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Stable carbon and nitrogen isotopic compositions of tropical atmospheric aerosols: sources and contribution from burning of C3 and C4 plants to organic aerosols Cover

Stable carbon and nitrogen isotopic compositions of tropical atmospheric aerosols: sources and contribution from burning of C3 and C4 plants to organic aerosols

Open Access
|Jan 2014

Figures & Tables

Fig. 1

Map showing the location of the sampling site of Morogoro, Tanzania.

Fig. 2

Typical examples of 5-day backward air mass trajectories arriving at Morogoro during the May–August 2011 sampling period.

Fig. 3

Trends of aerosol mass concentrations (µg m−3) in PM2.5 and PM10 during the May–August 2011 sampling period at Morogoro.

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Table 1. Concentrations of TC and TN (µg m−3), their isotope ratios (‰), TC/TN and TC/PM (%) in PM2.5 from Morogoro, Tanzania (n=21)

Dateδ1315NTCTNTC/TNTC/PMTN/PM
30/5/2011−25.4NA6.1BDLNA22.4NA31/5/2011−25.816.17.20.513.921.81.61/6/2011−25.113.53.70.66.312.92.02/6/2011−25.9NA6.0BDLNA26.4NA4/6/2011−24.813.43.90.410.411.61.15/6/2011−24.315.34.50.411.517.81.66/6/2011−25.6NA7.4BDLNA20.3NA7/6/2011−25.614.15.30.412.822.11.79/6/2011−26.1NA3.1BDLNA19.0NA12/6/2011NANA4.5BDLNA17.5NA13/6/2011NANA7.90.613.720.61.528/7/2011−22.620.38.00.99.221.92.429/7/2011−22.013.510.41.47.634.74.61/8/2011−21.822.19.70.911.430.02.62/8/2011−20.617.29.71.56.323.73.83/8/2011−21.217.98.30.612.827.32.14/8/2011NANA6.60.710.210.81.15/8/2011−22.414.26.90.79.614.51.56/8/2011−21.3NA4.2BDLNA9.6NA7/8/2011−21.716.45.50.78.117.52.28/8/2011−21.816.87.70.613.520.81.5Mean±SD−23.6±1.916.2±2.76.5±2.10.7±0.310.5±2.620.8±6.42.2±1.0

[i] BDL: below detection limit, DL: ca. 0.02 µg m−3 for TC and 0.05 µg m−3 for TN. NA: not available.

Table 2. Concentrations of TC and TN (µg m−3), their isotope ratios (‰), TC/TN and TC/PM (%) in PM10 from Morogoro, Tanzania (n=21)

Dateδ1315NTCTNTC/TNTC/PMTN/PM
30/5/2011−24.010.46.00.79.213.31.431/5/2011−24.111.68.20.711.0NDNA1/6/2011−24.4NA6.8BDLNA11.8NA2/6/2011−24.4NA8.3BDLNA16.1NA4/6/2011−23.413.04.20.66.911.81.75/6/2011−23.012.96.40.79.317.71.96/6/2011−23.712.79.70.812.020.11.77/6/2011−23.913.47.50.710.318.21.89/6/2011−23.810.76.40.78.715.21.812/6/2011−23.811.29.30.811.616.81.413/6/2011−23.415.411.41.011.919.91.728/7/2011−23.913.45.90.610.212.01.229/7/2011−23.516.510.50.911.128.72.61/8/2011−22.717.016.01.213.220.31.52/8/2011−22.618.718.01.611.418.11.63/8/2011−22.414.612.60.914.121.31.54/8/2011−23.9NA11.7BDLNA14.6NA5/8/2011−23.812.98.80.811.215.51.46/8/2011−23.713.95.30.511.512.21.17/8/2011NANA9.80.812.117.81.58/8/2011−23.414.711.20.814.120.11.4Mean±SD−23.6±0.513.7±2.29.2±3.50.8±0.211.1±1.817.0±4.21.6±0.3

[i] BDL: below detection limit, DL: ca. 0.02 µg m−3 for TC and 0.05 µg m−3 for TN. NA: not available.

Table 3. Isotope ratios (‰) of carbon and nitrogen in the fine and coarse fractions of Morogoro, Tanzania, during 2011 wet and dry season campaigns

Wet seasonDry seasonWet seasonDry season



δ13Cfineδ13Ccoarseδ13Cfineδ13Ccoarseδ15Nfineδ15Ncoarseδ15Nfineδ15Ncoarse
Min.−26.1−23.8−22.6−30.813.47.113.55.8Max.−24.3−17.8−20.6−23.416.112.522.119.7Mean±SD−25.4±0.6−21.5±2.1−21.7±0.7−26.5±3.014.7±1.29.1±2.917.4±3.112.1±5.1
Fig. 4

Temporal variation of TC and δ13C in (a) PM2.5 and (b) PM10 during the May–August 2011 sampling period at Morogoro.

Fig. 5

Relation between TC with levoglucosan and nss-K+ in PM2.5 (a, b) and PM10 (c, d) during the sampling period.

Fig. 6

Temporal variation of TN and δ15N in (a) PM2.5 and (b) PM10 during the May–August 2011 sampling period at Morogoro.

Fig. 7

Relation between NO3--N, NH4+-N and (NH4++NO3-)-N with TN in (a) PM2.5 and (b) PM10 during the sampling period.

Fig. 8

Linear relation between δ13C of TC with nss-K+ and levoglucosan in (a, b) PM2.5 and (c, d) PM10 during the sampling period in tropical aerosols from Tanzania.

Fig. 9

Biomass burning active fire spots detected by MODIS satellite images (from NASA website) over southern and eastern Africa and Madagascar in July 2011.

Language: English
Page range: 20176 - 20176
Submitted on: Nov 27, 2012
Accepted on: Nov 29, 2013
Published on: Jan 1, 2014
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services

© 2014 Stelyus L. Mkoma, Kimitaka Kawamura, Eri Tachibana, Pingqing Fu, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.