Organic Synthesis with Dioxiranes offers a comprehensive treatment of dioxirane chemistry, from fundamental mechanisms to advanced applications in precision synthesis. Structured consistently across chapters, it moves from basic dioxirane reactivity and mechanism through general oxidation across functional groups, substrate-specific epoxidation strategies, site-selective C–H functionalization and asymmetric synthesis. Organized by functional group and reaction type rather than mere chronology, it mirrors how practicing chemists actually search reference material. The book functions simultaneously as a conceptual introduction and a practical lookup resource — readable front-to-back to build understanding progressively, or consulted directly for a specific substrate or selectivity need.
Key Features
Consistent chapter template for easy, reference-style navigation
Organized by functional group and reaction type, not chronology
Layered selectivity framework: stereospecific, chemoselective, stereoselective, diastereoselective, enantioselective
Bond-type-first approach to C–H oxygenation strategies
Clear progression from fundamentals to precision, enantioselective synthesis
Readership
Synthetic chemists, researchers, and graduate students in organic and mechanistic chemistry.