Study of Adhesion at the Polymer-Silicate Composite Interface Under the Infulence of Physico-Mechanical Factors

Plastun, Nestor; Gandel, Radoslav; Jerabek, Jan; Sucharda, Oldrich

doi:10.2478/cee-2025-0091

Abstract

This paper investigates the potential of additive manufacturing for the production of polymer-based reinforcing elements designed to improve the structural properties and durability of silicate composites. The research addresses the interaction between polymer reinforcements and silicate composites, with a particular focus on the synergy at the material interface under physico-mechanical and environmental stresses. The aim is to increase both mechanical strength and resistance to degradation caused by water and chemical de-icing agents. Concrete composites reinforced with different 3D printed polymeric elements were experimentally tested for flexural and compressive strength as well as long-term durability. The results showed that optimized reinforcement geometry and material selection can lead to a significant improvement in composite properties. The high-performance concrete combined with appropriately designed polymer elements showed the greatest increase in compressive strength, while the conventional concrete benefited mainly in terms of flexural properties. In addition, some polymer reinforcements contributed to the maintenance of adhesive bonds even after prolonged exposure to aggressive environments. These findings confirm the viability of using additive manufacturing to create functional reinforcements tailored for cement-based materials, offering a new and adaptable approach to designing composites.

References

SINGH, H., AMBEKAR, R. S., DAS, D., DANAM, V. A., KATIYAR, N. K., KANTI DAS, B., TIWARY, C. S., & BHATTACHARYA, J. (2024). Enhancing structural resilience by using 3D printed complex polymer reinforcement for high damage tolerant structures. Construction and Building Materials, 425, 136085. https://doi.org/10.1016/j.conbuildmat.2024.136085.
Search in Google Scholar Back to article
HARRIS, M., RAZA, A., POTGIETER, J., IMDAD, A., RIMAŠAUSKIENĖ, R., & ARIF, K. M. (2023). 3D printed biodegradable polymer reinforced concrete with high structural stability. Structures, 51, 1609–1621. https://doi.org/10.1016/j.istruc.2023.03.156.
Search in Google Scholar Back to article
SALAZAR, B., AGHDASI, P., WILLIAMS, I. D., OSTERTAG, C. P., & TAYLOR, H. K. (2020). Polymer lattice-reinforcement for enhancing ductility of concrete. Materials & Design, 196, 109184. https://doi.org/10.1016/j.matdes.2020.109184.
Search in Google Scholar Back to article
SUCHARDA, O., MARCALIKOVA, Z., & GANDEL, R. (2022). Microstructure, Shrinkage, and Mechanical Properties of Concrete with Fibers and Experiments of Reinforced Concrete Beams without Shear Reinforcement. Materials, 15 (16), 5707. https://doi.org/10.3390/ma15165707.
Search in Google Scholar Back to article
SUCHARDA, O., KONECNY, P., KUBOSEK, J., PONIKIEWSKI, T., & DONE, P. (2015). Finite Element Modelling and Identification of the Material Properties of Fibre Concrete. Procedia Engineering, 109, 234–239, https://doi.org/10.1016/j.proeng.2015.06.222.
Search in Google Scholar Back to article
MATECKOVA, P., BILEK, V., & SUCHARDA, O. (2021). Comparative Study of High-Performance Concrete Characteristics and Loading Test of Pretensioned Experimental Beams. Crystals, 11, (4), 427). https://doi.org/10.3390/cryst11040427.
Search in Google Scholar Back to article
GANDEL, R., JERABEK, J., & MARCALIKOVA, Z. (2023). Reinforced Concrete Beams Without Shear Reinforcement Using Fiber Reinforced Concrete and Alkali-Activated Material. Civil and Environmental Engineering, 19 (1), 348–356. https://doi.org/10.2478/cee-2023-0031.
Search in Google Scholar Back to article
MARCALIKOVA, Z., JERABEK, J., GANDEL, R., GABOR, R., BILEK, V., & SUCHARDA, O. (2024). Mechanical Properties, Workability, and Experiments of Reinforced Composite Beams with Alternative Binder and Aggregate. Buildings, 14(7), 2142. https://doi.org/10.3390/buildings14072142.
Search in Google Scholar Back to article
PEKNIKOVA, A., JERABEK, J., GANDEL, R., GABOR, R., BILEK, V., & SUCHARDA, O. (2025). Physical–Mechanical Behavior of High-Performance Concrete and Ordinary Concrete with Portland Cement Mixtures After Exposure to Selected Durability Tests Including High Thermal Stress. Buildings, 15 (7), 1029, https://doi.org/10.3390/buildings15071029.
Search in Google Scholar Back to article
SCHNEIDER, M., ROMER, M., TSCHUDIN, M., & BOLIO, H. (2011). Sustainable cement production—present and future. Cement and Concrete Research, 41 (7), 642–650. https://doi.org/10.1016/j.cemconres.2011.03.019.
Search in Google Scholar Back to article
HUNTZINGER, D. N., & EATMON, T. D. (2009). A life-cycle assessment of Portland cement manufacturing: comparing the traditional process with alternative technologies. Journal of Cleaner Production, 17 (7), 668–675. https://doi.org/10.1016/j.jclepro.2008.04.007.
Search in Google Scholar Back to article
TURNER, L. K., & COLLINS, F. G. (2013). Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete. Construction and Building Materials, 43, 125–130. https://doi.org/10.1016/j.conbuildmat.2013.01.023.
Search in Google Scholar Back to article
JUENGER, M. C. G., WINNEFELD, F., PROVIS, J. L., & IDEKER, J. H. (2011). Advances in alternative cementitious binders. Cement and Concrete Research, 41 (12), 1232–1243. https://doi.org/10.1016/j.cemconres.2010.11.012.
Search in Google Scholar Back to article
PROVIS, J. L. (2018). Alkali-activated materials. Cement and Concrete Research, 114, 40–48. https://doi.org/10.1016/j.cemconres.2017.02.009.
Search in Google Scholar Back to article
SHI, C., JIMÉNEZ, A. F., & PALOMO, A. (2011). New cements for the 21st century: The pursuit of an alternative to Portland cement. Cement and Concrete Research, 41 (7), 750–763. https://doi.org/10.1016/j.cemconres.2011.03.016.
Search in Google Scholar Back to article
KOPIIKA, N., BLIKHARSKYY, Y., SELEJDAK, J., KHMIL, R., & BLIKHARSKYY, Z. (2025). Reliability-based analysis and residual life forecasting for corrosion-affected RC structures. Structures, 76, 108965. https://doi.org/10.1016/j.istruc.2025.108965
Search in Google Scholar Back to article
KRAMARCHUK, A., ILNYTSKYY, B., & KOPIIKA, N. (2023). Ensuring the load-bearing capacity of monolithic reinforced concrete slab damaged by cracks in the compressed zone. In Z. Blikharskyy (Ed.), Proceedings of EcoComfort 2022 (Lecture Notes in Civil Engineering, Vol. 290, pp. 185–192). Springer. https://doi.org/10.1007/978-3-031-14141-6_21
Search in Google Scholar Back to article
KOPIIKA, N., ROBERY, P., NINIC, J., & MITOULIS, S.-A. (2025). Remaining life of ageing RC infrastructure for sustainable development—Deterioration under climate change. Case Studies in Construction Materials, 22, e04757. https://doi.org/10.1016/j.cscm.2025.e04757
Search in Google Scholar Back to article
ISMAEEL, A. M., et al. (2024). Creating sustainable ultra-high-performance concrete (UHPC) utilizing recycled glass. Civil and Environmental Engineering, 20(2), 1152–1161. https://doi.org/10.2478/cee-2024-0084
Search in Google Scholar Back to article
ABD, W. F., et al. (2025). Investigation the mechanical and physical characteristics of sustainable refractory concrete. Civil and Environmental Engineering, 0(0). https://doi.org/10.2478/cee-2025-0004
Search in Google Scholar Back to article
HOANG, D. P., et al. (2025). Effect of short polypropylene fibre content on the mechanical properties of textile-reinforced engineered concrete composite. Civil and Environmental Engineering, 0(0). https://doi.org/10.2478/cee-2025-0039
Search in Google Scholar Back to article
MAHDI, F., ABBAS, H., & KHAN, A. A. (2010). Strength characteristics of polymer mortar and concrete using different compositions of resins derived from post-consumer PET bottles. Construction and Building Materials, 24 (1), 25–36. https://doi.org/10.1016/j.conbuildmat.2009.08.006.
Search in Google Scholar Back to article
MAHDI, F., ABBAS, H., & KHAN, A. A. (2013). Flexural, shear and bond strength of polymer concrete utilizing recycled resin obtained from post consumer PET bottles. Construction and Building Materials, 44, 798–811. https://doi.org/10.1016/j.conbuildmat.2013.03.081.
Search in Google Scholar Back to article
KIM, J., JEONG, D., SON, C., LEE, Y., KIM, E., & MOON, I. (2007). Synthesis and applications of unsaturated polyester resins based on PET waste. Korean Journal of Chemical Engineering, 24 (6), 1076–1083. https://doi.org/10.1007/s11814-007-0124-5.
Search in Google Scholar Back to article
BARKHAD, M. S., ABU-JDAYIL, B., IQBAL, M. Z., & MOURAD, A.-H. I. (2020). Thermal insulation using biodegradable poly(lactic acid)/date pit composites. Construction and Building Materials, 261, 120533). https://doi.org/10.1016/j.conbuildmat.2020.120533.
Search in Google Scholar Back to article
NGUYEN-VAN, V., LIU, J., PENG, C., ZHANG, G., NGUYEN-XUAN, H., & TRAN, P. (2022). Dynamic responses of bioinspired plastic-reinforced cementitious beams. Cement and Concrete Composites, 133, 104682. https://doi.org/10.1016/j.cemconcomp.2022.104682.
Search in Google Scholar Back to article
CHIADIGHIKAOBI, P. C., HASANZADEH, A., HEMATIBAHAR, M., KHARUN, M., MOUSAVI, M. S., STASHEVSKAYA, N. A., & ADEGOKE, M. A. (2024). Evaluation of the mechanical behavior of high-performance concrete (HPC) reinforced with 3D-Printed trusses. Results in Engineering, 22, 102058). https://doi.org/10.1016/j.rineng.2024.102058.
Search in Google Scholar Back to article
RODRÍGUEZ, C. R., DE MENDONÇA FILHO, F. F., MERCURI, L., GAN, Y., ROSSI, E., ANGLANI, G., ANTONACI, P., SCHLANGEN, E., & ŠAVIJA, B. (2020). Chemo-physico-mechanical properties of the interface zone between bacterial PLA self-healing capsules and cement paste. Cement and Concrete Research, 138, 106228. https://doi.org/10.1016/j.cemconres.2020.106228.
Search in Google Scholar Back to article
ŠAVIJA, B., FEITEIRA, J., ARAÚJO, M., CHATRABHUTI, S., RAQUEZ, J.-M., VAN TITTELBOOM, K., GRUYAERT, E., DE BELIE, N., & SCHLANGEN, E. (2016). Simulation-Aided Design of Tubular Polymeric Capsules for Self-Healing Concrete. Materials, 10 (1), 10). https://doi.org/10.3390/ma10010010.
Search in Google Scholar Back to article
PALOS, A., D’SOUZA, N. A., SNIVELY, C. T., & REIDY, R. F., III. (2001). Modification of cement mortar with recycled ABS. Cement and Concrete Research, 31 (7), 1003–1007. https://doi.org/10.1016/s0008-8846(01)00531-2.
Search in Google Scholar Back to article
SUCHARDA, O., GANDEL, R., CMIEL, P., JERABEK, J., & BILEK, V. (2024). Utilization of High-Performance Concrete Mixtures for Advanced Manufacturing Technologies. Buildings 14 (8), 2269. https://doi.org/10.3390/buildings14082269.
Search in Google Scholar Back to article
LE, T. T., AUSTIN, S. A., LIM, S., BUSWELL, R. A., GIBB, A. G. F., & THORPE, T. (2012). Mix design and fresh properties for high-performance printing concrete. In Materials and Structures, 45 (8), 1221–1232. https://doi.org/10.1617/s11527-012-9828-z.
Search in Google Scholar Back to article
LE, T. T., AUSTIN, S. A., LIM, S., BUSWELL, R. A., LAW, R., GIBB, A. G. F., & THORPE, T. (2012). Hardened properties of high-performance printing concrete. Cement and Concrete Research, 42 (3), 558–566. https://doi.org/10.1016/j.cemconres.2011.12.003.
Search in Google Scholar Back to article
DEL VISO, J. R., CARMONA, J. R., & RUIZ, G. (2008). Shape and size effects on the compressive strength of high-strength concrete. Cement and Concrete Research, 38 (3), 386–395. https://doi.org/10.1016/j.cemconres.2007.09.020.
Search in Google Scholar Back to article
SIM, J.-I., YANG, K.-H., KIM, H.-Y., & CHOI, B.-J. (2013). Size and shape effects on compressive strength of lightweight concrete. Construction and Building Materials 38, 854–864. https://doi.org/10.1016/j.conbuildmat.2012.09.073.
Search in Google Scholar Back to article
VU, C.-C., WEISS, J., PLÉ, O., & AMITRANO, D. (2021). The potential impact of size effects on compressive strength for the estimation of the Young’s modulus of concrete. Materials and Structures, 54 (5). https://doi.org/10.1617/s11527-021-01795-7.
Search in Google Scholar Back to article
QASIM, O. A. (2018). A Review Paper on Specimens Size and Shape Effects on the Concrete Properties. In International Journal of Recent Advances in Science and Technology (Vol. 5, Issue 3). IJPBR. https://doi.org/10.30750/ijarst.533.
Search in Google Scholar Back to article
TALAAT, A., EMAD, A., TAREK, A., MASBOUBA, M., ESSAM, A., & KOHAIL, M. (2021). Factors affecting the results of concrete compression testing: A review. Ain Shams Engineering Journal 12 (1), 205–221. https://doi.org/10.1016/j.asej.2020.07.015.
Search in Google Scholar Back to article
PATIL, A. Y., BANAPURMATH, N. R., E. P., S., CHITAWADAGI, M. V., KHAN, T. M. Y., BADRUDDIN, I. A., & KAMANGAR, S. (2020). Multi-Scale Study on Mechanical Property and Strength of New Green Sand (Poly Lactic Acid) as Replacement of Fine Aggregate in Concrete Mix. Symmetry 12 (11), 1823. https://doi.org/10.3390/sym12111823.
Search in Google Scholar Back to article
MORENO NIETO, D., ALONSO-GARCÍA, M., PARDO-VICENTE, M.-A., & RODRÍGUEZPARADA, L. (2021). Product Design by Additive Manufacturing for Water Environments: Study of Degradation and Absorption Behavior of PLA and PETG. Polymers, 13 (7), 1036. https://doi.org/10.3390/polym13071036.
Search in Google Scholar Back to article
PLASTUN, N (2024). Adhesion of concrete composite with polymer elements from additive 3D printing technology, Diploma thesis. Ostrava: VSB – Technical University of Ostrava
Search in Google Scholar Back to article
Experimental dataset. https://doi.org/10.5281/zenodo.14982019.
Search in Google Scholar Back to article

Study of Adhesion at the Polymer-Silicate Composite Interface Under the Infulence of Physico-Mechanical Factors

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