Table 1
Chemical compositions of the binders.
| Materials | Chemical composition (%) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| CaO | SiO2 | Al2O3 | Fe2O3 | MgO | SO3 | K2O | Na2O | P2O5 | Others | |
| Cement | 62.59 | 21.24 | 4.78 | 3.27 | 2.53 | 2.27 | 0.45 | 0.38 | — | 2.49 |
| Fly ash | 4.80 | 48.60 | 34.31 | 6.46 | 1.04 | 0.71 | 1.21 | 0.75 | 0.58 | 1.54 |
| GGBS | 44.68 | 24.85 | 20.49 | 0.67 | 5.43 | 1.79 | 0.33 | 0.22 | 0.03 | 1.51 |
| Silica fume | 1.35 | 94.40 | 0.53 | 0.14 | 0.48 | 1.02 | 1.59 | 0.11 | 0.15 | 0.23 |
| Blended cement | 51.26 | 21.10 | 16.98 | 3.27 | 3.01 | 2.23 | 0.57 | 0.33 | 0.19 | 1.06 |

Figure 1
XRD patterns of the binders.
Table 2
Basic properties of coarse aggregates.
| Sieve no. | Maximum particle size = 19 mm | Maximum particle size = 9.5 mm | Maximum particle size = 1.6 mm | ||||||
|---|---|---|---|---|---|---|---|---|---|
| Remain weight (g) | Retention (%) | Sieving rate (%) | Remain weight (g) | Retention (%) | Sieving rate (%) | Remain weight (g) | Retention (%) | Sieving rate (%) | |
| 3/2″ | 0 | 0 | 100 | 0 | 0 | 100 | 0 | 0 | 100 |
| 1″ | 0 | 0 | 100 | 0 | 0 | 100 | 0 | 0 | 100 |
| 3/4″ | 348 | 4 | 96 | 0 | 0 | 100 | 0 | 0 | 100 |
| 1/2″ | 6,911 | 75 | 25 | 1,022 | 18 | 82 | 0 | 0 | 100 |
| 3/8″ | 8,441 | 92 | 8 | 2,641 | 47 | 53 | 11 | 0 | 100 |
| #4 | 9,109 | 99 | 1 | 5,228 | 93 | 7 | 2,815 | 57 | 43 |
| #8 | 9,140 | 100 | 0 | 5,545 | 99 | 1 | 4,636 | 93 | 7 |
| Bottom | 9,176 | 100 | 0 | 5,615 | 100 | 0 | 4,975 | 100 | 0 |
| Physical properties | |||||||||
| Moisture content (%) | 0.89 | 1.17 | 2.23 | ||||||
| Absorption (%) | 0.83 | 1.25 | 1.13 | ||||||
| Surface moisture content (%) | 0.1 | 0.1 | 1.1 | ||||||

Figure 2
SEM photograph of blended cement.
Table 3
Mix percentage of binders.
| Mix no. | w/b | Binders | ||||
|---|---|---|---|---|---|---|
| Cement (%) | GGBS (%) | Fly ash (%) | Silica fume (%) | Blended cement (%) | ||
| A1 | 0.32 | 50 | 35 | 15 | ||
| A2 | 100 | |||||
| A3 | 45 | 30 | 20 | 5 | ||
| A4 | 35 | 35 | 30 | |||
| B1 | 0.39 | 50 | 35 | 15 | ||
| B2 | 100 | |||||
| B3 | 45 | 30 | 20 | 5 | ||
| B4 | 35 | 35 | 30 | |||
Table 4
Mix proportions (kg/m3).
| Mix no. | Water | w/b | Binders | Aggregates | Superplasticizer | |||||
|---|---|---|---|---|---|---|---|---|---|---|
| Cement | GGBS | Fly ash | Silica fume | Blended cement | Coarse aggregates | Fine aggregates | ||||
| A1 | 202 | 0.32 | 330 | 231 | 99 | — | — | 926 | 552 | 5.61 |
| A2 | 144 | — | — | — | — | 467 | 985 | 786 | 5.65 | |
| A3 | 199 | 297 | 198 | 132 | 33 | — | 933 | 533 | 5.81 | |
| A4 | 202 | 231 | 231 | 198 | — | — | 965 | 483 | 5.28 | |
| B1 | 188 | 0.39 | 247.5 | 173.3 | 74.3 | — | — | 939 | 733 | 3.96 |
| B2 | 159 | — | — | — | — | 420 | 947 | 837 | 5.29 | |
| B3 | 185 | 222.8 | 148.5 | 99 | 24.8 | — | 943 | 730 | 4.16 | |
| B4 | 184 | 175 | 175 | 150 | — | — | 938 | 702 | 4.25 | |

Figure 3
Test setup of rapid chloride migration test.

Figure 4
Device of the heat box.

Figure 5
Test setup of SEM.
Table 5
Results of flow performances.
| Mix no. | w/b | Water demand (kg/m3) | Superplasticizer dosage (kg/m3) | Slump flow (cm) |
|---|---|---|---|---|
| A1 | 0.32 | 202 | 5.61 | 56 × 58 |
| A2 | 144 | 5.65 | 59 × 61 | |
| A3 | 199 | 5.81 | 52 × 50 | |
| A4 | 202 | 5.28 | 65 × 68 | |
| B1 | 0.39 | 188 | 3.96 | 61 × 62 |
| B2 | 159 | 5.29 | 65 × 61 | |
| B3 | 185 | 4.16 | 56 × 57 | |
| B4 | 184 | 4.25 | 66 × 66 |

Figure 6
Slump flow for different groups.

Figure 7
Water demand for different groups.

Figure 8
Compressive strength for Group A.

Figure 9
Compressive strength for Group B.

Figure 10
Compressive strength of silica fume for different proportions.

Figure 11
Comparison of compressive strength of blended cement.

Figure 12
Diffusion coefficients for Group A.

Figure 13
Diffusion coefficients for Group B.

Figure 14
Relationship between diffusion coefficient and compressive strength of the proportion of the binders.

Figure 15
Relationship between the amount of silica fume on the diffusion coefficient and compressive strength.

Figure 16
Relationship between the diffusion coefficient and compressive strength of blended cement.
Table 6
Results of hydration heat (unit: kJ/kg).
| Proportion of binders | 28 days | 56 days |
|---|---|---|
| Cement:GGBS:fly ash = 50:35:15 | 250.0 | 292.5 |
| Cement:GGBS:fly ash = 35:35:30 | 233.6 | 274.2 |
| Blended cement | 188.4 | 210.3 |
| Cement:GGBS:fly ash:silica fume = 45:30:20:5 | 303.6 | 330.8 |

Figure 17
Construction diagram of Danjiang Bridge using blended cement from this study.

Figure 18
SEM images for A series specimens (×3,000). (a) A1 specimen, (b) A2 specimen, (c) A3 specimen, and (d) A4 specimen.
Table 7
Carbon emission calculation parameters (kg/tons).
| Concrete component | Cement | GGBS | Fly ash | Silica fume | Blended cement | Aggregates | Additives |
|---|---|---|---|---|---|---|---|
| Carbon emissions | 850 | 83 | 08 | 14 | 196 | 30.3 | 9.9 |
Table 8
Converted carbon emissions for the eight proportions (kg).
| Mix no. | Cement | GGBS | Fly ash | Silica fume | Blended cement | Aggregates | Additives | Carbon emissions |
|---|---|---|---|---|---|---|---|---|
| A1 | 330 | 231 | 99 | — | — | 1,478 | 5.61 | 345.3 |
| A2 | — | — | — | — | 467 | 1,771 | 5.65 | 145.2 |
| A3 | 297 | 198 | 132 | 33 | — | 1,466 | 5.81 | 314.9 |
| A4 | 231 | 231 | 198 | — | — | 1,448 | 5.28 | 261.0 |
| B1 | 247.5 | 173.3 | 74.3 | — | — | 1,672 | 3.96 | 276.1 |
| B2 | — | — | — | — | 420 | 1,784 | 5.29 | 136.4 |
| B3 | 222.8 | 148.5 | 99 | 24.8 | — | 1,664 | 4.16 | 253.3 |
| B4 | 175 | 175 | 150 | — | — | 1,640 | 4.25 | 214.2 |
Table 9
Prices of the concrete components used in this study (US$/kg).
| Concrete components | Cement | GGBS | Fly ash | Silica fume | Blended cement | Aggregates | Additives |
|---|---|---|---|---|---|---|---|
| Price | 0.09 | 0.06 | 0.03 | 0.50 | 0.07 | 0.02 | 1.00 |
Table 10
Converted raw material costs for the eight proportions (US$).
| Mix no. | w/b | Cement (kg) | GGBS (kg) | Fly ash (kg) | Silica fume (kg) | Blended cement (kg) | Aggregates (kg) | Additives (kg) | Cost (US$) |
|---|---|---|---|---|---|---|---|---|---|
| A1 | 0.32 | 330 | 231 | 99 | 1,478 | 5.61 | 75.60 | ||
| A2 | 467 | 1,771 | 5.65 | 63.37 | |||||
| A3 | 297 | 198 | 132 | 33 | 1,466 | 5.81 | 88.10 | ||
| A4 | 231 | 231 | 198 | 1,448 | 5.28 | 68.70 | |||
| B1 | 0.39 | 247.5 | 173.3 | 74.3 | 1,672 | 3.96 | 64.90 | ||
| B2 | 420 | 1,784 | 5.29 | 60.07 | |||||
| B3 | 222.8 | 148.5 | 99 | 24.8 | 1,664 | 4.16 | 73.37 | ||
| B4 | 175 | 175 | 150 | 1,640 | 4.25 | 60.43 |