Evolution of the dicalcium phosphate-dihydrate (DCPD) coating created by large amplitude sinusoidal voltammetry (LASV) on corrosion resistance of the ZW3 magnesium alloy in chloride containing environment

D. Kajánek; B. Hadzima; F. Pastorek; M. Neslušan Jacková

doi:10.2478/kom-2018-0003

Abstract

The contribution is focused on the preparation of coating based on the dicalcium phosphate-dihydrate (DCPD) on the surface of ZW3 magnesium alloy. For the preparation of the coating a cathodic electrodeposition technique called Large Amplitude Sinusoidal Voltammetry (LASV) was used. The DCPD layer was prepared at the temperature of 22 ± 2 °C in electrolyte composed of 0.1M Ca(NO₃).4H₂O, 0.06 M NH₄H₂PO₄ and H₂O₂. Electrochemical characteristics were evaluated by electrochemical impedance spectroscopy (EIS) in 0.1M NaCl solution. The obtained data in form of Nyquist plots were analysed by the equivalent circuit method. It is clear from the measured values of polarization resistance Rp that dicalcium phosphate-dihydrate (DCPD) layer prepared by LASV electro-deposition technique improved corrosion resistance of ZW3 alloy in the chosen environment.

References

1. Brunelli K. et al. Effect of HCl pre-treatment on corrosion resistence of cerium-based conversion coatings on magnesium and magnesium alloy, Corrosion Science2005, 47, 989-1000.10.1016/j.corsci.2004.06.016
Search in Google Scholar Back to article
2. Cui X. et al. Structure and corrosion resistence of modified mirco-arc oxidation coating on AZ31B magnesium alloy, Transaction of Nonferrous Metals Society of China2016, 26, 814-821.10.1016/S1003-6326(16)64172-9
Search in Google Scholar Back to article
3. Han B. et al. Fabrication of a novel Mg-RE (Nd,Ce) intermetallic compound coating by molten salt diffusion and its effect on corrosion resistance of magnesium alloys, Journal of Rare Earths2016, 34,10.1016/S1002-0721(16)60084-4
Open DOI Search in Google Scholar Back to article
4. Nový F. et al. Very high cycle fatigue behaviour of as-extruded AZ31, AZ80, and ZK60 magnesium alloys, International Journal of Materials and Research2009, 100, 288-291.10.3139/146.110043
Search in Google Scholar Back to article
5. Wang Y. et al. Corrosion behaviors and effects of corrosion products of plasmaelectrolytic oxidation coated AZ31 magnesium alloy under the saltspray corrosion test, Applied Surface Science2016, 378, 435-442.10.1016/j.apsusc.2016.04.011
Search in Google Scholar Back to article
6. Zhao, Y. et al. Formation and electrochemical behavior of Al and O plasma-implanted biodegradable Mg-Y-RE alloy, Materials Chemistry and Physics2012, 132, 187-191.10.1016/j.matchemphys.2011.11.028
Search in Google Scholar Back to article
7. Feng A., Han Y., Mechanical and in vitro degradation behavior of ultrafine calcium polyphosphate reinforced magnesium-alloy composites, Materials and Design2011, 32, 2813-2820.10.1016/j.matdes.2010.12.054
Search in Google Scholar Back to article
8. Gu, Y. et al. Long-term corrosion inhibition mechanism of microarc oxidation coated AZ31 Mg alloys for biomedical applications, Materials and Design2013, 46, 66-75.10.1016/j.matdes.2012.09.056
Search in Google Scholar Back to article
9. Gnedenkov A.S. et al. Features of the corrosion processes development at the magnesium alloys surface, Surface and Coatings Technology2013, 225, 112-118.10.1016/j.surfcoat.2013.03.023
Search in Google Scholar Back to article
10. Nasiri Vatan N., Ebrahimi-kahrizsangi R., Kasiri-asgarani M. Structural, tribological and electrochemical behavior of SiC nanocomposite oxide coatings fabricated by plasma electrolytic oxidation (PEO) on AZ31 magnesium alloy, Journal of Alloys and Compounds2016, 683, 241-255.10.1016/j.jallcom.2016.05.096
Search in Google Scholar Back to article
11. Say W.C., Chen C.C, Hsieh S. Electrochemical characterization of non-chromate surface treatments on AZ80 magnesium, Materials Characterization2008, 59, 1400-1406.10.1016/j.matchar.2007.12.007
Search in Google Scholar Back to article
12. Esmaily, M. et al. Fundamentals and advances in magnesium alloy corrosion, Progress in Materials Science2017, 89, 92-193.10.1016/j.pmatsci.2017.04.011
Search in Google Scholar Back to article
13. Song G.L. Recent progress in corrosion and protection of magnesiu alloys, Advanced Engineering Materials2005, 7, 563-586.10.1002/adem.200500013
Open DOI Search in Google Scholar Back to article
14. Shaw B.A. Corrosion resistance of magnesium alloys, ASM Handbook, Corrosion: Fundamentals, Testing and Protection2003, 13a, 692-696.10.31399/asm.hb.v13a.a0003675
Search in Google Scholar Back to article
15. Nwaogu N.C. et al. Influence of inorganic acid pickling on the corrosion resistance of magnesium alloy AZ31 sheet, Corrosion Science2009, 51, 2544-2556.10.1016/j.corsci.2009.06.045
Search in Google Scholar Back to article
16. Ghali E. Activity and passivity of magnesium and its alloy, Corrosion of magnesium alloys, edited by G.L. Song2011, 1, 66-109.10.1533/9780857091413.1.66
Search in Google Scholar Back to article
17. Turnold R. et al. The corrosion of magnesium in aqueous solution containing chloride ions, Corrosion Science1977, 17, 353-365.10.1016/0010-938X(77)90059-2
Open DOI Search in Google Scholar Back to article
18. Hadzima B. et al. Cathodic anticorrosive protection of magnesium alloy AZ91, Kovové materiály2003, 41, 257-269.
Search in Google Scholar Back to article
19. Gu Ch. et al. Electroless Ni-P plating on AZ91D magnesium alloy from a sulfate solution, Journal of Alloys and Compounds2005, 391, 104-109.10.1016/j.jallcom.2004.07.083
Search in Google Scholar Back to article
20. Mohedano M., Blawert C., Zheludkevich M.L. Silicate-based Plasma Electrolytic Oxidation (PEO) coatings with incorporated CeO₂ particles on AM50 magnesium alloy, Materials and Design2015, 86, 735-744.10.1016/j.matdes.2015.07.132
Search in Google Scholar Back to article
21. Kannan M.B. Electrochemical deposition of calcium phosphates on magnesiumand its alloys for improved bio-degradation performance: A review, Surface and Coatings Technology2016, 301, 36-41.10.1016/j.surfcoat.2015.12.044
Search in Google Scholar Back to article
22. Mhaede M., Pastorek F., Hadzima B. Influence of shot peening on corrosion properties of biocompatible magnesium alloy AZ31 coated by dicalcium phosphate dihydrate (DCPD), Materials Science and Engineering C2014, 39, 330-335.10.1016/j.msec.2014.03.023
Search in Google Scholar Back to article
23. Shandabaz S., Dias G.J. Calcium phosphate coating on magnesium alloys for biomedical aplications: A review, Acta Biomaterialia2012, 8, 20-30.10.1016/j.actbio.2011.10.016
Search in Google Scholar Back to article
24. Wang H. et al. Electrochemical property and in vitro degradation of DCPD–PCL composite coating on the biodegradable Mg–Zn alloy, Materials Letters2012, 68, 435-438-10.1016/j.matlet.2011.11.029
Search in Google Scholar Back to article
25. Xie J., Riley C., Chitur K. FTIR/ATR study of protein adsorption and brushite tranformation to hydroxyapatite, Biomaterials2002, 23, 3609-3616.10.1016/S0142-9612(02)00090-X
Open DOI Search in Google Scholar Back to article
26. Kajánek D. et al. Study of Corrosion Behavior of Dicalcium Phosphate-dihydrate (DCPD) Coating Prepared by Large Amplitude Sinusoidal Voltammetry (LASV) Technique on ZW3 Magnesium Alloy, Proceedia Engineering2017, 192, 399-403.10.1016/j.proeng.2017.06.069
Search in Google Scholar Back to article
27. Dorozhkin S. Calcium orthophosphate coatings on magnesium and its biodegradable alloys, Acta Biomaterialia2014, 10, 2919-2934.10.1016/j.actbio.2014.02.026
Search in Google Scholar Back to article
28. Peng P. et al. Thin calcium phosphate coatings on titanium by electrochemical deposition in modified simulated body fluid, Journal of Biomedical Materials Research Part A2006, 76, 347-355.10.1002/jbm.a.30514
Open DOI Search in Google Scholar Back to article
29. Omasta M. et al. Electrodeposition of calcium phosphate on EV31 magnesium alloy, Advanced Science Letters2016, 22, 651-655.10.1166/asl.2016.6911
Open DOI Search in Google Scholar Back to article
30. Chandrasekar M.S, Pushpavanam M. Electrochim. Pulse and pulse reverse plating-Conceptual, advantages and applications, Electrochemica Acta2008, 53, 3313-3322.10.1016/j.electacta.2007.11.054
Search in Google Scholar Back to article
31. Amirudin A., Thierry D. Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals, Progress in Organic Coatings1995, 26, 1-28.10.1016/0300-9440(95)00581-1
Search in Google Scholar Back to article
32. Pastorek F., Hadzima B. Study of calcium phosphate (DCPD) electrodeposition process on a Mg-3Al_1Zn magnesium alloy surface, Materials Engineering – Materiálové inžinierstvo2013, 20, 54-63.
Search in Google Scholar Back to article

Evolution of the dicalcium phosphate-dihydrate (DCPD) coating created by large amplitude sinusoidal voltammetry (LASV) on corrosion resistance of the ZW3 magnesium alloy in chloride containing environment

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