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Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

Nukleonika
Volume 60 (2015): Issue 4 (December 2015)
By:
Open Access
|Dec 2015

Abstract

Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone-based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.

DOI: https://doi.org/10.1515/nuka-2015-0123 | Journal eISSN: 1508-5791 | Journal ISSN: 0029-5922
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Language: English
Page range: 885 - 891
Submitted on: Aug 16, 2015
Accepted on: Aug 26, 2015
Published on: Dec 30, 2015
Published by: Institute of Nuclear Chemistry and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year
Keywords:
accelerated electrons,
CyMe4-BTPhen,
irradiation,
radiation stability,
solvent extraction
Related subjects:
Chemistry,
Nuclear chemistry,
Physics,
Astronomy and astrophysics,
Physics, other

© 2015 Petr Distler, Jana Kondé, Jan John, Zuzana Hájková, Jaroslav Švehla, Bohumír Grüner, published by Institute of Nuclear Chemistry and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

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