Have a personal or library account? Click to login
Structural and morphological analysis of barium cerate electrolyte for SOFC application Cover

Structural and morphological analysis of barium cerate electrolyte for SOFC application

Open Access
|Feb 2017

Abstract

Gadolinium doped barium cerate (BCG) electrolytes Ce0.8Gd0.2O1.9 + xBaO (x = 0.1 and 0.4) were prepared by wet chemical method for the use in solid oxide fuel cells operating at intermediate temperatures (600 °C to 800 °C). The as-prepared powder sample was calcined at 900 °C. The calcination temperature was identified using differential scanning calorimetry (DSC) analysis. The orthorhombic perovskite phase formation was confirmed by XRD analysis. From TEM results, the particle size was found to be about 32 nm which is in a good agreement with XRD results. BCG nanoparticles were formed at lower sintering temperature due to using microwave furnace. By reducing the sintering temperature of solid electrolyte through microwave technique, the percentage of barium loss was successfully reduced and the prepared electrolyte can be a good choice for solid oxide fuel cells operating at intermediate temperatures.

DOI: https://doi.org/10.1515/msp-2017-0021 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 120 - 125
Submitted on: May 4, 2016
Accepted on: Jan 4, 2017
Published on: Feb 24, 2017
Published by: Wroclaw University of Science and Technology
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2017 A. Senthil Kumar, R. Balaji, P. Puviarasu, S. Jayakumar, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.