Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique

Siemieniec, Marta; Kierzkowska-Pawlak, Hanna; Chacuk, Andrzej

doi:10.2478/v10216-011-0006-y

Abstract

The pseudo-first-order rate constants (kOV) for the reactions between CO₂ and diethanolamine have been studied using the stopped-flow technique in an aqueous solution at 293, 298, 303 and 313 K. The amine concentrations ranged from 167 to 500 mol·m^-3. The overall reaction rate constant was found to increase with amine concentration and temperature. Both the zwitterion and termolecular mechanisms were applied to correlate the experimentally obtained rate constants. The values of SSE quality index showed a good agreement between the experimental data and the corresponding fit by the use of both mechanisms.

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Reaction Kinetics of Carbon Dioxide in Aqueous Diethanolamine Solutions Using the Stopped-Flow Technique

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