inorg. Mater.+, 41,(2) (2005), 235. 10.1007/s10789-005-0041-0
Search in Google Scholar
[14] Novosad S.S., Kostyuk B.M., Ukr. J. Phys., 42(5) (1997), 568 (in ukr.).
Search in Google Scholar
[15] Lyskovich A.B., Martyniv S.D., Novosad S.S., Kostyuk B.M., Inorg. Mater.+, 34(8) (1998), 974 (in rus.).
Search in Google Scholar
[16] Novosad S.S., Novosad I.S., Kalivoshka B.M., Phys. Solid. State+, 53,8 (2011), 1548 (in rus.). 10.1134/S1063783411080233
Search in Google Scholar
[17] Novosad S.S., Kostyuk B.M., Ukr. J. Phys., 43,7 (1998), 871 (in ukr.).
Search in Google Scholar
[18] Novosad S.S., Kostyuk B.M., Funct. Mater., 5,2 (1998), 171.
Search in Google Scholar
[19] Novosad S.S., Ukr. J. Phys., 43,3 (1998), 338 (in ukr.).
Search in Google Scholar
[20] Georgobiani A.N., Sheikman M.K. (Eds.), Physics of A IIB VICompounds, Nauka, Moscow, 1986 (in rus.).
[21] Gurvich A.M., Introduction in Physical Chemistry of Crystal Luminophors, Vysshaya Shkola, Moscow, 1982 (in rus.).
Search in Google Scholar
[22] Novosad S.S., Kalivoshka B.M., Phys. Solid. State+, 51,6 (2009), 1072 (in rus.). 10.1134/S1063783409060080
Search in Google Scholar
[23] Novosad S.S., Kalivoshka B.M., PCSS, 8,4 (2007), 753 (in ukr.).
Search in Google Scholar
[24] Bolesta I.M., Velgosh S.R., Karbovnyk I.D. et al., Phys. Solid. State+, 54,10 (2012), 1935 (in rus.).
[25] Kolomiets B.T., Mamontova T.N., Chernyshov A.V., Sov. Phys. Semicond., 17,9 (1983), 708 (in rus.).
Search in Google Scholar
[26] Mamontova T.N., Chernyshov A.V., Sov. Phys. Semicond., 18,3 (1984), 332 (in rus.).
Search in Google Scholar

Articles in this issue

DOI: https://doi.org/10.2478/s13536-014-0232-y | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331

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Language: English

Page range: 604 - 609

Published on: Dec 19, 2014

Published by: Wroclaw University of Science and Technology

In partnership with: Paradigm Publishing Services

Publication frequency: 4 issues per year

Keywords:

cadmium bromide,

luminescence,

absorption,

photochemical reactions

Related subjects:

Materials sciences,

Materials sciences, other,

Nanomaterials,

Functional and smart materials,

Materials characterization and properties

© 2014 I. Bolesta, B. Kalivoshka, I. Karbovnyk, V. Lesivtsiv, I. Novosad, S. Novosad, I. Rovetskyy, S. Velgosh, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Volume 32 (2014): Issue 4 (December 2014)