Studies on structure, growth and characterization of third order nonlinear optical 2-amino-5-chloropyridinium-4-amino benzoate single crystal

Krishnakumar, M.; Thirupugalmani, K.; Brahadeeswaran, S.

doi:10.1515/msp-2017-0061

Abstract

Optically transparent single crystals of 2-amino-5-chloropyridinium-4-amino benzoate (2A5CP4AB) were grown at room temperature using solution growth technique. The structure was solved with a support of single crystal XRD, which revealed that the title compound belongs to the monoclinic crystal system having centrosymmetric space group P21/n. The UV-Vis spectrum and photoluminescence properties of the title compound showed the optical transmittance and emission behavior of the compound. The optical band gap was evaluated using the Tauc plot and it was found to be about 3.53 eV. The third order nonlinear optical behavior of the crystal was determined using Z-scan technique. Mechanical properties of the title compound were studied using Vickers microhardness study.

References

[1] PERIYASAMY B.K., JEBAS R.S., THAILAMPILLAI B., Mater. Lett., 61 (2007), 1489.10.1016/j.matlet.2006.07.069
Search in Google Scholar Back to article
[2] PRASAD P.N., WILLIAMS D.J., Introduction to Nonlinear Optical Effects in molecules and Polymers, Wiley, New York, 1991.
Search in Google Scholar Back to article
[3] CAROLIN M.L., VASUDEVAN S., Mater. Lett., 62 (2008), 2245.10.1016/j.matlet.2007.11.059
Search in Google Scholar Back to article
[4] ANANDHA BABU G., SREEDHAR S., VENUGOPAL R., RAMASAMY P., J. Cryst. Growth, 312 (2010), 1957.10.1016/j.jcrysgro.2010.03.017
Search in Google Scholar Back to article
[5] SANTHAKUMARI S., RAMAMURTHI K., Spectrochim. Acta A, 78 (2011), 653.10.1016/j.saa.2010.11.04321186136
Search in Google Scholar Back to article
[6] DHANRAJ P.V., RAJESH N.P., VINITHA G., BHAGAVANNARAYANA G., Mater. Res. Bull., 46 (2011), 726.10.1016/j.materresbull.2011.01.013
Search in Google Scholar Back to article
[7] BRAHADEESWARAN S., ONDUKA S., TAKAGI M., TAKAHASHI Y., ADACHI H., YOSHIMURA M., MORI Y., SASAKI T., J. Cryst. Growth, 292 (2006), 441.10.1016/j.jcrysgro.2006.04.052
Search in Google Scholar Back to article
[8] BRAHADEESWARAN S., ONDUKA S., TAKAGI M., TAKAHASHI Y., ADACHI H., KAMIMURA T., YOSHIMURA M., MORI Y., YOSHIDA K., SASAKI T., Cryst. Growth Des., 6 (2006), 2643.10.1021/cg0505721
Search in Google Scholar Back to article
[9] ROBINSON F.A., The vitamin Co-factors of Enzyme Systems, Pergamon, London, 1966.10.1016/B978-1-4831-6823-4.50013-6
Search in Google Scholar Back to article
[10] PAULING L., HAYWARD R., The Architecture of Molecules, W.H. Freeman, San Francisco, 1964.
Search in Google Scholar Back to article
[11] GRACIN S., RASMUSON A.C., Cryst. Growth Des., 4 (2004), 1013.10.1021/cg049954h
Search in Google Scholar Back to article
[12] ETTER M.C., FRANKENBACH G.A., Chem. Mater., 1 (1989), 10.10.1021/cm00001a005
Search in Google Scholar Back to article
[13] KASHINO S., SUMIDA Y., HAISA M., Acta Crystallogr. B, 28 (1972), 1374.10.1107/S0567740872004339
Search in Google Scholar Back to article
[14] KASHINO S., Acta Crystallogr. B, 29 (1973), 1836.10.1107/S0567740873005613
Search in Google Scholar Back to article
[15] RADEMEYER M., OVERBEEK G.E., LILES D.C., Acta Crystallogr. E, 66 (2010), 1634.10.1107/S1600536810047902
Search in Google Scholar Back to article
[16] BRAHADEESWARAN S., VENKATARAMAN V., BHAT H.L., J. Cryst. Growth, 205 (1999), 544.10.1016/S0022-0248(99)00302-4
Search in Google Scholar Back to article
[17] WU J.I., GOPALAKRISHNAN R., TAI C. ID., LAW C.W., Jpn. J. Appl. Phys., 43 (2004), 1507.10.1143/JJAP.43.1507
Search in Google Scholar Back to article
[18] SHANMUGAM G., BRAHADEESWARAN S., Spectrochim. Acta A, 95 (2012), 177.10.1016/j.saa.2012.04.100
Search in Google Scholar Back to article
[19] KWON S.J., JAZBINSEK M., KWON O.P., GUNTER P., Cryst. Growth Des., 10 (2010), 1552.10.1021/cg900882h
Search in Google Scholar Back to article
[20] MERCURY 1.3., Cambridge Crystallographic Data centre, CCDC Software Limited, Cambridge, UK, 2004.
Search in Google Scholar Back to article
[21] KANNAN V., SUGUMAR P., BRAHADEESWARAN S., PONNUSWAMY M.N., Acta Crystallogr. E, 8 (2012), 3187.10.1107/S1600536812043085
Search in Google Scholar Back to article
[22] FASONE S., GRASSO D., GANDOLFO C., J. Mol. Struct., 20 (1974), 449.10.1016/0022-2860(74)85122-7
Search in Google Scholar Back to article
[23] SHARMA Y.R., Elementary organic spectroscopy, S. Chand, New Delhi, 1996.
Search in Google Scholar Back to article
[24] SHANMUGAM G., BELSLEY M.S., ISAKOV D., MATOS KOMAS E.D., NEHRU K., BRAHADEESWARAN S., Spectrochim. Acta A, 95 (2012), 177.
Search in Google Scholar Back to article
[25] TAUC J.C., The optical properties of solids, Academic Press, North-Holland, 1972.
Search in Google Scholar Back to article
[26] ARAVINDAN A., SRINIVASAN P., Cryst. Res. Technol., 11 (2007), 1097.10.1002/crat.200710954
Search in Google Scholar Back to article
[27] SABARIGIRISUN T.C., DHANUSKODI S., Cryst. Res.Technol., 44 (2009), 1297. 10.1002/crat.200900351
Search in Google Scholar Back to article
[28] WOLFERSBERGER D., FRESSENGEAS N., MAUFOY J., KUGEL G., J. Nonlinear. Opt. Phys., 9 (2000), 441.10.1142/S0218863500000376
Search in Google Scholar Back to article
[29] THIRUPUGALMANI K., KARTHICK S., SHANMUGAM G., KANNAN V., SRIDHAR B., NEHRU K., BRAHADEESWARAN S., Opt. Mater., 49 (2015), 158.10.1016/j.optmat.2015.09.014
Search in Google Scholar Back to article
[30] ARUN K.J., JEYALAKSHMI S., Optoelectron. Adv. Mat., 2 (2008), 701.
Search in Google Scholar Back to article
[31] BOYD R.W., Nonlinear Optics, Elsevier, USA, 2008.
Search in Google Scholar Back to article
[32] CHEUNG Y.M., GAYEN S.K., J. Opt. Soc. Am. B, 11 (1994) 636.
Search in Google Scholar Back to article
[33] RODRIGUEZ L., AHN H.Y., BELFIELD D.K., Opt. Express, 17 (2009), 19617.10.1364/OE.17.01961719997182
Search in Google Scholar Back to article

Studies on structure, growth and characterization of third order nonlinear optical 2-amino-5-chloropyridinium-4-amino benzoate single crystal

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