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Thin-Layer Chromatography of Inks— Efficiency of Separation of Ink Components Cover

Thin-Layer Chromatography of Inks— Efficiency of Separation of Ink Components

Open Access
|Dec 2019

Figures & Tables

Solvent I:ethyl acetate / ethanol / water = 70:35:30 [2, 3, 4]
Solvent II:ethyl acetate / isopropanol / water / acetic acid = 30:15:10:1 [5, 6, 7, 8]2
Solvent III:butanol / isopropanol / water / acetic acid = 20:10:10:1 [9]
Solvent IV:butanol / ethanol / water / acetic acid = 60:10:20:0.5 [10, 11]
Figure 1

The thin-layer chromatogram obtained for Inks A through E (left to right) using Solvent I as the developing solvent (photographed under daylight).

Figure 2

The thin-layer chromatogram obtained for Inks A through E (left to right) using Solvent II as the developing solvent (photographed under daylight).

Figure 3

The thin-layer chromatogram obtained for Inks A through E (left to right) using Solvent III as the developing solvent (photographed under daylight).

Figure 4

The thin-layer chromatogram obtained for Inks A through E (left to right) using Solvent IV as the developing solvent (photographed under daylight).

Table 1

The results of the TLC separation of the dye components of the five inks, designated as Inks A through E, using four developing solvents, designated as Solvents I through IV.

InkNumber of separated dye components
Solvent ISolvent IISolvent IIISolvent IV
A4644
B8121110
C910109
D7989
E6777
Figure 5

Five thin-layer chromatograms obtained for Ink E using the following developing solvents (photographed under daylight):

SI – Solvent I (prepared about 1 hour prior to the TLC analysis)

SII-old – Solvent II (prepared 32 days prior to the day of the TLC analysis)

SII-fresh – Solvent II (prepared about 1 hour prior to the TLC analysis)

SIII– Solvent III (prepared about 1 hour prior to the TLC analysis)

SIV – Solvent IV (prepared about 1 hour prior to the TLC analysis)

DOI: https://doi.org/10.69525/jasqde.259 | Journal eISSN: 1524-7287
Language: English
Page range: 13 - 21
Published on: Dec 1, 2019
Published by: American Society of Questioned Document Examiners
In partnership with: Paradigm Publishing Services

© 2019 Valery N. Aginsky, published by American Society of Questioned Document Examiners
This work is licensed under the Creative Commons Attribution 4.0 License.