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Corrosion resistance of PPTA Ni-based hardfacing layers Cover

Corrosion resistance of PPTA Ni-based hardfacing layers

Open Access
|Dec 2024

Figures & Tables

Figure 1

OM images after 3% nital etching of the interface line (cross-section): reference material S1 (a), S2 (b and c), S3 (d and e), and S4 (f and g).
OM images after 3% nital etching of the interface line (cross-section): reference material S1 (a), S2 (b and c), S3 (d and e), and S4 (f and g).

Figure 2

Cross-sections of the hardfacing layers at lower magnifications (200×) (S2 (a), S3 (c), and S4 (e)) and higher magnifications (500×) (S2 (b), S3 (d), and S4 (f)).
Cross-sections of the hardfacing layers at lower magnifications (200×) (S2 (a), S3 (c), and S4 (e)) and higher magnifications (500×) (S2 (b), S3 (d), and S4 (f)).

Figure 3

Top view SEM images of tested materials before the electrochemical corrosion (S2 (a), S3 (c), and S4 (e)) and after the process (S2 (b), S3 (d), and S4 (f)); magnification: 1,000×.
Top view SEM images of tested materials before the electrochemical corrosion (S2 (a), S3 (c), and S4 (e)) and after the process (S2 (b), S3 (d), and S4 (f)); magnification: 1,000×.

Figure 4

SEM images of the cross-section of S2 (a), S3 (c), and S4 (e) samples. EDS spectra of the characteristic obtained from the surface of S2 (b), S3 (d), and S4 (f) samples.
SEM images of the cross-section of S2 (a), S3 (c), and S4 (e) samples. EDS spectra of the characteristic obtained from the surface of S2 (b), S3 (d), and S4 (f) samples.

Figure 5

Representative potentiodynamic polarization curves of hardfacing layers examined in 3.5% NaCl solution.
Representative potentiodynamic polarization curves of hardfacing layers examined in 3.5% NaCl solution.

Figure 6

SEM images of the cross-section of the corroded surface of coatings: (a) S1, (b) S2, (c) S3, and (d) S4.
SEM images of the cross-section of the corroded surface of coatings: (a) S1, (b) S2, (c) S3, and (d) S4.

Figure 7

Average values of the roughness parameter measured with the stylus profilometer.
Average values of the roughness parameter measured with the stylus profilometer.

Chemical composition of S235JR steel (in wt%) [33]_

CMnPSCuNFe
0.171.400.0350.0350.550.012Bal.

Chemical composition of feedstock powders (material no_ from Table 1)_

FeedstockElemental content (wt%)
CSiCrBNiMoCuFeW
S10.0318.0013.002.7bal.
S20.953.8016.503.30Bal.
S32.353.8016.503.30Bal.25.00
S40.504.0016.004.00Bal.3.03.0

Parameters used for hardfacing of the overlays_

Sample codeParameters
Current intensity (A)Torch speed (mm/s)Powder feed rate (g/min)
S11000.89.7
S2800.89.0
S31001.611.0
S4800.89.0

Electrochemical parameters obtained for all samples_

Sample code E OC (mV) E corr vs Ag/AgCl (mV) I corr (µA/cm2) R p (kΩ cm2) E p (mV)
Average result
S1−87.8−159.70.1213.7845
S2−262.0−290.90.3108.8535
S3−234.9−237.10.2146.8483
S4−194.4−200.30.1210.0438

Sample code and the PSD of powders [32]_

Feedstock materialSample codePSD (μm)
316LS1−150 + 45
NiCrBSiS2−125 + 45
NiCrBSi + 35 wt% WCS3−125 + 22
NiCrCuMoS4−125 + 45
DOI: https://doi.org/10.2478/msp-2024-0040 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 66 - 78
Submitted on: Aug 8, 2024
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Accepted on: Nov 13, 2024
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Published on: Dec 31, 2024
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2024 Monika Górnik, Marzena Lachowicz, Leszek Łatka, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.