Spectroscopic studies of dual fluorescence effects in a selected 1,3,4-thiadiazole derivative in organic solvents and aqueous solutions

Matwijczuk, Arkadiusz; Matwijczuk, Alicja; Karcz, Dariusz; Wybraniec, Sławomir; Kluczyk, Dariusz; Gagoś, Mariusz; Niewiadomy, Andrzej

doi:10.4467/2353737XCT.17.031.6342

Abstract

Spectroscopic studies of the fluorescence emission of selected 1,3,4-thiadiazoles in organic solvents and an aqueous solution were carried out. An interesting effect of pH-induced dual fluorescence was observed in the aqueous solution. The use of organic solvents resulted either in a single fluorescence maximum, double fluorescence (two well-resolved emission bands), or the dual fluorescence effect. The results obtained suggest that the fluorescence emission effects in 1,3,4-thiadiazoles are associated with both the conformational isomerism and the chromophore aggregation phenomena.

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Spectroscopic studies of dual fluorescence effects in a selected 1,3,4-thiadiazole derivative in organic solvents and aqueous solutions

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