Influence of the kind and concentration of ethoxylated alcohols on the transport of citric acid through polymer inclusion membranes

Marcin Dudek; Marta Przewoźna; Piotr Gajewski; Mariusz B. Bogacki

doi:10.2478/pjct-2013-0074

.blurhash-client-img { display: none !important; }

Influence of the kind and concentration of ethoxylated alcohols on the transport of citric acid through polymer inclusion membranes

Green Sciences

Volume 15 (2013): Issue 4 (December 2013)

By: Marcin Dudek, Marta Przewoźna, Piotr Gajewski and Mariusz B. Bogacki

Open Access

|Dec 2013

Abstract

Research into the influence of ethoxylated alcohols on the citric acid transport through polymer inclusion membranes (PIMs) has been carried out. This process may be used in the future as one of the methods of citric acid isolation. Ethoxylated alcohols, which were GENAPOL® X020, X060 and X150, served as both: plasticizer and carrier. The results showed that the maximum values of citric acid fl ux [mol/(m².s)] were equal to: 1.02.10^-4 (X020), 1.57.10^-4 (X060) and 1.77.10^-4 (X150). The obtained results allow proceeding further study on using the polymer inclusion membranes, as an alternative to traditional methods of citric acid separation, which are precipitation and extraction.

References

1. Kristiansen, B., Mattey, M. & Linden, J. (2002). Citricacid biotechnology (1st ed.). Taylor and Francis.
Search in Google Scholar
2. Dhillon, G.S., Brar, S.K. , Verma, M. & Tyagi, R.D. (2011). Recent advances in citric acid bio-production and recovery. Food Bioprocess Technol. 4(4), 505-509. DOI: 10.1007/s11947-010-0399-0.10.1007/s11947-010-0399-0
Open DOI Search in Google Scholar
3. Papanikolaou, S., Munigl ia, L., Chevalot, I., Aggelis, G. & Marc, I. (2002). Yarrowia lipolytica as a potential producer of citric acid from raw glycerol. J. Appl. Microbiol. 92 (4), 737-744. DOI: 10.1046/j.1365-2672.2002.01577.x.10.1046/j.1365-2672.2002.01577.x
Open DOI Search in Google Scholar
4. Rywińska, A., Rymowicz, W. , Żarowska, B. & Wojtatowicz, M. (2009). Biosynthesis of citric acid from glicerol by acetale mutants of Yarrowia lipolytica in fed-batch fermentation. FoodTechnol. Biotechnol. 47, 1-6.
Search in Google Scholar
5. Soccol, C., Vandenberghe, L. & Rodrigues, C. (2008). Current Developments in solid-state fermentation. Productionof Organic Acids by Solid-state Fermentation, (pp. 205-229). Springer New York, Retrieved October, 2011, from Springer- Link, http://link.springer.com/book/10.1007/978-0-387-75213-6/ page/1. DOI: 10.1007/978-0-387-75213-6_10.10.1007/978-0-387-75213-6_10
Open DOI Search in Google Scholar
6. da Silva, G.P., Mack, M. & Contiego, J. (2009). Glicerol: A promising and abundant carbon source for industrial microbiology. Biotechnol. Adv. 27, 30-39. DOI: 10.1016/j.biotechadv. 2008.07.006.10.1016/j.biotechadv.2008.07.006
Open DOI Search in Google Scholar
7. Kirsch, T., Ziegenfuss, H. & Maurer, G. (1997). Distribution of citric, acetic and oxalic acids between water and organic solutions of tri-n-octylamine. Fluid Phase Equilib. 129, 235-266.10.1016/S0378-3812(96)03154-8
Search in Google Scholar
8. Juang, R.S., Huang, R.H. & Wu, R.T. (1997). Separation of citric and lactic acids in aqueous solutions by solvent extraction and liquid membrane processes. J. Membr. Sci. 136, 89-99.10.1016/S0376-7388(97)00176-2
Search in Google Scholar
9. Walkowiak, W., Kozłowski, C.A., Pellowski, W. (2003). Zastosowanie polimerowych membran inkluzyjnych do wydzielania i separacji jonów metali. Membrany teoria i praktyka (pp. 47-78). Toruń, Poland, Wydawnictwo UMK.
Search in Google Scholar
10. Kim, J.S., Kim, S.K. & Ko, J.W. (2000). Selective transport of cesium ion in polymeric VTA membrane containing calixcrown ethers. Talanta 52, 1143-1148.10.1016/S0039-9140(00)00489-6
Search in Google Scholar
11. Sak ai, Y., Kadota, K. & Hayashita, T. (2010). The effect of the counter anion on the transport of thiourea in a PVC-based polymer inclusion membrane using Capriquat as carrier. J. Membr. Sci. 346(2), 250-255. DOI: 10.1016/j.memsci. 2009.09.038.10.1016/j.memsci.2009.09.038
Open DOI Search in Google Scholar
12. Per eira, N., St. John, A. & Cattrall, R. (2009). Infl uence of composition of polymer inclusion membranes on their homogeneity and fl exibility. Desalination 236(1-3), 327-333. DOI: 10.1016/j.desal.2007.10.083.10.1016/j.desal.2007.10.083
Open DOI Search in Google Scholar
13. Ngh iem, L.D., Mornane, P., Potter, I.D., Perera, J.M., Cattrall, R.W. & Kolev, S.D. (2006). Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). J. Membr. Sci. 281(1-2), 7-41. DOI: 10.1016/j.memsci.2006.03.035.10.1016/j.memsci.2006.03.035
Open DOI Search in Google Scholar
14. Lamb, J.D. & Nazarenko, A.Y. (1997). Lead(II) ion sorption and transport using polymer inclusion membranes containing tri-octylphosphine oxide. J. Membr. Sci. 134(2), 327-333. DOI: 10.1016/S0376-7388(97)00115-4.10.1016/S0376-7388(97)00115-4
Open DOI Search in Google Scholar
15. Gaj da, B., Skrzypczak, A. & Bogacki, M.B. (2010). Separation of cobalt (II), nickel (II), zinck (II) and cadium (II) ions from chloride solutions. Physicochem. Probl. Miner. Process. 46, 289-294.
Search in Google Scholar
16. Pos piech, B. & Walkowiak, W. (2007). Separation of copper(II), cobalt(II) and nickel(II) from chloride solutions by polymer inclusion membranes. Sep. Purif. Technol. 57(3), 461-465. DOI: 10.1016/j.seppur.2006.07.005.10.1016/j.seppur.2006.07.005
Open DOI Search in Google Scholar
17. Alm eida, M. (2012). Recent trends in extraction and transport of metal ions using polymer inclusion membranes (PIMs).\ J. Membr. Sci. 416, 9-23. DOI: 10.1016/j.memsci.2012.06.00610.1016/j.memsci.2012.06.006
Open DOI Search in Google Scholar
18. Mat sumoto, M., Takagi, T. & Kondo, K. (1998). Separation of lactic acid using polymeric membrane containing a mobile carrier. J. Ferment. Bioeng. 85(5), 483-487. DOI: 10.1016/ S0922-338X(98)80066-4.10.1016/S0922-338X(98)80066-4
Open DOI Search in Google Scholar
19. Gaj ewski, P. & Bogacki, M.B. (2012). Infl uence of Alkyl Chain Length in 1-Alkylimidazol on the Citric Acid Transport Rate across Polymer Inclusion Membrane, Separ. Sci. Technol. 47, 1374-1382. DOI: 10.1080/01496395.2012.672517.10.1080/01496395.2012.672517
Search in Google Scholar
20. Aro us, O., Saad Saoud, F. & Kerdjoudj, H. (2010). Cellulose triacetate properties and their effect on the thin fi lms morphology and performance. Innovations in Thin Film Processing and Characterisation. 17-20 November 2009, (pp. 1-5), Nancy, France.
Search in Google Scholar
21. Munro, T.A. & Smithe, B.D. (1997). Facilitated transport of amino acids by fi xed-site jumping. Chem. Commun. 2167-2168.10.1039/a702390a
Open DOI Search in Google Scholar
22. Riggs, J.A. & Smith, B.D. (1997). Facilitated Transport of Small Carbohydrates through Plasticized Cellulose Triacetate. J. Am. Chem. Soc. 119(11), 2765-2766.10.1021/ja964103m
Search in Google Scholar
23. White, K.M., Smith, B.D., Duggan, P.J., Sheahan, S.L. & Tyndall, E.M. (2001). Mechanism of facilitated saccharide transport through plasticized cellulose triacetate membranes. J. Membr. Sci. 194, 165-175. 10.1016/S0376-7388(01)00487-2
Search in Google Scholar

Articles in this issue

DOI: https://doi.org/10.2478/pjct-2013-0074 | Journal eISSN: 3072-0389

Journal RSS Feed

Language: English

Page range: 89 - 94

Published on: Dec 31, 2013

Published by: West Pomeranian University of Technology, Szczecin

In partnership with: Paradigm Publishing Services

Publication frequency: Volume open

Keywords:

citric acid,

polymer inclusion membranes,

ethoxylated alcohols

Related subjects:

Industrial chemistry,

Biotechnology,

Chemical engineering,

Process engineering

© 2013 Marcin Dudek, Marta Przewoźna, Piotr Gajewski, Mariusz B. Bogacki, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 15 (2013): Issue 4 (December 2013)