Surface modification of nano-TiN by using silane coupling agent

Guojun Cheng; Jiaqi Luo; Jiasheng Qian; Jibin Miao

doi:10.2478/s13536-013-0175-8

Abstract

Titanium nitride (TiN) nano-particles were subjected to graft modification by silane coupling agent (KH-570) via a direct blending method. The hydroxyl groups on the surface of TiN nano-particles can interact with silanol groups [-Si-OCH3] of KH-570 forming an organic coating layer. The covalent bonds (Ti-O-Si) formation was testified by Fourier transform infrared spectra (FTIR) and X-ray photoelectron spectroscopy (XPS). Through transmission electron micrograph (TEM) observations, it was found that KH-570 could improve the dispersibility of nano-TiN particles in ethyl acetate. Thermo gravimetric analysis (TGA) and contact angle measurements indicated that KH-570 molecules were adsorbed or anchored on the surface of nano-TiN particle and the net efficiency of it was 22.76 %, which facilitated to hinder the aggregation of nano-TiN particles.

References

[1] Tai Y.L., Qian J.S., Zhang Y.C., Miao J.B., Chem. Eng. J., 141 (2008), 354. http://dx.doi.org/10.1016/j.cej.2008.03.01210.1016/j.cej.2008.03.012
Search in Google Scholar
[2] Tai Y.L., Qian J.S., Miao J.B., Zhang Y.C., Mater. Design., 34 (2012), 522. http://dx.doi.org/10.1016/j.matdes.2011.05.00210.1016/j.matdes.2011.05.002
Search in Google Scholar
[3] Schmidt D.F., Giannelis E.P., Chem. Mater., 22 (2010), 167. http://dx.doi.org/10.1021/cm902697810.1021/cm9026978
Search in Google Scholar
[4] Li Z.W., Zhu Y.F., Appl. Surf. Sci., 211 (2003), 315. http://dx.doi.org/10.1016/S0169-4332(03)00259-910.1016/S0169-4332(03)00259-9
Search in Google Scholar
[5] Li H.Y., Yan Y., Liu B., Powder Technol., 178 (2007), 203. http://dx.doi.org/10.1016/j.powtec.2007.04.02010.1016/j.powtec.2007.04.020
Search in Google Scholar
[6] Sun Y.Y., Zhang Z.Q., Wong C.P., J. Colloid. Interf. Sci., 292 (2005), 436. http://dx.doi.org/10.1016/j.jcis.2005.05.06710.1016/j.jcis.2005.05.067
Search in Google Scholar
[7] Arita T., Moriya K.I., Yoshimura T., Minami K., Naka T., Ind. Eng. Chem. Res., 49 (2010), 9815. http://dx.doi.org/10.1021/ie101074w10.1021/ie101074w
Search in Google Scholar
[8] Arita T., Yu U., Minami K., Naka T., Ind. Eng. Chem. Res., 49 (2010), 1947. http://dx.doi.org/10.1021/ie901319c10.1021/ie901319c
Search in Google Scholar
[9] Kuma K.K., Raole P.M., Rayjada P.A., Chauhan N.L., Mukherjee S., Surf. Coat. Tech., 205 (2011), 187. http://dx.doi.org/10.1016/j.surfcoat.2011.04.09310.1016/j.surfcoat.2011.04.093
Search in Google Scholar
[10] Chen W.W., Wu S.W., Lei Y.D., Liao Z.F., Guo B.C., Liang X., Polymer, 52 (2011), 4387. http://dx.doi.org/10.1016/j.polymer.2011.07.02810.1016/j.polymer.2011.07.028
Search in Google Scholar
[11] Gupta S., Ramamurthy P.C., Madras G., Ind. Eng. Chem. Res., 50 (2011), 6585. http://dx.doi.org/10.1021/ie200283w10.1021/ie200283w
Search in Google Scholar
[12] Parlinska-wojtan M., Meier S., Patscheider J., Thin Solid Films, 518 (2010), 4890. http://dx.doi.org/10.1016/j.tsf.2010.02.06410.1016/j.tsf.2010.02.064
Search in Google Scholar
[13] Janes R.A., Aldissi M., Kaner R.B., Chem. Mater., 15 (2003), 4431. http://dx.doi.org/10.1021/cm034629n10.1021/cm034629n
Search in Google Scholar
[14] Subramanian B., Muraleedharan C.V., Ananthakumar R., Jayachandran M., Surf. Coat. Tech., 205 (2011), 5014. http://dx.doi.org/10.1016/j.surfcoat.2011.05.00410.1016/j.surfcoat.2011.05.004
Search in Google Scholar
[15] Rodríguez-Reyes J.C.F., Ni C.C., Bui H.P., Beebe T.P., Teplyakov A.V., Chem. Mater., 21 (2009), 5163. http://dx.doi.org/10.1021/cm902107h10.1021/cm902107h
Search in Google Scholar
[16] Sun D.F., Lang J.W., Yan X.B., Hu L.T., Xue Q.J., J. Solid. State. Chem., 184 (2011), 1333. http://dx.doi.org/10.1016/j.jssc.2011.03.05310.1016/j.jssc.2011.03.053
Search in Google Scholar
[17] Ros R.A., Dragos V.S., Appl. Surf. Sci., 258 (2012), 3871. http://dx.doi.org/10.1016/j.apsusc.2011.12.04910.1016/j.apsusc.2011.12.049
Search in Google Scholar
[18] Liu R., Lun N., Qi Y.X., Bai Y.J., Zhu H.L., J. Alloy. Compd., 509 (2011), 10032. http://dx.doi.org/10.1016/j.jallcom.2011.08.02210.1016/j.jallcom.2011.08.022
Search in Google Scholar
[19] Ma S.R., Shi L.Y., Feng X., Yu W.J., Lu B., J. Shanghai Jiaotong Univ., 3 (2008), 278. http://dx.doi.org/10.1007/s11741-008-0316-110.1007/s11741-008-0316-1
Search in Google Scholar
[20] Yao Q.Z., Zhou Y.M., Sun Y.Q., Ye X.Y., J. Inorg. Organomet. P., 4 (2008), 477. http://dx.doi.org/10.1007/s10904-008-9227-710.1007/s10904-008-9227-7
Search in Google Scholar
[21] Deng C., Yao N., Lu X., Qu S.X., Feng B., J. Mater. Sci., 16 (2009), 4394. http://dx.doi.org/10.1007/s10853-009-3662-x10.1007/s10853-009-3662-x
Search in Google Scholar
[22] Fu T., Zhao J.L., Wei J.H., Han Y., Xu K.W., J. Mater. Sci., 4 (2004), 1411. http://dx.doi.org/10.1023/B:JMSC.0000013906.60034.e810.1023/B:JMSC.0000013906.60034.e8
Search in Google Scholar
[23] Annunziata M., Oliva A., Basile M.A., Giodano M., Mazzola N., J. Dent., 39 (2011), 720. http://dx.doi.org/10.1016/j.jdent.2011.08.00310.1016/j.jdent.2011.08.003
Search in Google Scholar
[24] Jackson A.W., Shebanova O., Hector A.L., Mcmillan P.F., J. Solid. State. Chem., 179 (2006), 1383. http://dx.doi.org/10.1016/j.jssc.2006.01.06710.1016/j.jssc.2006.01.067
Search in Google Scholar
[25] Zhou X.S., Peng F., Wang H.J., Yu H., Wang J., Mater. Res. Bull., 46 (2011), 840. http://dx.doi.org/10.1016/j.materresbull.2011.02.02910.1016/j.materresbull.2011.02.029
Search in Google Scholar
[26] Chen D., Li J.H., J. Phys. Chem. C, 114 (2010), 10478. http://dx.doi.org/10.1021/jp100969a10.1021/jp100969a
Search in Google Scholar
[27] Sun J.F., Wang M.Z., Zhao Y.C., Li X.P., Liang B.Y., J. Alloy. Compd., 482 (2009), 29. http://dx.doi.org/10.1016/j.jallcom.2009.04.04310.1016/j.jallcom.2009.04.043
Search in Google Scholar
[28] Galvanetto E., Galliano F.P., Borgioli F., Bardi U., Lavacchi A., Thin Solid Films, 384 (2001), 223. http://dx.doi.org/10.1016/S0040-6090(00)01871-X10.1016/S0040-6090(00)01871-X
Search in Google Scholar
[29] Ismail I.M., Abdallah B., Abou-Kharroub M., Mrad O., Nucl. Instrum. Meth. B, 271 (2012), 102. http://dx.doi.org/10.1016/j.nimb.2011.11.01010.1016/j.nimb.2011.11.010
Search in Google Scholar
[30] Zhao J., Garza E.G., Lam K., Jones C.M., Appl. Surf. Sci., 158 (2000), 246. http://dx.doi.org/10.1016/S0169-4332(00)00024-610.1016/S0169-4332(00)00024-6
Search in Google Scholar
[31] Qiu Y.C., Yan K.Y., Yang S.H., Jin L.M., Deng H., Li W.S., ACS Nano, 4 (2010), 6515. http://dx.doi.org/10.1021/nn101603g10.1021/nn101603g
Search in Google Scholar
[32] Mazur M., Kaczmarek D., Domaradzki J., Wojcieszak D., Mater. Sci.-Poland, 31 (2013), 71. http://dx.doi.org/10.2478/s13536-012-0066-410.2478/s13536-012-0066-4
Search in Google Scholar

Surface modification of nano-TiN by using silane coupling agent

Abstract

Paradigm

My account