List of global manufactures of PHA
| Company | Headquarters | Product | Composition |
|---|---|---|---|
| Biomatera | Toronto, Canada | Biomatera | Not specified PHA |
| Biomer | Schwalbach, Germany | Biomer | P3HB |
| Bio-on | Bologna, Italy | MINERV-PHA | Not specified PHA |
| DaniMer Scientific | Bainbridge, Georgia, USA | Nodax PHA | Not specified PHA, e.g. P3H-B-co-3HHx |
| Kaneka Corporation | Tokyo, Japan | Kaneka PHBHTM | P3HB-co-3HHx |
| Mango Materials | Redwood City, USA California, | YOPP PHA | Not specified PHA |
| Nafigate | Prague, Czech Republic | Hydal | P3HB |
| NaturePlast | Arago, France | PHA | Not specified PHA |
| Newlight Technologies | Irvine, CA, USA | AirCarbonTM | Not specified PHA |
| RWDC Industries | Singapore, Singapore | Solon | Not specified PHA |
| Shenzhen Ecomann nology Biotech- | Shandong, China | AmBio | Not specified PHA |
| SIRIM | Selangor, Malaysia | PHA | Not specified PHA |
| TAIF Group | Tatarstan, Russian Federation | PHA | Not specified PHA |
| TEPHA | Massachusetts, USA | Tephaflex, TephElas | Not specified PHA |
| TianAn Biological Materials | Zhejiang, China | ENMAT | P3HB and P3HBV |
| Tianjin Green-Bio | Taijin, China | Sogreen | Not specified PHA, e.g. P3H-B-co-4HB |
Additive manufacturing technologies used for processing of polymers
| 3D printing technology | Principle | Polymer | Physical form |
|---|---|---|---|
| Stereolithography (SL) | Photopolymerization (radiation curing reaction of polymer in successive layers) | Liquid photosensitive polymer | Liquid |
| Selective laser sintering (SLS) | Steered powder bed fusion by CO2 laser beam (deposition of layer by layer sequence meshes, sintering and solidification) | Thermoplastics | Powder |
| Fused deposition modeling (FDM) | Extrusion of the molten filament (gradual deposition of layers and solidification) | Thermoplastics | Filament |
| 3D Bioprinting | Extrusion of the molten (or dissolved) polymer and deposition of layers through syringes or cartridges and consequent solidification | Biomaterials with required viscosity and flowability | Granules, paste or gel materials |
| Material jetting (MJ) | The charged droplets are steered released by the nozzle on the substrate (solidification depends on the type of polymer compound, e.g., under UV light) | Various polymer solutions with the required viscosity (photopolymer or thermoplastics) | Ink |
Thermal and mechanical properties of the selected commercial PHAs (10, 11, 12, 13), n – data were unlisted by the company
| Polymer | Trade name | Company | Melt temperature (°C) | Tensile strength (MPa) | Elongation at break (%) | Modulus (MPa) |
|---|---|---|---|---|---|---|
| P3HB | Biomer P226 | Biomer, Germany | 180 | 25.5 | n | 1520 |
| P3HBV | Enmat Y1000P | TianAn Biological Materials, China | 170 - 176 | 39 | 2 | 2800 - 3500 |
| P3HB-co-3HHx | PHBH X 151 A | Kaneka Corporation, Japan | 126 | 26 | 320 | 950 |
| P3HB-co-4HB | Sogreen | Tianjin Green-Bio, China | 110 | 14 | 775 | n |