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Modeling of transport properties of binary mixtures including ionic liquids based on their experimental estimation Cover

Modeling of transport properties of binary mixtures including ionic liquids based on their experimental estimation

Open Access
|Dec 2022

Abstract

Transport properties of selected imidazolium ionic liquids (1-ethyl-3-methylimidazolium acetate, [emim][ac], and 1-butyl-3-methylimidazolium trifluoromethanesulfonate, [bmim][triflate]) as well as of binary mixtures of these ILs with water and ethanol were estimated experimentally. Density data were obtained within the temperature range of 293.15—333.15 K and used for the excess molar volume calculations. For the binary mixtures comprising selected ionic liquids and water/ethanol, partial molar volumes of mixture components were computed and the excess molar volume variation with the mixture composition was correlated using the Redlich-Kister equation. Dependence of viscosity on the binary mixture composition and temperature was described using the Jouyban-Acree model. These data form a base for the assessment of OPEX connected with transportation of mixtures containing these ionic liquids.

DOI: https://doi.org/10.2478/acs-2022-0014 | Journal eISSN: 1339-3065 | Journal ISSN: 1337-978X
Language: English
Page range: 123 - 130
Published on: Dec 8, 2022
Published by: Slovak University of Technology in Bratislava
In partnership with: Paradigm Publishing Services
Publication frequency: 2 issues per year
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© 2022 Pavol Steltenpohl, Anna Holečková, Elena Graczová, published by Slovak University of Technology in Bratislava
This work is licensed under the Creative Commons Attribution 4.0 License.