Structural and optical properties of Dy3+ doped Sr2SiO4 phosphors

Verma, Durga; Patel, R.P.; Verma, Mohan L.

doi:10.2478/msp-2019-0008

Abstract

Dysprosium doped strontium silicate phosphor namely (Sr₂SiO₄:Dy³⁺) was prepared by low-temperature solution combustion method using urea (CO(NH₂)₂) as a fuel. The material was characterized by powder X-ray diffraction (XRD), FT-IR, SEM and EDX. The average crystallite sizes was calculated by Scherer formula. Thermoluminescence study was carried out for the phosphor which showed single glow curve. The kinetic parameter were calculated by using Chen’s glow curve method. Photoluminescence spectra revealed strong transition at 473 nm (blue), 571 nm (yellow) and weak transition at 645 nm (red). These peaks were assigned to transition ⁴F_9/2 →⁶H_15/2, _{13/2, 11/2}. CIE graph of Sr₂SiO₄:Dy³⁺ phosphor is suitable for the generation of white light emission.

References

[1] Feldmann C., Justel T., Ronda C.R., Schmidt P.J., Adv.Funct. Mater., 13 (2003), 511.10.1002/adfm.200301005
Search in Google Scholar Back to article
[2] Devaraju M.K., Yin S., Sato T., Nanotechnology, 20 (2009), 305302.10.1088/0957-4484/20/30/305302
Open DOI Search in Google Scholar Back to article
[3] Won J.K., Sung J.K., Lee K.S., Samoc M., Cartwright A.N., Prasad P.N., Nano Lett., 8 (2008), 3262.10.1021/nl8016219
Search in Google Scholar Back to article
[4] Singh A., Gunning R.D., Ahmed S., Barrett C.A., English N.J., Garatea J.A., Ryan K.M., J. Mater. Chem., 22 (2012), 1562.10.1039/C1JM14382D
Search in Google Scholar Back to article
[5] Pei L.Z., Pei Y.Q., Xie Y.K., Yuan C.Z., Li D.K., Zhang Q.F., Cryst Eng Comm, 14 (2012), 4262.10.1039/c2ce25063b
Open DOI Search in Google Scholar Back to article
[6] Siriwong P., Thongtem T., Phuruangrat A., Thongtem S., Cryst Eng Comm, 13 (2011), 1564.10.1039/C0CE00402B
Search in Google Scholar Back to article
[7] Huang S., Xu J., Zhang Z., Zhang X., Wang L., Gai S., He F., Niu N., Zhang M., Yang P., J. Mater. Chem., 22 (2012), 16136.10.1039/c2jm32412a
Open DOI Search in Google Scholar Back to article
[8] Hao E.C., Bailey R.C., Schatz G.C., Hupp J.T., Li S.Y., Nano Lett., 4 (2004), 327.10.1021/nl0351542
Search in Google Scholar Back to article
[9] Justel T., Nikol H., Ronda C., Angew. Chem. Int. Edit., 37 (1998), 3085.10.1002/(SICI)1521-3773(19981204)37:22<;3084::AID-ANIE3084>3.0.CO;2-W
Search in Google Scholar Back to article
[10] Feldmann C., Jüstel T., Ronda C.R., Schmidt P.J., Adv. Funct. Mater., 13 (2003), 511.10.1002/adfm.200301005
Search in Google Scholar Back to article
[11] Briche S., Zambon D., Boyer D., Chadeyron G., Mahiouet R., Opt. Mater., 28(2006), 615.10.1016/j.optmat.2005.09.029
Open DOI Search in Google Scholar Back to article
[12] Yu L., Li D., Yue M., Yao J., Lu S., Chem. Phys., 326 (2006), 478.10.1016/j.chemphys.2006.03.008
Search in Google Scholar Back to article
[13] Chen T.M., Chen S.C., Yu C.J., J. Solid State Chem., 144 (1999), 437.10.1006/jssc.1999.8202
Search in Google Scholar Back to article
[14] Jung K.Y., Lee H.W., Kang Y.C., Park S.B., Yang Y.S., Chem. Mater., 17 (2005), 2729.10.1021/cm050074f
Open DOI Search in Google Scholar Back to article
[15] Sreekanth C.R.P., Nagabhushana B.M., Chandrappa G.T., Ramesh K.P., Rao J.L., Mater. Chem. Phys., 95 (2006), 169.10.1016/j.matchemphys.2005.06.002
Search in Google Scholar Back to article
[16] Matsuzawa T., Aoki Y., Takeuchi N., Murayama Y., J. Electrochem. Soc., 143 (1996), 2670.10.1149/1.1837067
Search in Google Scholar Back to article
[17] Sun X.Y., Zhang J.H., Zhang X., Lu S.Z., Wang X.J., J. Lumin., 122 (2007), 955.10.1016/j.jlumin.2006.01.336
Search in Google Scholar Back to article
[18] Baginskiy I., Lui R.S., Wang C.L., Lin R.T., Yao Y.J., J. Electrochem. Soc., 158 (2011), 118.10.1149/1.3625282
Search in Google Scholar Back to article
[19] Catti M., Gazzoni G., Ivaldi G., Zanini G., Acta Crystallogr. B, 39 (1983), 674.10.1107/S0108768183003213
Search in Google Scholar Back to article
[20] Catti M., Gazzoni G., Ivaldi G., Acta Crystallogr. C, 39 (1983), 29.10.1107/S0108767383000057
Search in Google Scholar Back to article
[21] Hyde B.G., Sellar J.R., Stenberg L., Acta Crystallogr. B, 42 (1986), 423.10.1107/S0108768186097938
Open DOI Search in Google Scholar Back to article
[22] Stenberg L., Hyde B.G., Acta Crystallogr. B, 42 (1986), 417.10.1107/S010876818609794X
Open DOI Search in Google Scholar Back to article
[23] Dutczak D., Milbrat A., Katelnikovas A., Meijerink A., Ronda C., Justel T., J. Lumin., 132 (2012), 2398.10.1016/j.jlumin.2012.03.055
Search in Google Scholar Back to article
[24] Haranath D., Chander H., Sharma P., Singh S., Appl. Phys. Lett., 89 (2006), 173118.10.1063/1.2367657
Search in Google Scholar Back to article
[25] Su Q., Liang H., Li C., He H., Lu Y., Li J., Tao Y., J. Lumin., 122 (2007), 927.10.1016/j.jlumin.2006.01.329
Search in Google Scholar Back to article
[26] Gou Z., Chang J., Zhai W., J. Eur. Ceram. Soc., 25 (2005), 1507.10.1016/j.jeurceramsoc.2004.05.029
Search in Google Scholar Back to article
[27] Chandrasekhar M., Sunitha D.V., Dhananjaya N., Nagabhushana H., Sharma S.C., Nagabhushana B.M., Shivakumara C., Chakradhar R.P.S., J. Lumin., 132 (2012), 1798.10.1016/j.jlumin.2012.02.017
Search in Google Scholar Back to article
[28] Umesh B., Eraiah B., Nagabhushana H., Sharma S.C., Sunitha D.V., Nagabhushana B.M., Shivakumara C., Rao J.L., Chakradhar R.P.S., Spectrochim. Acta A, 93 (2012), 228.10.1016/j.saa.2012.02.08222484256
Search in Google Scholar Back to article
[29] Chen R., J. Electrochem. Soc., 116 (1969), 1254.10.1149/1.2412291
Search in Google Scholar Back to article
[30] Yuan Z.X., Chang C.K., Mao D.L., Ying W.J., J. Alloy. Compd., 377(1) (2004), 268.10.1016/j.jallcom.2004.01.063
Search in Google Scholar Back to article
[31] Sahu I.P., Bisen D.P., Brahme N., Displays, 35 (2014), 279.10.1016/j.displa.2014.09.006
Open DOI Search in Google Scholar Back to article
[32] Tamrakar R.K., Bisen D.P., Sahu I.P., Brahme N., J. Radiat. Res., 7 (2014), 417.10.1016/j.jrras.2014.07.003
Search in Google Scholar Back to article
[33] Furetta C., Handbook of Thermoluminescence, World Scientific Press, Singapore, 2003.10.1142/5167
Search in Google Scholar Back to article
[34] Chen R., McKeever S.W.S., Theory of Thermoluminescence and Related Phenomenon, World Scientific Press, Singapore, 1997.10.1142/2781
Search in Google Scholar Back to article
[35] McKeever S.W.S., Thermoluminescence of Solids, Cambridge University Press, Cambridge, 1985.10.1017/CBO9780511564994
Search in Google Scholar Back to article
[36] Van Uitert L.G., J. Electronchem. Soc., 114 (1967), 1048.10.1149/1.2424184
Search in Google Scholar Back to article
[37] Ozawa L., Jaffe P.M., J. Electronchem. Soc., 118 (1971), 1678.10.1149/1.2407810
Search in Google Scholar Back to article
[38] Dexter D.L., J. Chem. Phys., 21 (1953), 836.10.1063/1.1699044
Search in Google Scholar Back to article
[39] Mulak J., Mulak M., J. Phys. A-Math. Theor., 40(2007), 2063.10.1088/1751-8113/40/9/012
Open DOI Search in Google Scholar Back to article
[40] Gruber J.B., Zandi B., Valiev U.V., Rakhimov S.A., J. Appl. Phys., 94 (2003), 1030.10.1063/1.1581351
Search in Google Scholar Back to article
[41] Chen Y., Cheng X., Liu M., Qi Z., Shi C., J. Lumin., 129 (2009), 531.10.1016/j.jlumin.2008.12.008
Search in Google Scholar Back to article
[42] Gupta S.K., Kumar M., Natarajan V., Godbole S.V., Opt. Mater., 35 (2013), 2320.10.1016/j.optmat.2013.06.028
Open DOI Search in Google Scholar Back to article
[43] Zukauskas A., Shur M.S, Gaska R., Introduction to Solid State Lighting, Wiley, New York, 2002.
Search in Google Scholar Back to article
[44] CIE, Proceedings of the 8th Session of CIE, Cambridge, England, 1931.
Search in Google Scholar Back to article

Structural and optical properties of Dy3+ doped Sr2SiO4 phosphors

Abstract

Paradigm

My account