Photo-induced superhydrophilicity of nanocomposite TiO2-SiO2 thin film

Akbar Eshaghi; Amir Dashti; Ameneh Eshaghi; Reza Mozaffarinia

doi:10.2478/s13536-011-0005-9

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Photo-induced superhydrophilicity of nanocomposite TiO2-SiO2 thin film

Materials Science-Poland

Volume 29 (2011): Issue 1 (March 2011)

By: Akbar Eshaghi, Amir Dashti, Ameneh Eshaghi and Reza Mozaffarinia

Open Access

|Aug 2011

Abstract

In this work, TiO2 and TiO2-SiO2 thin films on glass substrates were prepared by the sol-gel dip coating process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to evaluate the structural and chemical properties of the films. The super-hydrophilicity was assessed by water contact angle measurement. XRD measurements confirmed the presence of polycrystalline anatase and rutile phases in the films. The water contact angle measurements showed that addition of SiO2 has a significant effect on the super-hydrophilicity of TiO2 thin films, especially if they are stored in a dark place.

References

[1] MENGA F., SUN Z., Appl. Surf. Sci., 1255 (2009), 13.
Search in Google Scholar
[2] POMONI K., VOMVAS A., TRAPALIS C., Thin Solid Films., 516 (2008), 1271. http://dx.doi.org/10.1016/j.tsf.2007.05.04010.1016/j.tsf.2007.05.040
Search in Google Scholar
[3] TAGA Y., Thin Solid Films., 517 (2009), 3167. http://dx.doi.org/10.1016/j.tsf.2008.11.08710.1016/j.tsf.2008.11.087
Search in Google Scholar
[4] KAFIZA A., KELLICI S., DARR J.A., PARKIN I.P., J. Photochem. Photobiol. A: Chem. 204 (2009), 183. http://dx.doi.org/10.1016/j.jphotochem.2009.03.01710.1016/j.jphotochem.2009.03.017
Search in Google Scholar
[5] DENISSON K.R., BOXALL C., Langmuir., 23 (2007), 4358. http://dx.doi.org/10.1021/la063347+10.1021/la063347+
Search in Google Scholar
[6] FUJISHIMA A., ZHANG X., C. R. Chimie., 9 (2006), 750. http://dx.doi.org/10.1016/j.crci.2005.02.05510.1016/j.crci.2005.02.055
Search in Google Scholar
[7] FUJISHIMA A., ZHANG X, TRYK D.A., Surf. Sci. Reports., 63 (2008), 515. http://dx.doi.org/10.1016/j.surfrep.2008.10.00110.1016/j.surfrep.2008.10.001
Search in Google Scholar
[8] FUNAKOSHI K., NONAMI T., J. Coat. Technol. Res., 4 (2007), 327. http://dx.doi.org/10.1007/s11998-007-9030-310.1007/s11998-007-9030-3
Search in Google Scholar
[9] NAKAMURA M., Thin Solid Films., 496 (2006), 131. http://dx.doi.org/10.1016/j.tsf.2005.08.25410.1016/j.tsf.2005.08.254
Search in Google Scholar
[10] GUAN K., LU B., YINY., Surf. Coat. Technol. 173 (2003) 219. http://dx.doi.org/10.1016/S0257-8972(03)00521-810.1016/S0257-8972(03)00521-8
Search in Google Scholar
[11] CHEN J., POON C.S., Build. Environ., 44 (2009), 1899. http://dx.doi.org/10.1016/j.buildenv.2009.01.00210.1016/j.buildenv.2009.01.002
Search in Google Scholar
[12] SIMONSEN M.E., JENSEN H., LI Z., SOGAARD E.G., J. Photochem. Photobiol. A: Chem. 200 (2008), 192. http://dx.doi.org/10.1016/j.jphotochem.2008.07.01310.1016/j.jphotochem.2008.07.013
Search in Google Scholar
[13] OHDAIRA T., NAGAI H., KAYANO S., KAZUHITO H., Surg. Endosc., 21 (2007), 333. http://dx.doi.org/10.1007/s00464-006-0795-810.1007/s00464-006-0795-8
Search in Google Scholar
[14] SAKAI N., FUJISHIMA A., WATANABE T., HASHIMOTO K., J. Phys. Chem. B., 105 (2001), 3023. http://dx.doi.org/10.1021/jp003212r10.1021/jp003212r
Search in Google Scholar
[15] NOSAKA A.Y., KOJIMA E., FUJIWARA T., YAGI H., AKUTSU H., NOSAKA Y., J. Phys. Chem. B. 107 (2003), 12042. http://dx.doi.org/10.1021/jp035526v10.1021/jp035526v
Search in Google Scholar
[16] KONTOS A.I, KONTOS A.G., TSOUKLERIS D.S., VLACHOS G.D., FALARAS P., Thin Solid Films 515 (2007), 7370. http://dx.doi.org/10.1016/j.tsf.2007.02.08210.1016/j.tsf.2007.02.082
Search in Google Scholar
[17] SHARMA S.D, SINGH D., SAINI K.K., KANT C., SHARMA V., JAIN S.C, SHARM C.P., Appl. Catal. A General. 314 (2006) 40–46. http://dx.doi.org/10.1016/j.apcata.2006.07.02910.1016/j.apcata.2006.07.029
Search in Google Scholar
[18] FUJISHIMA A, RAO T.N., TRYK D.A., J. Photochem. Photobiol. C Photochem. Rev. 1 (2000) 1. http://dx.doi.org/10.1016/S1389-5567(00)00002-210.1016/S1389-5567(00)00002-2
Search in Google Scholar
[19] MACHIDA M., NORIMOTO K., WATANABE T., HASHIMOTO K., FUJISHIMA A., J. Mater. Sci., 34 (1999), 2569. http://dx.doi.org/10.1023/A:100464451465310.1023/A:1004644514653
Search in Google Scholar
[20] GUAN K., YIN Y., Mater. Chem. Phys., 92 (2005), 10. http://dx.doi.org/10.1016/j.matchemphys.2004.01.04410.1016/j.matchemphys.2004.01.044
Search in Google Scholar
[21] SREEMANY M., SEN S., Mater. Chem. Phys., 83 (2004), 169. http://dx.doi.org/10.1016/j.matchemphys.2003.09.03010.1016/j.matchemphys.2003.09.030
Search in Google Scholar
[22] SHARMA S.D, SINGH D., SAINI K.K, KANT C., SHARMA V., JAIN S.C, SHARMA C.P., Appl. Catal. A General., 314 (2006), 40. http://dx.doi.org/10.1016/j.apcata.2006.07.02910.1016/j.apcata.2006.07.029
Search in Google Scholar
[23] LUCA D., MARDARE D., IACOMI F., TEODORESCU C.M., Appl. Surf. Sci., 252(2006), 6122. http://dx.doi.org/10.1016/j.apsusc.2006.05.01110.1016/j.apsusc.2006.05.011
Search in Google Scholar
[24] CHEN J., YAO M., WANG X., J. Nanopart. Res., 10 (2008), 163. http://dx.doi.org/10.1007/s11051-007-9237-310.1007/s11051-007-9237-3
Search in Google Scholar
[25] DOSS C.J, ZALLEN R., Phys. Rev. B Condense Mater., 48 (1993), 15626. http://dx.doi.org/10.1103/PhysRevB.48.1562610.1103/PhysRevB.48.15626
Search in Google Scholar
[26] YU J., ZHAO X., YU J., ZHONG G., J. Mater. Sci. Lett., 20 (2001), 1745. http://dx.doi.org/10.1023/A:101245841171710.1023/A:1012458411717
Search in Google Scholar
[27] TAKEUCHI M., BERTINETTI L., MARATA G., COLUCCIA S., ANPO M., Appl. Catal. A General. 307 (2006), 13. http://dx.doi.org/10.1016/j.apcata.2006.03.00210.1016/j.apcata.2006.03.002
Search in Google Scholar
[28] PARK J.K., KIM H.K., J. Mater. Process. Technol., 1861–3 (2007), 367. http://dx.doi.org/10.1016/j.jmatprotec.2006.12.00410.1016/j.jmatprotec.2006.12.004
Search in Google Scholar
[29] JENSEN H., SOLOVIEV A., LI Z., SOGAARD E.G., Appl. Surf. Sci., 246 (2005), 239. http://dx.doi.org/10.1016/j.apsusc.2004.11.01510.1016/j.apsusc.2004.11.015
Search in Google Scholar
[30] TANABE K., SUMIYOSHI T., SHIBATA K., KIYOUR T, J. Bull. Chem. Soc. Japan, 47 (1974), 1064. http://dx.doi.org/10.1246/bcsj.47.106410.1246/bcsj.47.1064
Search in Google Scholar
[31] EHRMAN S.H., FRIEDLANDER S.K., ZACHARIAH M.R., J. Mater. Res., 1412(1999), 4551. http://dx.doi.org/10.1557/JMR.1999.061710.1557/JMR.1999.0617
Search in Google Scholar
[32] CARTER C.B., NORTON M.G., Ceramic Materials; Science and Technology. Springer, 2007.
Search in Google Scholar
[33] YU J., YU J.C., HO W., JIANG Z., New J. Chem., 26 (2002), 607. http://dx.doi.org/10.1039/b200964a10.1039/b200964a
Search in Google Scholar
[34] YU J.C., YU J., HO W., ZHAO J., J. Photochem. and Photobiol. A Chem., 148 (2002) 331. http://dx.doi.org/10.1016/S1010-6030(02)00060-610.1016/S1010-6030(02)00060-6
Search in Google Scholar

Articles in this issue

DOI: https://doi.org/10.2478/s13536-011-0005-9 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331

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Language: English

Page range: 22 - 28

Published on: Aug 3, 2011

Published by: Wroclaw University of Science and Technology

In partnership with: Paradigm Publishing Services

Publication frequency: 4 issues per year

Keywords:

sol-gel,

Related subjects:

Materials sciences, other,

Nanomaterials,

Functional and smart materials,

Materials characterization and properties

© 2011 Akbar Eshaghi, Amir Dashti, Ameneh Eshaghi, Reza Mozaffarinia, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Volume 29 (2011): Issue 1 (March 2011)