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The indirect determination of chlorine atom concentration in the troposphere from changes in the patterns of non-methane hydrocarbons Cover

The indirect determination of chlorine atom concentration in the troposphere from changes in the patterns of non-methane hydrocarbons

Tellus B: Chemical and Physical Meteorology
Volume 49 (1997): Issue 5
By: ,  ,  ,   and    
Open Access
|Jan 1997
References

References

  1. Anlauf , K. G. , Mickle , R. E. and Trivett , N. B. A . 1994 . Measurements of ozone during Polar Sunrise Experi-ment 1992 . J. Geophys. Res . 99 , 25345-25 353 .
    Search in Google ScholarBack to article
  2. Atkinson , R . 1994. Gas phase chemistry of organic compounds. J. Phys. Ref. Data, Monograph 2.
    Search in Google ScholarBack to article
  3. Atkinson , R. and Aschmann , S. M . 1985 . Kinetics of the gas-phase reaction of Cl atoms with a series of organics at 2982 K and atmospheric pressure . Int. J. Chem. Kinet . 19 , 1097 – 1105 .
    Search in Google ScholarBack to article
  4. Atkinson , R. , Baulch , D. L. , Cox , R. A. , Hampson , R. F. Jr , Kerr , J. A. and Troe , J . 1989 . Evaluated kinetic and photochemical data for atmospheric chemistry. Supplement III, JUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry . J. Phys. Chem. Ref. Data 19 , 881 – 1095 .
    Search in Google ScholarBack to article
  5. Atkinson , R. , Baulch , D. L. , Cox , R. A. , Hampson , R. F. Jr , Kerr , J. A. and Troe , J . 1992 . Evaluated kinetic and photochemical data for atmospheric chemistry. Supplement IV, JUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry . J. Phys. Chem. Ref Data 21 , 1125 – 1568 .
    Search in Google ScholarBack to article
  6. Barrie , L. A. , Bottenheim , J. W. , Schnell , R. C. , Crutzen , P. J. and Rasmussen , R. A . 1988 . Ozone destruction and photochemical reactions at Polar Sunrise in the lower Arctic atmosphere . Nature 334 , 138 – 141 .
    Search in Google ScholarBack to article
  7. Bottenheim , J. W. , Barrie , L. A. , Atlas , E. , Heidt , L. E. , Niki , H. , Rasmussen , R. A. and Shepson , P. B . 1990 . Depletion of lower tropospheric ozone during Arctic spring: the Polar Sunrise Experiment 1988 . J. Geophys. Res . 95 , 101 – 127 .
    Search in Google ScholarBack to article
  8. Blake , D. R. , Blake , N. J. , Smith , T. W. , Wingenter , O. W. and Rowland , F. S . 1996 . Nonmethane hydrocarbon and halocarbon distributions during Atlantic stratocu-mulus transition experiment/marine aerosol and gas exchange, June 1992 . J. Geophys. Res . 101 , 4501 – 4514 .
    Search in Google ScholarBack to article
  9. Donahue , N. M. and Prinn , R. G . 1993 . In situ nonmethane hydrocarbon measurements on SAGA 3 . J. Geo-phys. Res . 98 , 16 915-16 932 .
    Search in Google ScholarBack to article
  10. Finlayson-Pitts , B. J . 1993 . Comment on indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Point Arena, California by Parish et al. J. Geophys. Res . 98 , 14 991-14 993 .
    Search in Google ScholarBack to article
  11. Graedel , T. E. and Keene , W. C . 1995 . Tropospheric budget of reactive chlorine . Global Biogeochemical Cycles 9 , 47 – 77 .
    Search in Google ScholarBack to article
  12. Hausmann , M. and Platt , U . 1994 . Spectroscopic measurements of bromine oxide and ozone in the high Arctic during Polar Sunrise . J. Geophys. Res . 99 , 25399-25 413 .
    Search in Google ScholarBack to article
  13. Hemmig , B. L. , Chatfield , R. B. Andreae , M. O. and Vastano , J. A . 1994. Dimethyl sulfide oxidation over the subtropical Atlantic: OH and other oxidants. EOS, Trans. Amer. Geophys. Union 75 (44), suppl., 149.
    Search in Google ScholarBack to article
  14. Hopper , J. F. and Hart , W . 1994 . Meteorological aspects of the 1992 Polar Sunrise Experiment . J. Geophys. Res . 99 , 25315-25 328 .
    Search in Google ScholarBack to article
  15. Jobson , B. T. , Niki , H. , Yokouchi , Y. , Bottenheim , J. , Hopper , F. and Leaitch , R . 1994a . Measurements of C2-C6 hydrocarbons during the polar sunrise 92 experiment . J. Geophys. Res . 99 , 25355 - 25368 .
    Search in Google ScholarBack to article
  16. Jobson , B. T. , Wu , Z. , Niki , H. and Barrie , L . 1994 . Measurements of C2-C6 hydrocarbons during the polar sunrise 92 experiment . J. Geophys. Res . 99 , 25 355 - 25 368 .
    Search in Google ScholarBack to article
  17. Keene , W. C. , Pszenny , A. A. P. , Jacob , D. J. , Duce , R. A. , Galloway , J. N. , Schultz-Tokos , J. J. , Sievering , H. and Boatman , J. F . 1990 . The geochemical cycling of reactive chlorine through the marine troposphere . Global Biogeochemical Cycles 4 , 407 – 430 .
    Search in Google ScholarBack to article
  18. Kieser , B. N. , Bottenheim , J. W. , Sideris , T. and Niki , H . 1993 . Spring 1989 observations of lower tropospheric chemistry in the Canadian high arctic . Atmos. Environ . 27A , 2979 – 2988 .
    Search in Google ScholarBack to article
  19. Koppmann , R. , Bauer , R. , Johnen , F. J. , Plass-Dillmer , C. and Rudolph , J . 1992 . The distribution of light nonmethane hydrocarbons over the mid-Atlantic: results of the Polarstern cruise ANT VII/1 . J. Atmos. Chem . 15 , 215 – 234 .
    Search in Google ScholarBack to article
  20. Maben , R. J. , Keene , W. C. , Pszenny , A. A. P. and Galloway , J. N . 1995 . Volatile inorganic Cl in surface air over eastern North America . Geophys. Res. Lett . 22 , 3513 – 3516 .
    Search in Google ScholarBack to article
  21. McKeen , S. A. , Trainer , M. , Hsie , E.-Y. , Tallamraju , R. K. and Liu , S. C . 1990 . On the indirect determination of atmospheric OH-radical concentrations from reactive hydrocarbon measurements . J. Geophys. Res . 95 , 7493 – 7500 .
    Search in Google ScholarBack to article
  22. McKeen , S. A. and Liu , S. C . 1993 . Hydrocarbon ratios and photochemical history of air masses . Geophys. Res. Lett . 20 , 2363 – 2366 .
    Search in Google ScholarBack to article
  23. McKeen , S. A. , Liu , S. C. , Hsie , E.-Y. , Lin , X. , Bradshaw , J. D. , Smyth , S. , Gregory , G. L. and Blake , D. R . 1996 . Hydrocarbon ratios during PEM-WEST A: a model perspective . J. Geophys. Res . 101 , 2087 – 2109 .
    Search in Google ScholarBack to article
  24. Parrish , D. , Hahn , C. , Williams , E. , Norton , R. and Fehsenfeld , F . 1992 . Indications of photochemical his-tories of Pacific air masses from measurements of atmospheric trace species at Point Arena . J. Geophys, Res . 97 , 15 883 – 15901 .
    Search in Google ScholarBack to article
  25. Parrish , D. , Hahn , C. , Williams , E. , Norton , R. , Fehsen-feld , F. , Singh , H. B. , Gandrud , B. W. and Ridley , B. A . 1993 . Reply . J. Geophys. Res . 98 , 14 991-14 994 .
    Search in Google ScholarBack to article
  26. Press , W. H. , Teukolsky , S. A. , Vetterling , W. T. and Flannery , B. P . 1992 . Numerical recipes, 2nd edition . Cambridge University Press , Cambridge USA , pp. 666 – 671 .
    Search in Google ScholarBack to article
  27. Pszenny , A. A. P. , Kenne , W. C. , Jacob , D. J. , Fan , S. , Maben , J. R. , Zetwo , M. P. , Springer-Young , M. and Galloway , J. N . 1993 . Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air . Geophys. Res. Lett . 20 , 699 – 702 .
    Search in Google ScholarBack to article
  28. Ramacher , B. , Rudolph , J. and Koppmann , R . 1996 . Hydrocarbon measurements in the spring Arctic tro-posphere during the ARCTOC 95 campaign . Tellus 49B , 446 – 485 .
    Search in Google ScholarBack to article
  29. Ratte , M. , Plass-Dillmer. C. , Koppmann , R. and Rudolph , J . 1995 . Horizontal and vertical profiles of light hydrocarbons in sea water related to biological, chemical and physical parameters . Tellus 47B , 607 – 623 .
    Search in Google ScholarBack to article
  30. Roberts , J. M. , Fehsenfeld , F. C. , Liu , S. C. , Bollinger , M. J. , Hahn , C. , Albritton , D. L. and Sievers , R. E . 1984 . Measurements of aromatic hydrocarbon ratios and NOx concentrations in the rural troposphere: Observations of air mass photochemical aging and NQ removal . Atmos. Environment 18 , 2421 – 2432 .
    Search in Google ScholarBack to article
  31. Rudolph , J . 1995 . The tropospheric distribution and budget of ethane . J. Geophys. Res . 100 , 11 383 - 11 391 .
    Search in Google ScholarBack to article
  32. Rudolph , J . 1988 . Two-dimensional distribution of light hydrocarbons: results from the STRATOZ III experi-ment . J. Geophys. Res . 93 , 8367 – 8377 .
    Search in Google ScholarBack to article
  33. Rudolph , J. , Johnen , F. J. , Khedim , A. and Pilwat , G . 1989b . The use of automated “on line” gaschromatog-raphy for the monitoring of organic trace gases in the atmosphere at low levels . Int. J. Environ. Anal. Chem . 38 , 143 – 155 .
    Search in Google ScholarBack to article
  34. Rudolph , J. , Koppmann , R. and Plass Dtilmer , Ch . 1996 . The budgets of ethane and tetrachlorethene: is there evidence for an impact of reactions with chlorine atoms in the troposphere? Atmos. Environ . 30 , 1887 – 1894 .
    Search in Google ScholarBack to article
  35. Sander , R. and Crutzen , P. J . 1996 . Model study indicat-ing halogen activation and ozone destruction in pol-luted air masses transported to the sea . J. Geophys. Res . 102 , 9121 – 9138 .
    Search in Google ScholarBack to article
  36. Singh , H. B. and Kasting , J. F . 1988 . Chlorine-hydrocarbon photochemistry in the marine tropo-sphere and the lower stratosphere . J. Atmos. Chem . 7 , 261 – 285 .
    Search in Google ScholarBack to article
  37. Singh , H. B. , Gregory , G. L. Anderson , B. , Browell , E. , Sachse , G. W. , Davis , D. D. , Crawford , J. , Bradshaw , D. J. , Talbot , R. , Blake , D. R. , Thornton , D. , Newell , R. and Merrill , J . 1996a . Low ozone in the marine bound-ary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms, and entrainment . J. Geophys. Res . 101 , 1907 – 1917 .
    Search in Google ScholarBack to article
  38. Singh , H. B. , Thakur , A. N. , Chen , Y. E. and Kanaki-dou , M . 1996b . Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere . Geo-phys. Res. Lett . 23 , 1529 – 1532 .
    Search in Google ScholarBack to article
  39. Solberg , S. , Schmidtbauer , N. , Semb , A. and Hov , O . 1996 . Boundary layer ozone depletion as seen in the Norwegian arctic in spring . J. Atmos. Chem . 23 , 301 – 332 .
    Search in Google ScholarBack to article
  40. Vogt , R. , Crutzen , P. J. and Sander , R . 1996 . A mechan-ism for halogen release from sea-salt aerosol in the remote marine boundary layer . Nature , in press .
    Search in Google ScholarBack to article
  41. Wang, Ch. J.-L. , Blake , D. R. and Rowland , F. S . 1995 . Seasonal variation in the atmospheric distribution of a reactive chlorine compound, tetrachloroethene (CCl2=CCl2). Geophys. Res. Lett . 22 , 1097 - 1100
    Search in Google ScholarBack to article
  42. Wingenter , O. W. , Kubo , M. K. , Blake , N. J. , Smith , T. W. , Blake , D. R. and Rowland , F. S . 1996 . Hydrocarbon and halocarbon measurements as photochem-ical and dynamical indicators of atmospheric hydroxyl, atomic chlorine, and vertical mixing obtained during Lagrangian ffights . J. Geophys. Res . 101 , 4331 – 4340 .
    Search in Google ScholarBack to article
  43. Yokouchi , Y. , Akimoto , H. , Barrie , L. A. , Bottenheim , J. W. , Anlauf , K. and Jobson , B. T . 1994 . Serial gas chromatographic/mass spectrometric measurements of some volatile organic compounds in the Arctic atmosphere during the 1992 Polar Sunrise Experiment . J. Geophys. Res . 99 , 25 379-25 389 .
    Search in Google ScholarBack to article
DOI: https://doi.org/10.3402/tellusb.v49i5.16016 | Journal eISSN: 1600-0889
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Language: English
Page range: 592 - 601
Submitted on: Oct 2, 1996
Accepted on: Jul 25, 1997
Published on: Jan 1, 1997
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services

© 1997 J. Rudolph, B. Ramacher, C. Plass-Dülmer, K.-P. Müller, R. Koppmann, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.

Volume 49 (1997): Issue 5
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