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Chrome-Free Sheep Leathers with Antimicrobiological Protection for Medical and Therapeutic Applications Cover

Chrome-Free Sheep Leathers with Antimicrobiological Protection for Medical and Therapeutic Applications

Open Access
|Jun 2024

Figures & Tables

Fig. 1.

The evaluation of antibacterial activity of sheep leather samples on the flesh and fleece side
The evaluation of antibacterial activity of sheep leather samples on the flesh and fleece side

Fig. 2.

The evaluation of antifungal activity of sheep leather samples on the flesh and fleece side
The evaluation of antifungal activity of sheep leather samples on the flesh and fleece side

Fig. 3.

The evaluation of antifungal activity of sheep leather samples – assessment of growth in agar medium under the samples
The evaluation of antifungal activity of sheep leather samples – assessment of growth in agar medium under the samples

Fig. 4.

Inhibition demonstration of bacterial growth by sample no. 4
Inhibition demonstration of bacterial growth by sample no. 4

Fig. 5.

Inhibition demonstration of fungal growth by sample no. 4
Inhibition demonstration of fungal growth by sample no. 4

Determination of the antibacterial activity of leather samples against bacteria: S_ aureus, E_ coli and P_ aeruginosa

Sample No.Staphylococcus aureusEscherichia coliPseudomonas aeruginosa
Inhibition zone of growth [mm] W/SGrowth W/SAssessment W/SInhibition zone of growth [mm] W/SGrowth W/SAssessment W/SInhibition zone of growth [mm] W/SGrowth W/SAssessment W/S
10/0heavy/noneinsufficient effect/good effect0/0heavy/noneinsufficient effect/good effect0/0heavy/noneinsufficient effect/good effect
20/0heavy/noneinsufficient effect/good effect0/0heavy/noneinsufficient effect/good effect0/0heavy/noneinsufficient effect/good effect
30/6heavy/noneinsufficient effect/good effect0/7heavy/noneinsufficient effect/good effect0/7,5heavy/noneinsufficient effect/good effect
41,5/5,5none/nonegood effect/good effect1,5/7none/nonegood effect/good effect0/2,5none/nonegood effect/good effect

Determination of antifungal activity of leather samples against fungi: C_ albicans, A_ brasiliensis and T_ mentagrophytes

Sample numberCandida albicansAspergillus brasiliensisTrichophyton mentagrophytes
Inhibition zone of growth [mm] W/SAssessment of growth on samples W/SAssessment of growth in agar medium under the samples W/SInhibition zone of growth [mm] W/SAssessment of growth on samples W/SAssessment of growth in agar medium under the samples W/SInhibition zone of growth [mm] W/SAssessment of growth on samples W/SAssessment of growth in agar medium under the samples W/S
10/01*/15/50/04/35/30/03/34/2
20/01*/15/40/04/24/30/03/24/1
30/01*/05/00/533/04/00/623/04/0
454/650/00/00/290/00/071/590/00/0

Test results of physical and chemical parameters for sheep skins protected with an agent containing a zinc pyrithione formulation_

No.Indicator nameUnit of measureResultTechnical requirements according to ŁIT in KrakowMethod
1.
  • Tear strength

  • - along

  • - across

N
  • 206,4

  • 188,5

≥ 100PN –EN ISO 3376:2012
2.
  • Max. elongation

  • - along

  • - across

%
  • 59,6

  • 58,8

≥ 50
3.
  • Temperature of shrink

  • - along

  • - across

ºC
  • 86

  • 85,5

> 70PN-EN ISO 3380:2015-11
4.
  • Abrasion resistance load 9 kPa

  • - dry

  • - wet

number of cycles
  • 25 600

  • in the middle part of the samples, the fleece was abrasion to a height of about 10 mm, full fleece was observed at the periphery of the samples;

  • 12 800

  • fulling of wool hair

  • ≥ 25 600 without skin damage

  • ≥ 12 800 without skin damage

PN-EN ISO 20344:2012 p.6.12
5.
  • pH / number of differences

  • - wool

  • - skin

-
  • 3,5

  • 4,3

  • 3,5–7,0

  • For pH < 4,00 number of differences ≤0,7

PN-EN ISO 4045:2018-09
6.Water vapour permeabilitymg/(cm2 h)11,43≥ 4
  • PN-EN ISO 14268:2013-03 (water vapor permeability for leather)

  • PN-EN ISO 17229:2016-05 (water vapor absorption)

Water vapour absorptionmg/cm27,74not normalized
7.Water vapour coefficientmg/cm299,2min. 33
8.
  • Seam tearing force

  • - along

  • - across

N
  • 111,7

  • 113,5

≥ 70PN-EN ISO 23910
9.Formaldehydemg/kg(58,1 ±0,8)≤ 75,0PN-EN ISO 17226-2:2019-05
10.Chrome(VI)mg/kgundetectable 1/undetectablePN-EN ISO 5398-2:2010
DOI: https://doi.org/10.2478/ftee-2024-0021 | Journal eISSN: 2300-7354 | Journal ISSN: 1230-3666
Language: English
Page range: 1 - 9
Published on: Jun 27, 2024
Published by: Łukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres
In partnership with: Paradigm Publishing Services
Publication frequency: Volume open

© 2024 Michalina Falkiewicz-Dulik, published by Łukasiewicz Research Network, Institute of Biopolymers and Chemical Fibres
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.