Skip to main content
Have a personal or library account? Click to login
Gamma radiolytic stability of CyMe4BTBP and the effect of nitric acid Cover

Gamma radiolytic stability of CyMe4BTBP and the effect of nitric acid

Nukleonika
Volume 60 (2015): Issue 4 (December 2015)
By: ,  ,  ,  ,   and    
Open Access
|Dec 2015
References

References

  1. 1. OECD-NEA. (2011). Potential benefi ts and impacts of advanced nuclear fuel cycles with actinide partitioning and transmutation. Issy-les-Moulineaux, France: O. Publishing OECD-NEA. (NEA no. 6894).
    Search in Google Scholar
  2. 2. González-Romero, E. M. (2011). Impact of partitioning and transmutation on the high level waste management. Nucl. Eng. Des., 241, 3436-3444. DOI: 10.1016/j.nucengdes.2011.03.030.
    Open DOISearch in Google Scholar
  3. 3. Modolo, G., Geist, A., & Miguirditchian, M. (2015). Minor actinide separations in the reprocessing of spent nuclear fuels: recent advances in Europe. In R. Taylor (Ed.), Reprocessing and recycling of spent nuclear fuel (pp. 245-287). Oxford: Woodhead Publishing.
    Search in Google Scholar
  4. 4. Baron, P., Hérès, X., Lecomte, M., & Masson, M. (2001). Separation of the minor actinides: the DIAMEX-SANEX concept. In Proceedings of the International Conference on Future Nuclear Systems, GLOBAL’01, 9-13 September 2001. Paris, France.
    Search in Google Scholar
  5. 5. Courson, O., Lebrun, M., Malmbeck, R., Pagliosa, G., Romer, K., Satmark, B., & Glatz, J. P. (2000). Partitioning of minor actinides from HLLW using the DIAMEX process. Part 1 - Demonstration of extraction performances and hydraulic behaviour of the solvent in a continuous process. Radiochim. Acta, 88, 857-863. DOI: 10.1524/ract.2000.88.12.857.
    Open DOISearch in Google Scholar
  6. 6. Malmbeck, R., Courson, O., Pagliosa, G., Romer, K., Satmark, B., Glatz, J. P., & Baron, P. (2000). Partitioning of minor actinides from HLLW using the DIAMEX process. Part 2 - “Hot” continuous counter-current experiment. Radiochim. Acta, 88, 865-871. DOI: 10.1524/ract.2000.88.12.865.
    Open DOISearch in Google Scholar
  7. 7. Geist, A., Hill, C., Modolo, G., Foreman, M. R. S. J., Weigl, M., Gompper, K., Hudson, M. J., & Madic, C. (2006). 6,6ʹ-Bis(5,5,8,8-tetramethyl-5,6,7,8- tetrahydro-benzo[1,2,4]triazin-3-yl)[2,2ʹ]bipyridine, an effective extracting agent for the separation of americium(III) and curium(III) from the lanthanides. Solvent Extr. Ion Exch., 24, 463-483. DOI: 10.1080/07366290600761936.
    Open DOISearch in Google Scholar
  8. 8. Foreman, M. R. S., Hudson, M. J., Drew, M. G. B., Hill, C., & Madic, C. (2006). Complexes formed between the quadridentate, heterocyclic molecules 6,6ʹ-bis-(5,6-dialkyl-1,2,4-triazin-3-yl)-2,2ʹ-bipyridine (BTBP) and lanthanides(III): implications for the partitioning of actinides(III) and lanthanides(III). Dalton Trans., 13, 1645-1653. DOI: 10.1039/B511321k.
    Open DOISearch in Google Scholar
  9. 9. Magnusson, D., Christiansen, B., Foreman, M. R. S., Geist, A., Glatz, J. P., Malmbeck, R., Modolo, G., Serrano-Purroy, D., & Sorel, C. (2009). Demonstration of a SANEX process in centrifugal contactors using the CyMe4-BTBP molecule on a genuine fuel solution. Solvent Extr. Ion Exch., 27, 97-106. DOI: 10.1080/07366290802672204.
    Open DOISearch in Google Scholar
  10. 10. Wilden, A., Schreinemachers, C., Sypula, M., & Modolo, G. (2011). Direct selective extraction of actinides (III) from PUREX raffi nate using a mixture of CyMe4BTBP and TODGA as 1-cycle SANEX solvent. Solvent Extr. Ion Exch., 29, 190-212. DOI: 10.1080/07366299.2011.539122.
    Open DOISearch in Google Scholar
  11. 11. Magnusson, D., Geist, A., Wilden, A., & Modolo, G. (2013). Direct selective extraction of actinides (III) from PUREX raffi nate using a mixture of CyMe4-BTBP and TODGA as 1-cycle SANEX solvent. Part II: Flowsheet design for a counter-current centrifugal contactor demonstration process. Solvent Extr. Ion Exch., 31, 1-11. DOI: 10.1080/07366299.2012.700596.
    Open DOISearch in Google Scholar
  12. 12. Wilden, A., Modolo, G., Schreinemachers, C., Sadowski, F., Lange, S., Sypula, M., Magnusson, D., Geist, A., Lewis, F. W., Harwood, L. M., & Hudson, M. J. (2013). Direct selective extraction of actinides (III) from PUREX raffi nate using a mixture of CyMe4BTBP and TODGA as 1-cycle SANEX solvent. Part III: Demonstration of a laboratory-scale counter-current centrifugal contactor process. Solvent Extr. Ion Exch., 31, 519-537. DOI: 10.1080/07366299.2013.775890.
    Open DOISearch in Google Scholar
  13. 13. Mincher, B. J. (2010). An overview of selected radiation chemical reactions affecting fuel cycle solvent extraction. ACS Symp. Ser., 1046, 181-192. DOI: 10.1021/bk-2010-1046.ch015.
    Open DOISearch in Google Scholar
  14. 14. Hill, C., Berthon, L., & Madic, C. (2005). Study of the stability of BTP extractants under radiolysis. In Proceedings of the GLOBAL 2005, 9-13 October (p. 283). Tsukuba, Japan.
    Search in Google Scholar
  15. 15. Retegan, T., Ekberg, C., Englund, S., Fermvik, A., Foreman, M. R. S., & Skarnemark, G. (2007). The behaviour of organic solvents containing C5-BTBP and CyMe4-BTBP at low irradiation doses. Radiochim. Acta, 95, 637-642. DOI: 10.1524/ ract.2007.95.11.637.
    Open DOISearch in Google Scholar
  16. 16. Fermvik, A., Berthon, L., Ekberg, C., Englund, S., Retegan, T., & Zorz, N. (2009). Radiolysis of solvents containing C5-BTBP: identifi cation of degradation products and their dependence on absorbed dose and dose rate. Dalton Trans., 32, 6421-6430. DOI: 10.1039/b907084b.
    Open DOISearch in Google Scholar
  17. 17. Fermvik, A., Ekberg, C., Englund, S., Foreman, M. R. S. J., Modolo, G., Retegan, T., & Skarnemark, G. (2009). Infl uence of dose rate on the radiolytic stability of a BTBP solvent for actinide(III)/lanthanide(III) separation. Radiochim. Acta, 97, 319-324. DOI: 10.1524/ract.2009.1615.
    Open DOISearch in Google Scholar
  18. 18. Magnusson, D., Christiansen, B., Malmbeck, R., & Glatz, J. P. (2009). Investigation of the radiolytic stability of a CyMe4-BTBP based SANEX solvent. Radiochim. Acta, 97, 497-502. DOI: 10.1524/ ract.2009.1647.
    Open DOISearch in Google Scholar
  19. 19. Fermvik, A., Aneheim, E., Grüner, B., Hájková, Z., Kvicalová, M., & Ekberg, C. (2012). Radiolysis of C5-BTBP in cyclohexanone irradiated in the absence and presence of an aqueous phase. Radiochim. Acta, 100, 273-282. DOI: 10.1524/ract.2012.1908.
    Open DOISearch in Google Scholar
  20. 20. Mincher, B. J., Modolo, G., & Mezyk, S. P. (2010). Review: The effects of radiation chemistry on solvent extraction 4: Separation of the trivalent actinides and considerations for radiation-resistant solvent systems. Solvent Extr. Ion Exch., 28, 415-436. DOI: 10.1080/07366299.2010.485548.
    Open DOISearch in Google Scholar
  21. 21. Sulich, A., Grodkowski, J., Mirkowski, J., & Kocia, R. (2014). Reactions of ligands from BT(B)P family with solvated electrons and benzophenone ketyl radicals in 1-octanol solutions. Pulse radiolysis study. J. Radioanal. Nucl. Chem., 300, 415-421. DOI: 10.1007/ s10967-014-3021-5.
    Open DOISearch in Google Scholar
  22. 22. Mincher, B. J., & Mezyk, S. P. (2009). Radiation chemical effects on radiochemistry: A review of examples important to nuclear power. Radiochim. Acta, 97, 519-534. DOI: 10.1524/ract.2009.1646.
    Open DOISearch in Google Scholar
  23. 23. Mincher, B. J., Modolo, G., & Mezyk, S. P. (2009). The effects of radiation chemistry on solvent extraction: 1. Conditions in acidic solution and a review of TBP radiolysis. Solvent Extr. Ion Exch., 27, 1-25. DOI: 10.1080/07366290802544767.
    Open DOISearch in Google Scholar
  24. 24. Mincher, B. J. (2015). Radiation chemistry in the reprocessing and recycling of spent nuclear fuels. In R. Taylor (Ed.), Reprocessing and recycling of spent nuclear fuel (pp. 191-211). Oxford: Woodhead Publishing.
    Search in Google Scholar
  25. 25. Nilsson, M., Andersson, S., Ekberg, C., Foreman, M. R. S., Hudson, M. J., & Skarnemark, G. (2006). Inhibiting radiolysis of BTP molecules by addition of nitrobenzene. Radiochim. Acta, 94, 103-106. DOI: 10.1524/ract.2006.94.2.103.
    Open DOISearch in Google Scholar
  26. 26. Mincher, B. J., Arbon, R. E., Knighton, W. B., & Meikrantz, D. H. (1994). Gamma-ray-induced degradation of PCBs in neutral isopropanol using spent reactor-fuel. Appl. Radiat. Isot., 45, 879-887. DOI: 10.1016/0969-8043(94)90219-4.
    Open DOISearch in Google Scholar
  27. 27. Freeman, G. R. (1970). Radiolysis of alcohols. Actions Chim. Biol. Radiat., 14, 73-134.
    Search in Google Scholar
  28. 28. Mincher, B. J., Mezyk, S. P., Elias, G., Groenewold, G. S., Riddle, C. L., & Olson, L. G. (2013). The radiation chemistry of CMPO: Part 1. Gamma radiolysis. Solvent Extr. Ion Exch., 31, 715-730. DOI: 10.1080/07366299.2013.815491.
    Open DOISearch in Google Scholar
  29. 29. Symons, M. C. R., & Eastland, G. W. (1977). Radiation mechanisms. Part 18. The radiolysis of alcohols: an electron spin resonance study. J. Chem. Res., Suppl., 254-255.
    Search in Google Scholar
  30. 30. Sugo, Y., Sasaki, Y., & Tachimori, S. (2002). Studies on hydrolysis and radiolysis of N,N,Nʹ,Nʺ-tetraoctyl-3-oxapentane-1,5-diamide. Radiochim. Acta, 90, 161-165. DOI: 10.1524/ract.2002.90.3_2002.161.
    Open DOISearch in Google Scholar
  31. 31. Sugo, Y., Izumi, Y., Yoshida, Y., Nishijima, S., Sasaki, Y., Kimura, T., Sekine, T., & Kudo, H. (2007). Influence of diluent on radiolysis of amides in organic solution. Radiat. Phys. Chem., 76, 794-800. DOI: 10.1016/j.radphyschem.2006.05.008.
    Open DOISearch in Google Scholar
  32. 32. Steppert, M., Cisarova, I., Fanghanel, T., Geist, A., Lindqvist-Reis, P., Panak, P., Stepnicka, P., Trumm, S., & Walther, C. (2012). Complexation of europium(III) by bis(dialkyltriazinyl)bipyridines in 1-octanol. Inorg. Chem., 51, 591-600. DOI: 10.1021/ic202119x.
    Open DOISearch in Google Scholar
  33. 33. Mezyk, S. P., Cullen, T. D., Elias, G., & Mincher, B. J. (2010). Aqueous nitric acid radiation effects on solvent extraction process chemistry. ACS Symp. Ser., 1046, 193-203. DOI: 10.1021/bk-2010-1046.ch016.
    Open DOISearch in Google Scholar
  34. 34. Mincher, B. J. (2012). Degradation issues in aqueous reprocessing systems. Compr. Nucl. Mater., 5, 367-388. DOI: 10.1016/b978-0-08-056033-5.00104-x.
    Open DOISearch in Google Scholar
  35. 35. Mincher, B. J., Mezyk, S. P., & Martin, L. R. (2008). A pulse radiolysis investigation of the reactions of tributyl phosphate with the radical products of aqueous nitric acid irradiation. J. Phys. Chem. A, 112, 6275-6280. DOI: 10.1021/jp802169v.
    Open DOISearch in Google Scholar
  36. 36. Harwood, L. M., Lewis, F. W., Hudson, M. J., John, J., & Distler, P. (2011). The separation of americium(III) from europium(III) by two new 6,6ʹ-bistriazinyl-2,2ʹ-bipyridines in different diluents. Solvent Extr. Ion Exch., 29, 551-576. DOI: 10.1080/10496475.2011.556989.
    Open DOISearch in Google Scholar
  37. 37. Joshi, R., Pathak, P. N., Manchanda, V. K., Sarkar, S. K., & Mukherjee, T. (2010). Reactions of N,N-dihexyloctanamide with nitrate and dodecane radicals: a pulse radiolysis study. Res. Chem. Intermed., 36, 503-510. DOI: 10.1007/s11164-010-0161-2.
    Open DOISearch in Google Scholar
  38. 38. Neta, P., & Huie, R. E. (1986). Rate constants for reactions of nitrogen oxide (NO3) radicals in aqueous solutions. J. Phys. Chem., 90, 4644-4648. DOI: 10.1021/j100410a035.
    Open DOISearch in Google Scholar
  39. 39. Katsumura, Y. (1998). NO2 • and NO3 • radicals in radiolysis of nitric acid solutions. In Z. B. Alfassi (Ed.), The chemistry of free radicals: N-centered radicals (pp. 393-412). Weinheim: Wiley.
    Search in Google Scholar
  40. 40. Katsumura, Y., Jiang, P. Y., Nagaishi, R., Oishi, T., Ishigure, K., & Yoshida, Y. (1991). Pulse radiolysis study of aqueous nitric acid solutions: formation mechanism, yield, and reactivity of NO3 radical. J. Phys. Chem., 95, 4435-4439. DOI: 10.1021/ j100164a050.
    Open DOISearch in Google Scholar
DOI: https://doi.org/10.1515/nuka-2015-0156 | Journal eISSN: 1508-5791 (formerly 0029-5922) | Journal ISSN: 0029-5922
Journal RSS Feed
Language: English
Page range: 879 - 884
Submitted on: Jun 23, 2015
Accepted on: Sep 15, 2015
Published on: Dec 30, 2015
Published by: Institute of Nuclear Chemistry and Technology
In partnership with: Paradigm Publishing Services
Keywords:
CyMe4BTBP,
gamma radiolysis,
liquid-liquid extraction,
nitric acid,
partitioning,
protective effect
Related subjects:
Chemistry,
Nuclear chemistry

© 2015 Holger Schmidt, Andreas Wilden, Giuseppe Modolo, Jaroslav Švehla, Bohumir Grüner, Christian Ekberg, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Volume 60 (2015): Issue 4 (December 2015)
Previous article
Next article