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Polyolefin oxo-degradation accelerators - a new trend to promote environmental protection Cover

Polyolefin oxo-degradation accelerators - a new trend to promote environmental protection

Open Access
|Dec 2010

Abstract

The paper presents the results of the tests on the preparation of iron (III) stearate - the most prominent oxo-biodegradation agent for polyolefinic plastics. The process chosen for testing was the double precipitation process, using stearic acid alkalised with soda lye and iron (III) chloride or iron (III) sulphate. A number of iron (III) stearate preparation methods described in the literature were tested and an analytical procedure for monitoring the process was developed using both the classical and instrumental techniques. FTIR spectroscopy is the most useful technique for the product quality control and identification. During the study the characteristics of the proper product were also determined using the DSC methods. Microscopy and laser diffraction particle size analysis were applied to determine the size of the precipitated product grains. An application sample of the product obtained by the double decomposition method from iron (III) sulphate as the iron carrier has successfully passed the application tests in the polyethylene packaging film.

Language: English
Page range: 44 - 52
Published on: Dec 28, 2010
Published by: West Pomeranian University of Technology, Szczecin
In partnership with: Paradigm Publishing Services
Publication frequency: 4 issues per year

© 2010 Barbara Cichy, Jacek Kwiecień, Magdalena Piątkowska, Ewa Kużdżał, Edyta Gibas, Grażyna Rymarz, published by West Pomeranian University of Technology, Szczecin
This work is licensed under the Creative Commons License.

Volume 12 (2010): Issue 4 (December 2010)