On the structure of [Al(DMSO2)3]3+

Martin Breza

doi:10.2478/acs-2014-0002

Abstract

The most stable [Al(DMSO₂)₃]³⁺ complex cation in dimethyl sulfone (DMSO₂, (CH₃)₂SO₂) has D₃ symmetry with twofold axes in Al-S lines coincident with the twofold rotation axes of mutually turned DMSO₂ ligands by ca 60°. The central Al atom is hexacoordinated by six O atoms with nearly octahedral coordination. More than one electron is transferred to the Al central atom from DMSO₂ ligands. Weaker and longer S-O, stronger and shorter S-C bonds, lower O-S-O bond angles and greater O-S-C and C-S-C ones in [Al(DMSO₂)₃]³⁺ than in free DMSO₂ are implied by weak Al-O bonding.

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On the structure of [Al(DMSO2)3]3+

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