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DOAS-observation of halogen radical-catalysed arctic boundary layer ozone destruction during the ARCTOC campaigns 1995 and 1996 in Ny-Ålesund, Spitsbergen Cover

DOAS-observation of halogen radical-catalysed arctic boundary layer ozone destruction during the ARCTOC campaigns 1995 and 1996 in Ny-Ålesund, Spitsbergen

Open Access
|Jan 1997

References

  1. Atkinson , R. , Baulch , D. L. , Cox , R. A. , Hampson , R. F. , Kerr , J. A. and Troe , J . 1992 . Evaluated kinetic and photochemical data for atmospheric chemistry, supplement-IV. IUPAC Subcommittee on Gas kinetic data evaluation for atmospheric chemistry. .1. Phys . Chem. Reference Data 21 , 1125 1568 .
  2. Axelson , H. , Galle , B. , Gustavsson , K. , Ragnarsson , P. and Rudin , M . 1990 . A transmitting/receiving tele-scope for DOAS-measurements using retroreflector technique Techn . Dig. Series 4 , 641 644 .
  3. Barrie , L. A. , Li , S. M , Toom , D. M. , Landsberger , S. and Sturges , W . 1994 . Measurements of aerosol and gaseous halogens, nitrates and sulphur oxides by denuder and filter systems during Polar Sunrise Experiment 1992 . J. Geophys. Res . 99 , 25 , 453-25 , 468 .
  4. Barrie , L. A. , Bottenheim , J. W. , Schnell , R. C. , Crutzen , P. J. and Rasmussen , R. A . 1988 . Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere . Nature 334 , 138 141 .
  5. Bass , A. M. and Paur R. J . 1985. The ultra-violet cross-sections of ozone (I). The measurements. Proceedings of the Quadrennialozone symposium, Halkidiki, Greece. C. Zerefos Ghazi , (eds), pp. 606 - 616 .
  6. Bedjanian , Y. , Vesine , E. , LeBras , G. and Poulet , G . 1996 . Laboratory study of the stratospheric chemistry of JO radicals, Proceedings of the XVIII Quad . Ozone Symp. L'Aquila , in press .
  7. Behnke , W. , Kruger , H.-U. , Scheer , V. and Zetzsch , C . 1992 . Formation of ClNO2 and HONO in the presence of NO2, O3 and wet NaCl aerosol. J. Aerosol Sc i . 23 , 933 936 .
  8. Behnke , W. , Scheer , V. and Zetzsch , C . 1993 . Formation of ClNO2 and HNO3 in the presence of N2O5 and wet pure NaCl- and wet mixed NaCl/Na2SO4-aerosol. J. Aerosol Sc i . 24 , 115 116 .
  9. Bottenheim , J. W. , Barrie , L. W. , Atlas , E. , Heidt , L. E. , Niki , H. , Rasmussen , R. A. and Shepson , P. B . 1990 . Depletion of lower tropospheric ozone during Arctic spring: The Polar Sunrise Experiment 1988 . J. Geo-phys. Res . 95 , 18 555-18 568 .
  10. Bongartz , A. , Kames , J. , Welter , F. and Schurath , U . 1991 . Near-UV absorption cross sections and trans/ cis equilibrium of nitrous acid . J. Phys. Chem . 95 , 1076 1082 .
  11. Borken , J . 1996 . Ozonabbau durch Halogene in der arktischen Grenzschicht: Reaktionskinetische Modellrechnungen zu einem Friihjahrsphänomen . Diploma Thesis , University of Heidelberg .
  12. Brassington , D. J . 1981 . Sulfur dioxide absorption cross-section measurements from 290 nm. to 317 nm . Appl. Opt . 20 , 3774 3779 .
  13. Brauers , T. , Dorn , H.-P. and Platt , U . 1990. Spectro-scopic measurements of NO2, O3, SO2, IO and NO3 in maritime air. In Physico-chemical behaviour of atmospheric pollutants. Proceeding of the 5th European Symp., Varese, Italia, Restelli , G. and Angeletti , G. (eds), pp. 237 - 242 , Kluwer Academic , Doordrecht .
  14. Brauers , T. , Hausmann , M. , Brandenburger , U. and Dorn , R-P . 1995 . Improvement of differential optical absorption spectroscopy using multichannel scanning technique . Appl. Opt . 34 , 4472 4479 .
  15. Brenninkmeijer , C. A. M. , Manning , M. R. , Lowe , D. C. , Wallace , G. A. , Sparks , R. J. and Volz-Thomas , A . 1992. Interhemispheric asymmetry in OH abundance inferred from measurements of atmospheric 14CO3 Nature 356, 50 - 52 .
  16. Cantrell , C. A. , Davidson , J. A. , McDaniel , A. H. , Shetter , R. E. and Calvert , J. G . 1990 . Temperature-dependent formaldehyde cross section in the near-ultraviolett spectral region . J. Phys. Chem . 94 , 3902 3908
  17. Chatfield , R. B. and Crutzen , P. J . 1990 . Are there inter-actions of iodine and sulfur species in marine air pho-tochemistry , J. Geophys. Res . 95 , 22 , 319-22 , 341 .
  18. Cicerone , R. J . 1981 . Halogens in the atmosphere Rev . Geophys. and Space Phys . 19 , 123 139 .
  19. Coquart , B. , Jenouvrier , A. and Merienne , M. F . 1995 . The NO2-absorption Spectrum (II). Absorption cross sections at low temperature in the 400-500 nm region . J. Atmos. Chem . 21 , 251 261 .
  20. Davis , D. , Crawford , J. , Liu , S. , McKeen , S. , Bandy , A. , Thornton , D. , Rowland , F. and Blake , D . 1996 . Poten-tial impact of iodine on tropospheric levels of ozone and other critical oxidants , J. Geophys. Res . , 101 , 2135 2147 .
  21. De More , W. B. , Sander , S. P. , Golden , D. M. , Hampson , R. F. , Kurylo M. J. , Howard , C. J. , Ravishankara , A. R. , Kolb , C. E. and Molina , M. J . 1994. Chemical kinetics and photochemical data for use in stratospheric modelling. JPL Publication, 94 - 26 .
  22. Fan , S.-M. and Jacob , D. J . 1992 . Surface ozone depletion in the Arctic spring sustained by bromine reactions on aerosols . Nature 359 , 522 524 .
  23. Finlayson-Pitts , B. J . 1993 . Indications of photochemical histories of Pacific air masses from measurements of atmospheric trace species at Point-Arena, California: Comment . J. Geophys. Res . 98 , 14 , 991-14 , 993 .
  24. Finlayson-Pitts , B. J. and Johnson , S. N . 1988 . The reac-tion of NO2 with NaBr: Possible source of BrNO in polluted marine atmospheres . Atmos. Environ . 22 , 1107 1112 .
  25. Finlayson-Pitts , B. J. , Livingston , F. E. and Berko , H. N . 1990 . Ozone destruction and bromine photo chemistry in the Arctic spring . Nature 343 , 622 625 .
  26. Frieß , U . 1997 . Spektroskopische Messungen stratosphärischer Spurenstoffe auf der Neumayer-Station (Antarktis) in den Jahren 1994195 . Diploma Thesis , University of Heidelberg .
  27. Hausmann , M. and Platt , U . 1994 . Spectroscopic meas-urement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992 . J. Geophys. Res . 99 , 25 , 399-25 , 414 .
  28. Hausmann , M. , Ritz , D. and Platt , U. 1992. New coaxial “long-path-DOAS” system: first application to BrO measurement in the Arctic troposphere, Proceedings Europto series. Optical methods in atmospheric chemistry , H. I. Schiff Platt (eds.) pp. 1715 , 341 - 352 .
  29. Himmelmann , S. , Orphal , J. , Bovensmann , H. , Richter , A. , Ladstätter-WeiBenmayer , A. and Burrows , J. P . 1996 . First observation of the OM molecule by time-resolved flash photolysis absorption spectro-scopy . Chem. Phys. Lett . 251 , 330 334 .
  30. Jenkin , M. E . 1992. The photochemistry of iodinecontaining compounds in the marine boundary layer. Report AEA Harwell, AEA-EE-0405.
  31. Jobson , B. T. , Niki , H. , Yokouchi , Y. , Bottenheim , J. , Hopper , F. and Leaitch , R . 1994 . Measurements of C2-C6 hydrocarbons during Polar Sunrise Experiment 1992 . J. Geophys. Res . 99 , 25 , 355-25 , 368 .
  32. Khalil , M. A. K. , Rasmussen , R. A. and Gundwardena , A . 1993 . Atmospheric methyl bromide: trends and global mass balance . J. Geophys. Res . 98 , 2887 2896 .
  33. Kirchner , U. , Benter , Th. and Schindler , R. N . 1997 . Experimental verification of gas phase bromine enrich-ment in reactions of HOBr with sea salt doped ice surfaces . Ber. Bunsenges. Phys. Chem . 101 , 975 977 .
  34. Knoll , P. , Singer , R. and Kiefer , W . 1990 . Improving spectroscopic techniques by a scanning multichannel method . Appl. Spectr . 44 , 776 782 .
  35. Kreher , K . 1996 . Spectroscopic measurements of atmospheric OClO, BrO and NO2 and their relation to Antarctic ozone depletion . PhD Thesis , University of Heidelberg .
  36. Laszlo , B. , Huie , R. E. , Kurylo , M. J. and Miziolek , A. W . 1997 . Kinetic studies of the reaction of BrO and TO Radicals . J. Geophys. Res . 102 , 1523 1532 .
  37. Le Bras , G. and Platt , U . 1995 . A possible mechanism for combined chlorine and bromine catalysed destruc-tion of tropospheric ozone in the Arctic . Geophys. Res. Lett . 22 , 599 602 .
  38. Lehrer , E . 1995. Variabilität arktischer Aerosolchemie im Verlauf troposphdrischer Ozonabbnahme-Episoden, Diploma Thesis, University of Heidelberg.
  39. Lehrer , E. , Wagenbach , D. and Platt , U . 1996. Aerosol chemical composition during tropospheric ozone depletion at Ny-Alesund/Svalbard. Tellus 47B, this issue.
  40. Manö , S. and Andreae , M. O ., 1994 . Emission of methyl bromide from biomass burning . Science 263 , 1255 1256 .
  41. McConnell , J. C. , Henderson , G. S. , Barrie , L. , Bot-tenheim , J. , Niki , H. , Langford , C. H. and Templeton , E. M. J . 1992 . Photochemical bromine production implicated in Arctic boundary-layer ozone depletion . Nature 355 , 150 152 .
  42. Mickle , R. E. , Bottenheim , J. W. , Leaitch , R. W. and Evans , W . 1989 . Boundary layer ozone depletion during AGASP-II . Atmos. Environ . 23 , 2443 2449 .
  43. Mozurkewich , M . 1995. Mechanisms for the release of halogens from sea-salt particles by free radical reac-tions. J. Geophys. Res. , 100, 14,199-14,207.
  44. Murayama , S. , Nakazawa , T. , Tanaka , M. , Aoki , S. and Kawaguchi , S . 1992 . Variations of tropospheric ozone concentration over Syowa station, Antarctica . Tellus 44B , 262 272 .
  45. Oertel , T . 1992. Verteilung leichtflachtiger Organobromverbindungen in der marinen Troposphtire und im Oberfltichenwasser des Atlantik. PhD thesis, FB2, University of Bremen.
  46. Platt , U. and Perner , D . 1983 . Measurements of atmo-spheric trace gases by long path differential UV/visible absorption spectroscopy: optical and laser remote sensing . D. K. Killinger Mooradian (eds.). Springer Ser. Optical Sci. 39 , 95 105 .
  47. Platt , U . 1994. Differential optical absorption spectro-scopy (DOAS). In: Air monitoring by spectroscopic techniques, M. W. Sigrist (ed). Chemical Analysis Series, vol 127, John Wiley & Sons, Inc.
  48. Platt , U. and Hausmann , M . 1994 . Spectroscopic meas-urement of the free radicals NO3, BrO, IO, and OH in the troposphere . Res. Chem. Intermed . 20 , 557 578 .
  49. Platt , U . 1995. The chemistry of halogen compounds in the Arctic troposphere. Proc. LACTOZ/HALIPP Workshop, Leipzig, Sept. 1994, in press.
  50. Platt , U. and Janssen , C . 1996 . Observation and role of the free radicals NO3, ClO, BrO and IO in the tropo-sphere . Faraday Discuss . 100 , 175 198 .
  51. Platt , U. , Tuckermann M. , Ackermann , R. , Unold , W. , Lorenzen-Schmidt H. , Trost , B. and Stutz , J . 1996 . Halogen oxide measurements in the Arctic boundary layer and implications for sudden ozone depletion . Proceedings of the XVIII Quadrennial Ozone Symposium, L'Aquila , Italy , in press .
  52. Platt , U . 1997. DOAS-measurements during the ARCTOC campaigns 1995 and 1996 in Ny Alesund/Svalbard. ARCTOC Final Report, U. Platt and E. Lehrer , eds., University of Heidelberg , Heidelberg .
  53. Pszenny , A. A. P. , Keene , W. C. , Jacob , D. J. , Fan , S. , Maben , J. R. , Zetwo , M. P. , Springeryoung , M. and Galloway , J. N . 1993 . Evidence of inorganic chlorine gases other than hydrogen chloride in marine surface air . Geophys. Res. Lett . 20 , 699 702 .
  54. Ramacher , B. , Rudolph , J. and Koppmann , R . 1997 . Hydrocarbon measurements in the spring arctic tropo-sphere during the ARCTOC 95 campaign . Tellus 49B , 466 485 .
  55. Rasmussen , R. A. , Khalil , M. A. K. , Gunawardena , R. and Hoyt , S. D . 1982 . Atmospheric methyl iodide (CH3I) . J. Geophys. Res . 87 , 3086 3090 .
  56. Rasmussen , A. , Havskov Soerensen , J. , Killsholm , S. and Mikkelsen , I. S . 1997 Analysis of tropospheric ozone measurements in Greenland . ARCTOC Final Report , U. Platt Lehrer (eds): University of Heidelberg , Heidelberg , pp. A-159 - A180 .
  57. Sander , R. and Crutzen , P. J . 1996 . Model study indicat-ing halogen activation and ozone destruction in pol-luted air masses transported to the sea. J . Geophys. Res . 101D , 9121 9138 .
  58. Schall , C. and Heumann K. G . 1993 . GC determination of volatile organoiodine and organobromine cornpounds in seawater and air samples . Fresenius J. Anal. Chem . 346 , 717 722 .
  59. Schneider , W. , Moortgat , G. K. , Tyndall G. S. and Bur-rows , J . 1987 . Absorption cross section of NO2 in the UV and visible region (200-700 um) at 298K . J. Photochem. Photobiol., A: Chem . 40 , 195 217 .
  60. Simon , F. G. , Schneider , W. , Moortgat G. K. and Burrows J. P . 1990 . A study of the ClO absorption cross-section between 240 and 310 nm and the kinetics of the self-reaction at 300K . J. Photochern. Photobiol . A 55 , 1 23 .
  61. Solberg , S. , Hermansen , O. , Joranger , E. , Schmidt-bauer , N. , Stordal , F. and Hov , O . 1994. Tropospheric ozone depletion in the arctic during spring, measurements on the Zeppelin mountain on Spitsbergen. NILU report OR 27/94, ISBN 82-425-0575-6.
  62. Solberg , S. , Schmidtbauer , N. , Semb , A. and Stordal , F . 1996 . Boundary-layer ozone depletion as seen in the Norwegian Arctic in spring . J. Atmos. Chem . 23 , 301 332 .
  63. Solomon , S. , Garcia , R. R. and Ravishankara , A. R ., 1994 . On the role of iodine in ozone depletion . J. Geo-phys. Res . 99 , 20 , 491-20 , 499 .
  64. Sturges , W. T. and Barrie , L. A . 1988 . Chlorine, bromine and iodine in arctic aerosols . Atmos. Environ . 22 , 1179 1194 .
  65. Sturges , W. T. , Cota , G. F. and Buckley , P. T . 1992 . Bromoform emission from Arctic ice algae . Nature 358 , 660 662 .
  66. Sturges , W. T. , Schnell , R. C. , Dutton , G. S. , Garcia , S. R. and Lind , J. A . 1993 . Spring measurements of tropospheric bromine at Barrow, Alaska . Geophys. Res. Lett . 20 , 201 204 .
  67. Stutz , J . 1996. Messung der Konzentration troposphdrischer Spurenstoffe mittels Differentieller-Optischer Absorptionsspektroskopie: Eine neue Generation von Geraten und Algorithmen. PhD Thesis. University of Heidelberg.
  68. Stutz , J. and Platt , U . 1997 . Improving long-path differential optical absorption spectroscopy (DOAS) with a quartz-fiber mode-mixer . Appl. Optics 36 , 1105 1115 .
  69. Stutz , J. and Platt , U . 1996 . Numerical analysis and error estimation of differential optical absorption spectro-scopy measurements least-squares methods . Appl. Optics 35 , 6041 6053 .
  70. Tang , T. and McConnel , J. C . 1996 . Autocatalytic release of bromine from arctic snow pack during polar sunrise . Geophys. Res. Lett . , 23 , 2633 2636 .
  71. Tuckermann , M . 1996 . Troposphdrische DOAS-Messungen zum halogenkatalysierten Ozonabbau im arktischen Friihjahr (Ny-Àlesund, Svalbard) . Diploma Thesis , University of Heidelberg .
  72. Unold , W . 1995 . Bodennahe Messungen von Halogenox-iden in der Arktis . Diploma Thesis , University of Heidelberg .
  73. Vierkorn-Rudolph , B. , Bachmann , K. , Schwarz , B. and Meixner X . 1984 . Vertical profiles of hydrogen chlor-ide in the troposphere . J. Atmos. Chem . 2 , 47 63 .
  74. Vogt , R. , Crutzen , P. J. and Sander , R . 1996 . A mechan-ism for halogen release from sea-salt aerosol in the remote marine boundary layer . Nature 383 , 327 330 .
  75. Wahner , A. , Tyndall , G. S. and Ravishankara , A. R . 1987 . Absorption cross sections for °CIO as a function of temperature in the wavelength range 240-480 nm . J. Chem. Phys . 91 , 2735 2738
  76. Wahner , A. , Ravishankara , A. R. , Sander , S. P. and Friedl , R. R . 1988 . Absorption cross section of BrO between 312 and 385 nm at 298 and 223 K . Chem. Phys. Lett . 152 , 507 512 .
  77. Wayne , R. P. , Poulet , G. , Biggs , P. , Burrows , J. P. , Cox , R. A. , Crutzen , P. J. , Haymann , G. D. , Jenkin , M. E. , Le Bras , G. , Moortgat , G. K. , Platt , U. and Schindler , R. N . 1995 . Halogen oxides: radicals, sources and res-ervoirs in the laboratory and in the atmosphere . Atmosph. Environ . 29 , 2675 2884 .
  78. Wessel , S . 1996 . Tropospharische Ozonvariation in Polar-regionen . PhD Thesis , University of Bremen .
  79. Yvon , S. A. and Butler , J. H . 1996 . An improved estimate of the oceanic lifetime of atmospheric CH3Br . Geophys. Res. Lett . 23 , 53 56 .
  80. Zetzsch , C. and Behnke , W ., 1993. Heterogeneous reactions of chlorine compounds. NATO-ASI Series Subseries I “Global Environmental Change”, 11°1.7 ( H. Niki H. Becker , (eds.). Springer-Verlag, Heidelberg , 291 - 306 .
Language: English
Page range: 533 - 555
Submitted on: Dec 2, 1996
Accepted on: Sep 3, 1997
Published on: Jan 1, 1997
Published by: Stockholm University Press
In partnership with: Paradigm Publishing Services

© 1997 M. Tuckermann, R. Ackermann, C. Gölz, H. Lorenzen-Schmidt, T. Senne, J. Stutz, B. Trost, W. Unold, U. Platt, published by Stockholm University Press
This work is licensed under the Creative Commons Attribution 4.0 License.