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Structural, electrical and magnetic features of Kagomé YBaCo4O7 system Cover

Structural, electrical and magnetic features of Kagomé YBaCo4O7 system

Open Access
|Dec 2016

Figures & Tables

XRD pattern of YBaCo4O7 with Reitveld refinement.
XRD pattern of YBaCo4O7 with Reitveld refinement.
(a) SEM image and (b) EDX pattern of YBaCo4O7.
(a) SEM image and (b) EDX pattern of YBaCo4O7.
Raman spectrum of YBaCo4O7 in the 100 cm−1to 1600 cm−1region.
Raman spectrum of YBaCo4O7 in the 100 cm−1to 1600 cm−1region.
Resistance vs. temperature at 0 T and 8 T magnetic field.
Resistance vs. temperature at 0 T and 8 T magnetic field.
lnp vs. T−1/4 (K−1/4) at 0 T and 8 T with linear fit.
lnp vs. T−1/4 (K−1/4) at 0 T and 8 T with linear fit.
M (emu ) vs. T (K) for ZFC, FC and FCW for YBaCo4O7 under 1 T magnetic field.
M (emu ) vs. T (K) for ZFC, FC and FCW for YBaCo4O7 under 1 T magnetic field.
Isothermal magnetization moment (emu) vs. magnetic field H (Oe).
Isothermal magnetization moment (emu) vs. magnetic field H (Oe).

YBaCo4O7 different XRD parameters; space group - P63mc, a = 6_2874 Å, c = 10_2533 Å, volume = 660_9953 Å3, χ2 = 1_351, Rwp = 19_5, Rexp = 16_7_

AtomAtom site multiplicityXYZOccupancy
Y2b0.666670.333340.878550.16667
Ba2b0.666670.333340.500000.16667
Co12a0.000000.000000.440280.16667
Co26c0.189870.852180.677240.50000
O16c0.388930.471000.711810.50000
O22a0.000000.000000.221560.16667
O36c0.124360.809510.545660.50000

Elemental composition details in wt_% and at_% of YBaCo4O7 obtained from EDX pattern_

Elementwt.%at.%
O K30.4268.66
Co K29.0117.77
Y L20.278.23
Ba L20.305.34
Total100.00100.00
DOI: https://doi.org/10.1515/msp-2016-0122 | Journal eISSN: 2083-134X | Journal ISSN: 2083-1331
Language: English
Page range: 786 - 793
Submitted on: Feb 13, 2016
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Accepted on: Oct 25, 2016
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Published on: Dec 23, 2016
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2016 Masroor Ahmad Bhat, R. A. Zargar, Anchit Modi, M. Arora, N. K. Gaur, published by Wroclaw University of Science and Technology
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.