
Evaluation of Data Processing Strategies for Methane Isotopic Signatures Determined During Near-Source Measurements
References
- Akritas, M.G. and Bershady, M.A. (1993) Linear regression for astronomical data with measurement errors and intrinsic scatter. Astrophys. J., 420(2): 706–714. DOI: 10.1086/177901
- Al-Shalan, A., Lowry, D., Fisher, R.E., Nisbet, E.G., Zazzeri, G., Al-Sarawi, M. and France, J.L. (2022) Methane emissions in Kuwait: Plume identification, isotopic characterisation and inventory verification. Atmos. Environ., 268:
118763 . DOI: 10.1016/j.atmosenv.2021.118763 - Assan, S., Baudic, A., Guemri, A., Ciais, P., Gros, V. and Vogel, F.R. (2017) Characterization of interferences to in situ observations of d13CH4 and C2H6 when using a cavity ring-down spectrometer at industrial sites. Atmospheric Meas. Tech., 10: 2077–2091. DOI: 10.5194/amt-10-2077-2017
- Bakkaloglu, S., Lowry, D., Fisher, R.E., France, J.L. and Nisbet, E.G. (2021) Carbon isotopic characterisation and oxidation of UK landfill methane emissions by atmospheric measurements. Waste Manag., 132: 162–175. DOI: 10.1016/j.wasman.2021.07.012
- Bakkaloglu, S., Lowry, D., Fisher, R.E., Menoud, M., Lanoisellé, M., Chen, H., Röckmann, T. and Nisbet, E.G. (2022) Stable isotopic signatures of methane from waste sources through atmospheric measurements. Atmos. Environ., 276:
119021 . DOI: 10.1016/j.atmosenv.2022.119021 - Basu, S., Lan, X., Dlugokencky, E., Michel, S., Schwietzke, S., Miller, J.B., Bruhwiler, L., Oh, Y., Tans, P.P., Apadula, F., Gatti, L.V., Jordan, A., Necki, J., Sasakawa, M., Morimoto, S., Di Iorio, T., Lee, H., Arduini, J. and Manca, G. (2022) Estimating emissions of methane consistent with atmospheric measurements of methane and δ13C of methane. Atmospheric Chem. Phys., 22: 15351–15377. DOI: 10.5194/acp-22-15351-2022
- Brownlow, R., Lowry, D., Fisher, R.E., France, J.L., Lanoisellé, M., White, B., Wooster, M.J., Zhang, T. and Nisbet, E.G. (2017) Isotopic ratios of tropical methane emissions by atmospheric measurement: Tropical methane δ13C source signatures. Glob. Biogeochem. Cycles, 31: 1408–1419. DOI: 10.1002/2017GB005689
- Chanton, J.P., Rutkowski, C.M., Schwartz, C.C., Ward, D.E. and Boring, L. (2000) Factors influencing the stable carbon isotopic signature of methane from combustion and biomass burning. J. Geophys. Res. Atmospheres, 105: 1867–1877. DOI: 10.1029/1999JD900909
- Craig, H. (1957) Isotopic standards for carbon and oxygen and correctiofna ctors for mass-spectrometric analysis of carbon dioxide. Geochim. Cosmochim. Acta., 12: 133–149. DOI: 10.1016/0016-7037(57)90024-8
- Defratyka, S. (2021)
Characterizing methane (CH4) emissions in urban environments (Paris) . Paris-Saclay, Gif sur Yvette. - Defratyka, S. (2023) Dataset: Statistical evaluation of methane isotopic signatures determined during near-source measurements. Mendeley Data, V1. DOI: 10.17632/vfbbdvp9w2.1
- Defratyka, S.M., Paris, J.-D., Yver-Kwok, C., Fernandez, J.M., Korben, P. and Bousquet, P. (2021) Mapping urban methane sources in Paris, France. Environ. Sci. Technol., 55: 8583–8591. DOI: 10.1021/acs.est.1c00859
- Dlugokencky, E.J. (2022) NOAA/ESRL. Available at
https://gml.noaa.gov/ccgg/trends_ch4/ [Last accessed 03 February 2025]. - Fernandez, J.M., Maazallahi, H., France, J.L., Menoud, M., Corbu, M., Ardelean, M., Calcan, A., Townsend-Small, A., van der Veen, C., Fisher, R.E., Lowry, D., Nisbet, E.G. and Röckmann, T. (2022) Street-level methane emissions of Bucharest, Romania and the dominance of urban wastewater. Atmospheric Environ. X, 13:
100153 . DOI: 10.1016/j.aeaoa.2022.100153 - Fisher, R., Lowry, D., Wilkin, O., Sriskantharajah, S. and Nisbet, E.G. (2006) High-precision, automated stable isotope analysis of atmospheric methane and carbon dioxide using continuous-flow isotope-ratio mass spectrometry. Rapid Commun. Mass Spectrom., 20: 200–208. DOI: 10.1002/rcm.2300
- France, J.L., Cain, M., Fisher, R.E., Lowry, D., Allen, G., O’Shea, S.J., Illingworth, S., Pyle, J., Warwick, N., Jones, B.T., Gallagher, M.W., Bower, K., Le Breton, M., Percival, C., Muller, J., Welpott, A., Bauguitte, S., George, C., Hayman, G.D., Manning, A.J., Myhre, C.L., Lanoisellé, M. and Nisbet, E.G. (2016) Measurements of δ13C in CH4 and using particle dispersion modeling to characterize sources of Arctic methane within an air mass. J. Geophys. Res. Atmospheres, 121,14,257–14,270. DOI: 10.1002/2016JD026006
- Gardiner, T., Helmore, J., Innocenti, F. and Robinson, R. (2017) Field validation of remote sensing methane emission measurements. Remote Sens., 9:
956 . DOI: 10.3390/rs9090956 - Germain-Piaulenne, E., Paris, J.-D., Gros, V., Quehe, P.-Y., Pikridas, M., Baisnee, D., Berchet, A., Sciare, J. and Bourtsoukidis, E. (2024) Middle East oil and gas methane emissions signature captured at a remote site using light hydrocarbon tracers. Atmos. Environ. 22:
100253 . DOI: 10.1016/j.aeaoa.2024.100253 - Hogg, D.W., Bovy, J. and Lang, D. (2010) Data analysis recipes: Fitting a model to data. ArXiv10084686 Astro-Ph Physicsphysics. [Last accessed 03 February 2025].
- Hoheisel, A., Yeman, C., Dinger, F., Eckhardt, H. and Schmidt, M. (2019) An improved method for mobile characterisation of D13CH4 source signatures and its application in Germany. Atmospheric Meas. Tech., 12: 1123–1139. DOI: 10.5194/amt-12-1123-2019
- Karion, A., Sweeney, C., Tans, P. and Newberger, T. (2010) AirCore: An innovative atmospheric sampling system. J. Atmospheric Ocean. Technol., 27(11): 1839–1853. DOI: 10.1175/2010JTECHA1448.1
- Keeling, C.D. (1961) The concentration and isotopic abundances of carbon dioxide in rural and marine air. Geochim. Cosmochim. Acta, 24: 277–298. DOI: 10.1016/0016-7037(61)90023-0
- Lan, X., Basu, S., Schwietzke, S., Bruhwiler, L.M.P., Dlugokencky, E.J., Michel, S.E., Sherwood, O.A., Tans, P.P., Thoning, K., Etiope, G., Zhuang, Q., Liu, L., Oh, Y., Miller, J.B., Pétron, G., Vaughn, B.H. and Crippa, M. (2021) Improved constraints on global methane emissions and sinks using δ13C-CH4. Glob. Biogeochem. Cycles, 35,
e2021GB007000 . DOI: 10.1029/2021GB007000 - Legendre, P. and Legendre, L. (1998) Numerical ecology, second English ed. Amsterdam: Elsevier Science B.V.
- Lopez, M., Sherwood, O.A., Dlugokencky, E.J., Kessler, R., Giroux, L. and Worthy, D.E.J. (2017) Isotopic signatures of anthropogenic CH4 sources in Alberta, Canada. Atmos. Environ., 164: 280–288. DOI: 10.1016/j.atmosenv.2017.06.021
- Lowry, D., Fisher, R.E., France, J.L., Coleman, M., Lanoisellé, M., Zazzeri, G., Nisbet, E.G., Shaw, J.T., Allen, G., Pitt, J. and Ward, R.S. (2020) Environmental baseline monitoring for shale gas development in the UK: Identification and geochemical characterisation of local source emissions of methane to atmosphere. Sci. Total Environ., 708:
134600 . DOI: 10.1016/j.scitotenv.2019.134600 - Maazallahi, H., Fernandez, J.M., Menoud, M., Zavala-Araiza, D., Weller, Z.D., Schwietzke, S., von Fischer, J.C., Denier van der Gon, H. and Röckmann, T. (2020) Methane mapping, emission quantification, and attribution in two European cities: Utrecht (NL) and Hamburg (DE). Atmospheric Chem. Phys., 20: 14717–14740. DOI: 10.5194/acp-20-14717-2020
- Menoud, M., Morales, R.P., Pison, I., Bousquet, P. and Röckmann, T. (2020) Characterisation of methane sources in Lutjewad, The Netherlands, using quasi-continuous isotopic composition measurements. Tellus B, 72(1): 1–20. DOI: 10.1080/16000889.2020.1823733
- Menoud, M., van der Veen, C., Lowry, D., Fernandez, J.M., Bakkaloglu, S., France, J.L., Fisher, R.E., Maazallahi, H., Stanisavljević, M., Nęcki, J., Vinkovic, K., Łakomiec, P., Rinne, J., Korbeń, P., Schmidt, M., Defratyka, S., Yver-Kwok, C., Andersen, T., Chen, H. and Röckmann, T. (2022) New contributions of measurements in Europe to the global inventory of the stable isotopic composition of methane. Earth Syst. Sci. Data, 14: 4365–4386. DOI: 10.5194/essd-14-4365-2022
- Menoud, M., van der Veen, C., Necki, J., Bartyzel, J., Szénási, B., Stanisavljević, M., Pison, I., Bousquet, P. and Röckmann, T. (2021) Methane (CH4) sources in Krakow, Poland: insights from isotope analysis. Atmospheric Chem. Phys., 21: 13167–13185. DOI: 10.5194/acp-21-13167-2021
- Miller, J.B. and Tans, P.P. (2003) Calculating isotopic fractionation from atmospheric measurements at various scales. Tellus B Chem. Phys. Meteorol., 55(2): 207–214. DOI: 10.3402/tellusb.v55i2.16697
- Pataki, D.E., Ehleringer, J.R., Flanagan, L.B., Yakir, D., Bowling, D.R., Still, C.J., Buchmann, N., Kaplan, J.O. and Berry, J.A. (2003) The application and interpretation of Keeling plots in terrestrial carbon cycle research: APPLICATION OF KEELING PLOTS. Glob. Biogeochem. Cycles, 17(1):
1022 . DOI: 10.1029/2001GB001850 - Phillips, N.G., Ackley, R., Crosson, E.R., Down, A., Hutyra, L.R., Brondfield, M., Karr, J.D., Zhao, K. and Jackson, R.B. (2013) Mapping urban pipeline leaks: Methane leaks across Boston. Environ. Pollut., 173: 1–4. DOI: 10.1016/j.envpol.2012.11.003
- Rella, C.W., Hoffnagle, J., He, Y. and Tajima, S. (2015) Local- and regional-scale measurements of CH4, d13CH4, and C2H6; in the Uintah Basin using a mobile stable isotope analyzer. Atmospheric Meas. Tech., 8: 4539–4559. DOI: 10.5194/amt-8-4539-2015
- Rennick, C., Arnold, T., Safi, E., Drinkwater, A., Dylag, C., Webber, E.M., Hill-Pearce, R., Worton, D.R., Bausi, F. and Lowry, D. (2021) Boreas: A sample preparation-coupled laser spectrometer system for simultaneous high-precision in situ analysis of δ13C and δ2H from ambient air methane. Anal. Chem., 93: 10141–10151. DOI: 10.1021/acs.analchem.1c01103
- Rigby, M., Manning, A.J. and Prinn, R.G. (2012) The value of high-frequency, high-precision methane isotopologue measurements for source and sink estimation: METHANE ISOTOPOLOGUES IN INVERSIONS. J. Geophys. Res. Atmospheres, 117:
D12312 . DOI: 10.1029/2011JD017384 - Röckmann, T., Eyer, S., van der Veen, C., Popa, M.E., Tuzson, B., Monteil, G., Houweling, S., Harris, E., Brunner, D., Fischer, H., Zazzeri, G., Lowry, D., Nisbet, E.G., Brand, W.A., Necki, J.M., Emmenegger, L. and Mohn, J. (2016) In situ observations of the isotopic composition of methane at the Cabauwtall tower site. Atmospheric Chem. Phys., 16: 10469–10487. DOI: 10.5194/acp-16-10469-2016
- Saunois, M., Stavert, A.R., Poulter, B., Bousquet, P., Canadell, J.G., Jackson, R.B., Raymond, P.A., Dlugokencky, E.J., Houweling, S., Patra, P.K., Ciais, P., Arora, V.K., Bastviken, D., Bergamaschi, P., Blake, D.R., Brailsford, G., Bruhwiler, L., Carlson, K.M., Carrol, M., Castaldi, S., Chandra, N., Crevoisier, C., Crill, P.M., Covey, K., Curry, C.L., Etiope, G., Frankenberg, C., Gedney, N., Hegglin, M.I., Höglund-Isaksson, L., Hugelius, G., Ishizawa, M., Ito, A., Janssens-Maenhout, G., Jensen, K.M., Joos, F., Kleinen, T., Krummel, P.B., Langenfelds, R.L., Laruelle, G.G., Liu, L., Machida, T., Maksyutov, S., McDonald, K.C., McNorton, J., Miller, P.A., Melton, J.R., Morino, I., Müller, J., Murguia-Flores, F., Naik, V., Niwa, Y., Noce, S., O’Doherty, S., Parker, R.J., Peng, C., Peng, S., Peters, G.P., Prigent, C., Prinn, R., Ramonet, M., Regnier, P., Riley, W.J., Rosentreter, J.A., Segers, A., Simpson, I.J., Shi, H., Smith, S.J., Steele, L.P., Thornton, B.F., Tian, H., Tohjima, Y., Tubiello, F.N., Tsuruta, A., Viovy, N., Voulgarakis, A., Weber, T.S., van Weele, M., van der Werf, G.R., Weiss, R.F., Worthy, D., Wunch, D., Yin, Y., Yoshida, Y., Zhang, W., Zhang, Z., Zhao, Y., Zheng, B., Zhu, Qing, Zhu, Qiuan and Zhuang, Q. (2020) The global methane budget 2000–2017. Earth Syst. Sci. Data, 12: 1561–1623. DOI: 10.5194/essd-12-1561-2020
- Schwietzke, S., Sherwood, O.A., Bruhwiler, L.M.P., Miller, J.B., Etiope, G., Dlugokencky, E.J., Michel, S.E., Arling, V.A., Vaughn, B.H., White, J.W.C. and Tans, P.P. (2016) Upward revision of global fossil fuel methane emissions based on isotope database. Nature, 538: 88–91. DOI: 10.1038/nature19797
- Sherwood, O.A., Schwietzke, S., Arling, V.A. and Etiope, G. (2017) Global inventory of gas geochemistry data from fossil fuel, microbial and burning sources, version 2017. Earth Syst. Sci. Data, 9: 639–656. DOI: 10.5194/essd-9-639-2017
- Simpson, I.J., Sulbaek Andersen, M.P., Meinardi, S., Bruhwiler, L., Blake, N.J., Helmig, D., Rowland, F.S. and Blake, D.R. (2012) Long-term decline of global atmospheric ethane concentrations and implications for methane. Nature, 488: 490–494. DOI: 10.1038/nature11342
- Townsend-Small, A., Ferrara, T.W., Lyon, D.R., Fries, A.E. and Lamb, B.K. (2016) Emissions of coalbed and natural gas methane from abandoned oil and gas wells in the United States. Geophys. Res. Lett., 43: 2283–2290. DOI: 10.1002/2015GL067623
- Townsend-Small, A., Tyler, S.C., Pataki, D.E., Xu, X. and Christensen, L.E. (2012) Isotopic measurements of atmospheric methane in Los Angeles, California, USA: Influence of “fugitive” fossil fuel emissions: Los Angeles methane emissions. J. Geophys. Res. Atmospheres, 117:
D07308 . DOI: 10.1029/2011JD016826 - Turner, A.J., Frankenberg, C. and Kort, E.A. (2019). Interpreting contemporary trends in atmospheric methane. Proc. Natl. Acad. Sci., 116: 2805–2813. DOI: 10.1073/pnas.1814297116
- Varga, T., Fisher, R.E., France, J.L., Haszpra, L., Jull, A.J.T., Lowry, D., Major, I., Molnár, M., Nisbet, E.G. and László, E. (2021) Identification of potential methane source regions in Europe using δ13C-CH4 measurements and trajectory modeling. J. Geophys. Res. Atmospheres, 126:
e2020JD033963 . DOI: 10.1029/2020JD033963 - Wehr, R. and Saleska, S.R. (2017) The long-solved problem of the best-fit straight line: application to isotopic mixing lines. Biogeosciences, 14: 17–29. DOI: 10.5194/bg-14-17-2017
- Whiticar, M.J. (1999) Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane. Chem. Geol., 161: 291–314. DOI: 10.1016/S0009-2541(99)00092-3
- York, D. (1966) Least-squares fitting of a straight line. Can. J. Phys., 44(5): 1079–1086. DOI: 10.1139/p66-090
- York, D., Evensen, N.M., Martínez, M.L. and De Basabe Delgado, J. (2004) Unified equations for the slope, intercept, and standard errors of the best straight line. Am. J. Phys., 72(3): 367–375. DOI: 10.1119/1.1632486
- Zazzeri, G., Lowry, D., Fisher, R.E., France, J.L., Lanoisellé, M. and Nisbet, E.G. (2015) Plume mapping and isotopic characterisation of anthropogenic methane sources. Atmos. Environ., 110: 151–162. DOI: 10.1016/j.atmosenv.2015.03.029
- Zobitz, J.M., Keener, J.P., Schnyder, H. and Bowling, D.R. (2006) Sensitivity analysis and quantification of uncertainty for isotopic mixing relationships in carbon cycle research. Agric. For. Meteorol., 136: 56–75. DOI: 10.1016/j.agrformet.2006.01.003
DOI: https://doi.org/10.16993/tellusb.1878 | Journal eISSN: 1600-0889
Language: English
Page range: 1 - 17
Submitted on: Jul 24, 2024
Accepted on: Jan 16, 2025
Published on: Feb 6, 2025
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services
Keywords:
© 2025 Sara M. Defratyka, James L. France, Rebecca E. Fisher, Dave Lowry, Julianne M. Fernandez, Semra Bakkaloglu, Camille Yver-Kwok, Jean-Daniel Paris, Philippe Bousquet, Tim Arnold, Chris Rennick, Jon Helmore, Nigel Yarrow, Euan G. Nisbet, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.