Figure 1.

Water quality indicators evaluated for each tested liquid phase of washings
| Parameter | Raw washings | Supernant water | Filtrate |
|---|---|---|---|
| pH [-] | 9.15-9.58 | 8.94-9.58 | 9.05-9.25 |
| Conductivity [mS/cm] | 4.259-5.400 | 4.377-4.816 | 4.278-5.766 |
| Potential redox [mV] | 747-751 | 771-780 | 776-781 |
| Absorbance UV254 [cm-1] | 1.826-2.760 | 1.028-1.160 | 0.885-1.132 |
| Turbidity [NTU] | 138-852 | 17.0-21.6 | 0.12-1.09 |
| Content of suspensions [mg/L] | 308-750 | 45-53 | <25 |
| TOC [mg/L] | 66.28-70.65 | 56.33-59.38 | 57.32-61.2 |
| TC [mg/L] | 72.7-73.39 | 61.14-62.64 | 63.98-64.31 |
| IC [mg/L] | 2.05-7.11 | 1.76-6.31 | 2.78-6.99 |
The toxicity effect of filter backwash water on the various indicator organisms
| Type of swimming pool from that the sample of filter backwash water was collected | Tested organism | Toxic effect [%] | References |
|---|---|---|---|
| School swimming pool | Aliivibrio fischeri | 63 | [6] |
| Daphnia magna | 40 | ||
| Chaoborus falvicans | 87 | ||
| Sports swimming pool | Aliivibrio fischeri | 98 | [7] |
| Hot tube | Aliivibrio fischeri | 70 | |
| Sports swimming pool | Aliivibrio fischeri | 100 | [8] |
| Jacuzzi | Lemna minor | 31 | [9] |
The presence of micropollutants in individual liquid phases and their potential toxicity
| Group | Compound | Raw sample | Filtrate | Supernatant water | Potential toxicity |
|---|---|---|---|---|---|
| Products Care Personal | Octanal | + | + | - | N |
| Benzyl alcohol | + | + | + | Y | |
| Pentanedinitrile | + | + | + | Y | |
| Nonanal | + | + | - | Y | |
| Cyclohexasiloxane, dodecamethyl- | + | - | - | N | |
| Cetyl alcohol | + | - | - | Y | |
| Hexa-hydro-farnesol | + | - | - | Y | |
| Oleic Acid | + | - | + | N | |
| Diethyl Phthalate | + | + | + | Y | |
| Benzophenone | + | + | + | Y | |
| Isopropyl myristate | + | - | - | Y | |
| 1-Octadecanol | + | + | + | N | |
| Octocrylene | + | - | - | Y | |
| Debrisoquine | + | - | + | Y | |
| Benzyl cyanide | + | + | - | Y | |
| Cimetidine | + | + | - | Y | |
| Undecylenic acid | + | + | - | Y | |
| Gitoxigenin | + | - | - | Y | |
| Disinfection By-Products | 2-Chlorohistidine | + | - | - | Y |
| Decyl chloride | + | + | + | Y | |
| 1-Tetradecanol, 14-chloro- | + | - | - | Y | |
| 2,2,2-TriB-N,N-dimethylacetamide | + | + | - | Y | |
| Industry additives | 1-Eicosanol | + | - | - | Y |
| Bis(2-ethylhexyl) phthalate | + | + | + | Y | |
| Kodaflex DOTP | + | + | + | Y | |
| Heptadecane | + | - | - | Y | |
| Hexadecanethiol | + | - | - | Y | |
| Dibutyl phthalate | + | + | + | Y | |
| Glycidyl oleate | + | + | + | Y | |
| Glycidyl phenyl ether | + | + | + | Y | |
| Nonanenitrile | + | + | + | Y | |
| Food additives | Decanal | + | + | + | N |
| Methyl caprate | + | - | - | Y | |
| Triacetin | + | + | + | N | |
| Methyl dodecanoate | + | + | + | Y | |
| Hedione | + | + | + | N | |
| Methyl tetradecanoate | + | + | + | N | |
| Tetradecanoic acid | + | + | - | Y | |
| Isopropyl palmitate | + | + | + | N | |
| Care Cleaning Products | Dodecanenitrile | + | - | - | Y |
| Palmitoleic acid | + | - | - | Y | |
| Methyl palmitate | + | + | + | N | |
| Dioctyl adipate | + | - | - | Y | |
| Tridecanoic acid | + | + | + | Y |
Chronic toxicity of selected organic micropollutants in the water environment and their acute toxicity determined for aquatic organisms
| Compound | The trophic group of tested organisms | Species of tested organism | Parameter (duration of the test) | The value [mg/L] | References |
|---|---|---|---|---|---|
| Ibuprofen | Vascular plants | Lemna minor | LOEC | 22.00 | [27] |
| Crustaceans | Gammarus pulex | LOEC | 0.00001 | [28] | |
| Planorbis carnatus | LOEC | 24.30 | [29] | ||
| Thamnocephalus platyurus | LC50 (24 h) | 19.59 | [30] | ||
| Hydra attenuata | LC50 (96 h) | 1.65 | [31] | ||
| Algae | Desmodesmus subspicatus | EC50 (72h) | 315 | [32] | |
| Synechocystis sp. | LOEC (72h) | 1.00 | [33] | ||
| Molluscs | Planorbis carnatus | LC50 (72 h) | 17.10 | [29] | |
| Amphibians | Xnopus laevis | EC50 | 30.70 | [34] | |
| Fishes | Oncorhynchus mykiss | LOEC | 1.00 | [35] | |
| Oryzias latipes | LC50 (96 h) | >100.00 | [36] | ||
| Caffeine | Rotifera | Plationus patulus | LC50 (48 h) | 580.00 | [37] |
| Crustaceans | Pimephales promelas | LC50 (24 h) | 100.00 | [38] | |
| Fishes | Chironomus dilutus | LC50 (24 h) | 1.23 | [38] | |
| Pimephales promelas | LOEC | 20.00 | [38] | ||
| Carbamazepine | Vascular plants | Lemna minor | LOEC | 22.50 | [27] |
| Lemna gibba | LOEC | >1.00 | [39] | ||
| Crustaceans | Ceriodaphnia dubia | LOEC | 100.00 | [40] | |
| Calluna vulgaris | EC50 (48 h) | 155.00 | [36] | ||
| Ceriodaphnia dubia | EC50 (48 h) | 77.70 | [40] | ||
| Hydra attenuata | EC50 | 15.50 | [31] | ||
| Algae | Desmodesmus subspicatus | EC50 (72 h) | 74.00 | [27] | |
| Cyclotella meneghiniana | EC50 (96 h) | 10.00 | [40] | ||
| Synechococcus leopolensis | EC50 (96 h) | 17.00 | [40] | ||
| Insects | Chironomus tentans | LOEC | 47.30 | [41] | |
| Amphibians | Xnopus laevis | EC50 (96 h) | >100.00 | [34] | |
| Fishes | Oryzias latipes | LOEC | 6.10 | [36] | |
| EC50 (48 h) | 35.40 | [30] | |||
| Danio rerio | LOEC | 50.00 | [39] | ||
| Oncorhynchus mykiss (juvenile) | LC50 (96 h) | 19.90 | [42] | ||
| Oxybenzone | Crustaceans | Daphnia magna | EC50 (24 h) | 1.67 | [43] |
| Algae | Scenedesmus vacuolatus | IC50 (24 h) | 0.36 | [44] | |
| Desmodesmus subspicatus | IC50 (72 h) | 0.61 | [43] | ||
| Fishes | Oncorhynchus mykiss | LOEC | 0.75 | [45] | |
| Oryzias latipes | LOEC | 0.62 | [45] |