
Aerosol chemical composition during tropospheric ozone depletion at Ny Ålesund/Svalbard
Abstract
During spring 1995, aerosol filters were continuously sampled with a temporal resolution of 4–24 h at the NILU Zeppelin Mountain Station (Ny Ålesund/Svalbard) and analysed for bromide, major ions and methanesulfonic acid (MSA). During a strong ozone depletion event at the end of April, a corresponding increase in the non-sea salt Br- exceeding the typical background level by more than one order of magnitude was observed. Peak f-Br levels (120 ng/m3) were almost equal to results of measurements reported earlier from Alert and Barrow. Less pronounced O3 depletion events occurring in early May were associated with a relatively weak Br- enhancement. A good correlation of f-Br and simultaneously measured BrO was found ([BrO]= 2 [f-Br] on a per molecule basis), except for situations with near zero O3.
© 1997 E. Lehrer, D. Wagenbach, U. Platt, published by Stockholm University Press
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