The Synthesis of 2,2-BIS(1-INDOL-3-YL)Acenaphthylene-1(2)-Ones Using Nanocatalysis: Fluorescent Sensing for Cu2+ Ions

Mohammadi Ziarani, Ghodsi; Khademi, Mahdieh; Mohajer, Fatemeh; Badiei, Alireza; Varma, Rajender S.

doi:10.2478/eces-2022-0033

Abstract

2,2-bis(1H-indol-3-yl)acenaphthylene-1(2H)-ones were synthesised by the reaction of acenaphthenequinone and 2 equivalents of indole using Fe₃O₄@SiO₂@Si-Pr-NH-CH₂CH₂NH₂ as the basic magnetic nanocatalyst, assembled under greener and sustainable conditions in high purity and yields. Furthermore, the photoluminescence properties of 2,2-bis(2-methyl-1H-indol-3-yl)acenaphthylene-1(2H)-one were exploited for the sensing of copper ions in the mixed solvent systems comprising H₂O and CH₃CN in excitation wavelength at 410 nm with a detection limit of 9.5 ∙ 10_–6 M.

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The Synthesis of 2,2-BIS(1-INDOL-3-YL)Acenaphthylene-1(2)-Ones Using Nanocatalysis: Fluorescent Sensing for Cu2+ Ions

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