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Assessing the Accuracy of Nitrate Concentration Data for Water Quality Monitoring Using Visual and Cell Phone Quantification Methods Cover

Assessing the Accuracy of Nitrate Concentration Data for Water Quality Monitoring Using Visual and Cell Phone Quantification Methods

By: Melissa Topping and  Alan Kolok  
Open Access
|Feb 2021

Figures & Tables

Table 1

Organizations that participated in testing events with their corresponding test dates and sample sizes.

TESTING EVENTDATESAMPLE SIZEVOLUNTEER TYPE
ORED staff2/26/1923University of Idaho staff
Idaho commons3/22/1923University of Idaho college students, staff
ORED open house4/4/1911General college population
Spokane River forum4/16/1916Water professionals, educators, general public
Columbia High School5/28/1915High school students
Palouse Basin aquifer committee meeting10/10/1913General public, water professionals, students
OurGem symposium11/6/199General public, water professionals
Idaho Water Institute symposium11/12/193Water resources graduate students, faculty
Idaho commons12/6/199University of Idaho college students
Idaho water quality workshop2/11/2010Water professionals, students, general public, faculty
Continuum test: visual samplers6/24/195Idaho Water Institute staff and interns
Continuum test: app samplers1/24/205Water resources graduate students

[i] Notes: ORED = Office of Research and Economic Development.

Table 2

Breakdown of volunteers using each quantification method using either categorical or continuous instructions to test their sample.

NITRATE CONCENTRATION (PPM)TOOLCATEGORICAL INSTRUCTIONS N =CONTINUOUS INSTRUCTIONS N =
2App1716
Eye1816
15App1716
Eye1715
Table 3

Test strip categories used by visual volunteers and the ranges of continuous nitrate samples placed in those bins.

HACH© TEST STRIP SCALE (PPM)CONTINUOUS SAMPLES ASSIGNED TO EACH CATEGORY (PPM)
0.0n/a
1.01
2.03
5.05, 7
10.09, 11, 13, 15
20.017, 19, 21, 23, 25, 27, 29, 31, 33, 35
50.037, 39, 41, 43, 45, 47, 49
cstp-6-1-346-g1.png
Figure 1

Graphical representation of the proportions of accurate and inaccurate responses for both analytic tools.

cstp-6-1-346-g2.png
Figure 2

A scatter plot of data produced by continuous app users that compares the actual concentration of nitrate to the volunteers’ recorded values.

cstp-6-1-346-g3.png
Figure 3

The dots represent continuous sample concentrations and their designated Hach© category bins. For example, concentrations that fall between 15.1 and 35.9 ppm (or mg/L) would be binned into category 5.

cstp-6-1-346-g4.png
Figure 4

The relationship between nitrate concentrations and corresponding response categories produced by visual volunteers. The blue color corresponds to the samples in the lower range with smaller residuals and the orange corresponds to the samples in the higher range with residuals across three categories. The size of the circles provides a visual approximation of the proportion of samples that fall within each response concentration. In each case the total proportion equals 100%. The response concentration categories are defined by Hach as: 0 = 0ppm, 1 = 1ppm, 2 = 2ppm, 3 = 5 ppm, 4 = 10 ppm, 5 = 20 ppm, and 6 = 50 ppm.

DOI: https://doi.org/10.5334/cstp.346 | Journal eISSN: 2057-4991
Language: English
Submitted on: Jun 4, 2020
Accepted on: Feb 3, 2021
Published on: Feb 26, 2021
Published by: Ubiquity Press
In partnership with: Paradigm Publishing Services
Publication frequency: 1 issue per year

© 2021 Melissa Topping, Alan Kolok, published by Ubiquity Press
This work is licensed under the Creative Commons Attribution 4.0 License.